(Z)-1,2-Difluoroethylene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C2H2F2 = (Z)-1,2-Difluoroethylene

By formula: C2H2F2 = C2H2F2

Quantity Value Units Method Reference Comment
Δr-1.08 ± 0.12kcal/molEqkCraig, Piper, et al., 1971gas phase

(Z)-1,2-Difluoroethylene = C2H2F2

By formula: C2H2F2 = C2H2F2

Quantity Value Units Method Reference Comment
Δr0.93kcal/molEqkCraig and Entemann, 1961gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C     Symmetry Number σ = 2


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 CH str 3135  D 3135 W gas SF8)
a1 2 CC str 1715  C 1715 S gas
a1 3 CH bend 1266  C 1266 S gas
a1 4 CF str 1014  C 1014 S gas
a1 5 CCF deform 255  D 255 W gas
a2 6 CH bend 866  E  ia CF ( )From product rule
a2 7 Torsion 482  E  ia CF ( )Calculated by assuming ?/?
b1 8 CH str 3135  D 3135 W gas SF1)
b1 9 CH bend 1376  C 1376 S gas
b1 10 CF str 1127  C 1127 VS gas
b1 11 CCF deform 768  B 768 S gas
b2 12 CH bend 756  B 756 S gas

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
WWeak
iaInactive
CFCalculated frequency
SFCalculation shows that the frequency approximately equals that of the vibration indicated in the parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty
E15~30 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Craig, Piper, et al., 1971
Craig, N.C.; Piper, L.G.; Wheeler, V.L., Thermodynamics of cis-trans isomerizations. II. The 1-chloro-2-fluoroethylenes, 1,2-difluorocyclopropanes, and related molecules, J. Phys. Chem., 1971, 75, 1453-1460. [all data]

Craig and Entemann, 1961
Craig, N.C.; Entemann, E.A., Thermodynamics of cis-trans isomerizations. The 1,2-difluoroethylenes, J. Am. Chem. Soc., 1961, 83, 3047-3050. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume I, National Bureau of Standards, 1972, 1-160. [all data]


Notes

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