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Cobalt ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Cobalt ion (1+) bullet 2Methane) + Methane = (Cobalt ion (1+) bullet 3Methane)

By formula: (Co+ bullet 2CH4) + CH4 = (Co+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar46.kJ/molSIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
41. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
3.477.SIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Cobalt ion (1+) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen)

By formula: Co+ + H2 = (Co+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar82. ± 4.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=76.1 kJ/mol, «DELTA»rS(300 K)=86.2 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar92.0J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=76.1 kJ/mol, «DELTA»rS(300 K)=86.2 J/mol*K; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
73.2 (+9.6,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M

Cobalt ion (1+) + Methane = (Cobalt ion (1+) bullet Methane)

By formula: Co+ + CH4 = (Co+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
90.0 (+6.7,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M
90.0 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
94. (+2.,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Benzene) + Benzene = (Cobalt ion (1+) bullet 2Benzene)

By formula: (Co+ bullet C6H6) + C6H6 = (Co+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar167. ± 14.kJ/molCIDTMeyer, Khan, et al., 1995RCD
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
167. (+13.,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M
113. (+4.2,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Ethane = (Cobalt ion (1+) bullet Ethane)

By formula: Co+ + C2H6 = (Co+ bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
100. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
117. (+6.7,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

(Cobalt ion (1+) bullet 2helium) + helium = (Cobalt ion (1+) bullet 3helium)

By formula: (Co+ bullet 2He) + He = (Co+ bullet 3He)

Quantity Value Units Method Reference Comment
Deltar5.5 ± 0.4kJ/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 5.10 kJ/mol, «DELTA»rS(100 K) = 46.4 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar48.5J/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 5.10 kJ/mol, «DELTA»rS(100 K) = 46.4 J/mol*K; M

(Cobalt ion (1+) bullet neon) + neon = (Cobalt ion (1+) bullet 2neon)

By formula: (Co+ bullet Ne) + Ne = (Co+ bullet 2Ne)

Quantity Value Units Method Reference Comment
Deltar8.2 ± 0.4kJ/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 8.16 kJ/mol, «DELTA»rS(100 K) = 52.3 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar48.5J/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 8.16 kJ/mol, «DELTA»rS(100 K) = 52.3 J/mol*K; M

(Cobalt ion (1+) bullet helium) + helium = (Cobalt ion (1+) bullet 2helium)

By formula: (Co+ bullet He) + He = (Co+ bullet 2He)

Quantity Value Units Method Reference Comment
Deltar15.4 ± 0.4kJ/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 14.3 kJ/mol, «DELTA»rS(100 K) = 79.9 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 14.3 kJ/mol, «DELTA»rS(100 K) = 79.9 J/mol*K; M

Cobalt ion (1+) + Carbon monoxide = (Cobalt ion (1+) bullet Carbon monoxide)

By formula: Co+ + CO = (Co+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar174. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar160. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
174. (+6.7,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
163. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + neon = (Cobalt ion (1+) bullet neon)

By formula: Co+ + Ne = (Co+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 0.4kJ/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 9.12 kJ/mol, «DELTA»rS(100 K) = 58.6 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar64.4J/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 9.12 kJ/mol, «DELTA»rS(100 K) = 58.6 J/mol*K; M

Cobalt ion (1+) + helium = (Cobalt ion (1+) bullet helium)

By formula: Co+ + He = (Co+ bullet He)

Quantity Value Units Method Reference Comment
Deltar14.9 ± 0.4kJ/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 12.6 kJ/mol, «DELTA»rS(100 K) = 61.5 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar71.5J/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 12.6 kJ/mol, «DELTA»rS(100 K) = 61.5 J/mol*K; M

(Cobalt ion (1+) bullet Methane) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Methane)

By formula: (Co+ bullet CH4) + H2 = (Co+ bullet H2 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
73. (+3.,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Methane = (Cobalt ion (1+) bullet Methane bullet Hydrogen)

By formula: (Co+ bullet H2) + CH4 = (Co+ bullet CH4 bullet H2)

Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
94.6 (+5.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 2Hydrogen)

By formula: (Co+ bullet H2) + H2 = (Co+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar75. ± 3.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=71.1 kJ/mol, «DELTA»rS(300 K)=103. J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=71.1 kJ/mol, «DELTA»rS(300 K)=103. J/mol*K; M

(Cobalt ion (1+) bullet 2Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 3Hydrogen)

By formula: (Co+ bullet 2H2) + H2 = (Co+ bullet 3H2)

Quantity Value Units Method Reference Comment
Deltar44. ± 2.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=85.8 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=85.8 J/mol*K; M

(Cobalt ion (1+) bullet 3Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 4Hydrogen)

By formula: (Co+ bullet 3H2) + H2 = (Co+ bullet 4H2)

Quantity Value Units Method Reference Comment
Deltar44. ± 3.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=105. J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=105. J/mol*K; M

(Cobalt ion (1+) bullet 4Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 5Hydrogen)

By formula: (Co+ bullet 4H2) + H2 = (Co+ bullet 5H2)

Quantity Value Units Method Reference Comment
Deltar22. ± 3.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=18. kJ/mol, «DELTA»rS(300 K)=91.6 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=18. kJ/mol, «DELTA»rS(300 K)=91.6 J/mol*K; M

(Cobalt ion (1+) bullet 5Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 6Hydrogen)

By formula: (Co+ bullet 5H2) + H2 = (Co+ bullet 6H2)

Quantity Value Units Method Reference Comment
Deltar20. ± 3.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17. kJ/mol, «DELTA»rS(300 K)=99.6 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17. kJ/mol, «DELTA»rS(300 K)=99.6 J/mol*K; M

(Cobalt ion (1+) bullet 6Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 7Hydrogen)

By formula: (Co+ bullet 6H2) + H2 = (Co+ bullet 7H2)

Quantity Value Units Method Reference Comment
Deltar6. ± 3.kJ/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=3. kJ/mol; «DELTA»rS(300 K)=75.3 J/mol*K; M
Quantity Value Units Method Reference Comment
Deltar75.3J/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=3. kJ/mol; «DELTA»rS(300 K)=75.3 J/mol*K; M

(Cobalt ion (1+) bullet Methane) + Methane = (Cobalt ion (1+) bullet 2Methane)

By formula: (Co+ bullet CH4) + CH4 = (Co+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar109.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
95.8 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
104. (+4.2,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Cobalt ion (1+) + Ethylene = (Cobalt ion (1+) bullet Ethylene)

By formula: Co+ + C2H4 = (Co+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar186. ± 9.2kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
179. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
27. (+13.,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 2Carbon monoxide)

By formula: (Co+ bullet CO) + CO = (Co+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar153. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
152. (+8.8,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
138. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Methane) + Ethane = (Cobalt ion (1+) bullet Ethane bullet Methane)

By formula: (Co+ bullet CH4) + C2H6 = (Co+ bullet C2H6 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar108.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
119. (+5.4,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Cobalt ion (1+) + Water = (Cobalt ion (1+) bullet Water)

By formula: Co+ + H2O = (Co+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar160. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Deltar168.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
161. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Water)

By formula: (Co+ bullet H2O) + H2 = (Co+ bullet H2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar103.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
83. (+3.,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Water) + Methane = (Cobalt ion (1+) bullet Methane bullet Water)

By formula: (Co+ bullet H2O) + CH4 = (Co+ bullet CH4 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar113.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
108. (+3.,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

(Cobalt ion (1+) bullet Ethane) + Methane = (Cobalt ion (1+) bullet Methane bullet Ethane)

By formula: (Co+ bullet C2H6) + CH4 = (Co+ bullet CH4 bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar110.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
102. (+4.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Propene = (Cobalt ion (1+) bullet Propene)

By formula: Co+ + C3H6 = (Co+ bullet C3H6)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
180. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
180. (+6.7,-0.) CIDHaynes and Armentrout, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Water = (Cobalt ion (1+) bullet 2Water)

By formula: (Co+ bullet H2O) + H2O = (Co+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar175.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
162. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Acetylene = (Cobalt ion (1+) bullet Acetylene)

By formula: Co+ + C2H2 = (Co+ bullet C2H2)

Quantity Value Units Method Reference Comment
Deltar180. ± 7.9kJ/molIRMPDSurya, Ranatunga, et al., 1997RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
27. (+13.,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

(Cobalt ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 3Carbon monoxide)

By formula: (Co+ bullet 2CO) + CO = (Co+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar82. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
82. (+12.,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 4Carbon monoxide)

By formula: (Co+ bullet 3CO) + CO = (Co+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar74.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
75.3 (+5.9,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 5Carbon monoxide)

By formula: (Co+ bullet 4CO) + CO = (Co+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar74.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
75.3 (+5.0,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

Cobalt ion (1+) + Benzene = (Cobalt ion (1+) bullet Benzene)

By formula: Co+ + C6H6 = (Co+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar256. ± 11.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
256. (+10.,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Ammonia) + Ammonia = (Cobalt ion (1+) bullet 2Ammonia)

By formula: (Co+ bullet H3N) + H3N = (Co+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar248. ± 13.kJ/molCIDTWalter and Armentrout, 1998RCD
Deltar256.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Ammonia = (Cobalt ion (1+) bullet Ammonia)

By formula: Co+ + H3N = (Co+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar218. ± 15.kJ/molCIDTWalter and Armentrout, 1998RCD
Deltar246.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Methyl radical = (Cobalt ion (1+) bullet Methyl radical)

By formula: Co+ + CH3 = (Co+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar204. ± 13.kJ/molCIDTFisher, Sunderlin, et al., 1989RCD
Deltar205. ± 15.kJ/molCIDTGeorgiadis, Fisher, et al., 1989RCD

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) bullet Carbon monosulfide)

By formula: Co+ + CS = (Co+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar258. ± 33.kJ/molCIDTRue, Armentrout, et al., 2001RCD
Deltar240. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cobalt ion (1+) bullet 2Water) + Water = (Cobalt ion (1+) bullet 3Water)

By formula: (Co+ bullet 2H2O) + H2O = (Co+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
64.9 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Water) + Water = (Cobalt ion (1+) bullet 4Water)

By formula: (Co+ bullet 3H2O) + H2O = (Co+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
58.2 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Propyne = (Cobalt ion (1+) bullet Propyne)

By formula: Co+ + C3H4 = (Co+ bullet C3H4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
79.1 (+8.8,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet 3Methane) + Methane = (Cobalt ion (1+) bullet 4Methane)

By formula: (Co+ bullet 3CH4) + CH4 = (Co+ bullet 4CH4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
67.8 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 10cobalt) + cobalt = (Cobalt ion (1+) bullet 11cobalt)

By formula: (Co+ bullet 10Co) + Co = (Co+ bullet 11Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
329. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 11cobalt) + cobalt = (Cobalt ion (1+) bullet 12cobalt)

By formula: (Co+ bullet 11Co) + Co = (Co+ bullet 12Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
351. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 12cobalt) + cobalt = (Cobalt ion (1+) bullet 13cobalt)

By formula: (Co+ bullet 12Co) + Co = (Co+ bullet 13Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
303. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 13cobalt) + cobalt = (Cobalt ion (1+) bullet 14cobalt)

By formula: (Co+ bullet 13Co) + Co = (Co+ bullet 14Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
380. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 14cobalt) + cobalt = (Cobalt ion (1+) bullet 15cobalt)

By formula: (Co+ bullet 14Co) + Co = (Co+ bullet 15Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
355. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 15cobalt) + cobalt = (Cobalt ion (1+) bullet 16cobalt)

By formula: (Co+ bullet 15Co) + Co = (Co+ bullet 16Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
346. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 16cobalt) + cobalt = (Cobalt ion (1+) bullet 17cobalt)

By formula: (Co+ bullet 16Co) + Co = (Co+ bullet 17Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
371. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 9cobalt) + cobalt = (Cobalt ion (1+) bullet 10cobalt)

By formula: (Co+ bullet 9Co) + Co = (Co+ bullet 10Co)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
314. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T., Co+(H2)n Clusters: Binding Energies and Molecular Parameters, J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012 . [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B., Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4, J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References