Bismuth ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Bismuth ion (1+) • 2Water) + Water = (Bismuth ion (1+) • 3Water)

By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr14.0kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr24.4cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 3Water) + Water = (Bismuth ion (1+) • 4Water)

By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr12.0kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr23.5cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 4Water) + Water = (Bismuth ion (1+) • 5Water)

By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr10.5kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 5Water) + Water = (Bismuth ion (1+) • 6Water)

By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr9.7kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr23.6cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • Water) + Water = (Bismuth ion (1+) • 2Water)

By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr17.7kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr25.5cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 2Ammonia) + Ammonia = (Bismuth ion (1+) • 3Ammonia)

By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr13.4kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr26.0cal/mol*KHPMSCastleman, 1978gas phase; M

(Bismuth ion (1+) • Ammonia) + Ammonia = (Bismuth ion (1+) • 2Ammonia)

By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr23.2kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr33.0cal/mol*KHPMSCastleman, 1978gas phase; M

Bismuth ion (1+) + Water = (Bismuth ion (1+) • Water)

By formula: Bi+ + H2O = (Bi+ • H2O)

Quantity Value Units Method Reference Comment
Δr22.8kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr27.1cal/mol*KHPMSTang and Castleman, 1974gas phase; M

Bismuth ion (1+) + Ammonia = (Bismuth ion (1+) • Ammonia)

By formula: Bi+ + H3N = (Bi+ • H3N)

Quantity Value Units Method Reference Comment
Δr35.5kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr35.7cal/mol*KHPMSCastleman, 1978gas phase; M

Bismuth ion (1+) + Benzene = (Bismuth ion (1+) • Benzene)

By formula: Bi+ + C6H6 = (Bi+ • C6H6)

Quantity Value Units Method Reference Comment
Δr<35.5kcal/molPDisWilley, Yeh, et al., 1992RCD

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bismuth ion (1+) + Benzene = (Bismuth ion (1+) • Benzene)

By formula: Bi+ + C6H6 = (Bi+ • C6H6)

Quantity Value Units Method Reference Comment
Δr<35.5kcal/molPDisWilley, Yeh, et al., 1992RCD

Bismuth ion (1+) + Water = (Bismuth ion (1+) • Water)

By formula: Bi+ + H2O = (Bi+ • H2O)

Quantity Value Units Method Reference Comment
Δr22.8kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr27.1cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • Water) + Water = (Bismuth ion (1+) • 2Water)

By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr17.7kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr25.5cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 2Water) + Water = (Bismuth ion (1+) • 3Water)

By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr14.0kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr24.4cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 3Water) + Water = (Bismuth ion (1+) • 4Water)

By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr12.0kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr23.5cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 4Water) + Water = (Bismuth ion (1+) • 5Water)

By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr10.5kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 5Water) + Water = (Bismuth ion (1+) • 6Water)

By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr9.7kcal/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr23.6cal/mol*KHPMSTang and Castleman, 1974gas phase; M

Bismuth ion (1+) + Ammonia = (Bismuth ion (1+) • Ammonia)

By formula: Bi+ + H3N = (Bi+ • H3N)

Quantity Value Units Method Reference Comment
Δr35.5kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr35.7cal/mol*KHPMSCastleman, 1978gas phase; M

(Bismuth ion (1+) • Ammonia) + Ammonia = (Bismuth ion (1+) • 2Ammonia)

By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr23.2kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr33.0cal/mol*KHPMSCastleman, 1978gas phase; M

(Bismuth ion (1+) • 2Ammonia) + Ammonia = (Bismuth ion (1+) • 3Ammonia)

By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr13.4kcal/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr26.0cal/mol*KHPMSCastleman, 1978gas phase; M

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tang and Castleman, 1974
Tang, I.N.; Castleman, A.W., Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Bismuth Ion, J. Chem. Phys., 1974, 60, 10, 3981, https://doi.org/10.1063/1.1680846 . [all data]

Castleman, 1978
Castleman, A.W., The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+, Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4 . [all data]

Willey, Yeh, et al., 1992
Willey, K.F.; Yeh, C.S.; Robbins, D.L.; Duncan, M.A., Charge-transfer in the photodissociation of metal ion-benzene complexes, J. Phys. Chem., 1992, 96, 23, 9106, https://doi.org/10.1021/j100202a007 . [all data]


Notes

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