Bismuth ion (1+)
- Formula: Bi+
- Molecular weight: 208.97985
- IUPAC Standard InChI: InChI=1S/Bi/q+1
- IUPAC Standard InChIKey: SAPXNJKQDHJIRE-UHFFFAOYSA-N
- CAS Registry Number: 16463-30-2
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Options:
Reaction thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.4 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 4
) +
= (
• 5
)
By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.5 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.7 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 5
) +
= (
• 6
)
By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.2 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 33.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
+
= (
•
)
By formula: Bi+ + H2O = (Bi+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.8 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.1 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
+
= (
•
)
By formula: Bi+ + H3N = (Bi+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.5 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.7 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
+
= (
•
)
By formula: Bi+ + C6H6 = (Bi+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <35.5 | kcal/mol | PDis | Willey, Yeh, et al., 1992 | RCD |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+
= (
•
)
By formula: Bi+ + C6H6 = (Bi+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <35.5 | kcal/mol | PDis | Willey, Yeh, et al., 1992 | RCD |
+
= (
•
)
By formula: Bi+ + H2O = (Bi+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.8 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.1 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.4 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 4
) +
= (
• 5
)
By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.5 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.7 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 5
) +
= (
• 6
)
By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
+
= (
•
)
By formula: Bi+ + H3N = (Bi+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.5 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.7 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.2 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 33.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tang and Castleman, 1974
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Bismuth Ion,
J. Chem. Phys., 1974, 60, 10, 3981, https://doi.org/10.1063/1.1680846
. [all data]
Castleman, 1978
Castleman, A.W.,
The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+,
Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4
. [all data]
Willey, Yeh, et al., 1992
Willey, K.F.; Yeh, C.S.; Robbins, D.L.; Duncan, M.A.,
Charge-transfer in the photodissociation of metal ion-benzene complexes,
J. Phys. Chem., 1992, 96, 23, 9106, https://doi.org/10.1021/j100202a007
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.