1-Propene, 1-chloro-, (Z)-
- Formula: C3H5Cl
- Molecular weight: 76.525
- IUPAC Standard InChIKey: OWXJKYNZGFSVRC-IHWYPQMZSA-N
- CAS Registry Number: 16136-84-8
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: cis-1-Chloropropene; Propene, 1-chloro-, (Z)-; cis-1-Chloro-1-Propene; 1-Chloro-propene; (Z)-1-Chloro-1-propene; (Z)-1-Propene, 1-chloro
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 305.6 ± 0.7 | K | AVG | N/A | Average of 6 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
6.67 | 291. | N/A | Horstmann, Gardeler, et al., 2001 | Based on data from 276. to 332. K.; AC |
6.98 | 252. | A | Stephenson and Malanowski, 1987 | Based on data from 237. to 338. K. See also Dykyj, 1970.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C3H5Cl = C3H5Cl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -0.7 ± 0.064 | kcal/mol | Eqk | Shevtsova and Andreevskii, 1971 | gas phase; Heat of isomerization |
By formula: C3H5Cl = C3H5Cl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.76 ± 0.03 | kcal/mol | Ciso | Abell and Adolf, 1969 | gas phase; HBr catalyst |
By formula: C3H5Cl = C3H5Cl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.5 ± 0.2 | kcal/mol | Eqk | Alfassi, Golden, et al., 1973 | liquid phase |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Horstmann, Gardeler, et al., 2001
Horstmann, Sven; Gardeler, Hergen; Fischer, Kai; Köster, Frank; Gmehling, Jürgen,
Vapor Pressure, Vapor-Liquid Equilibrium, and Excess Enthalpy Data for Compounds and Binary Subsystems of the Chlorohydrin Process for Propylene Oxide Production,
J. Chem. Eng. Data, 2001, 46, 2, 337-345, https://doi.org/10.1021/je000292j
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Shevtsova and Andreevskii, 1971
Shevtsova, L.A.; Andreevskii, D.N.,
Cis-trans isomerization of 1-chloro-1-propene,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1971, 15, 718-720. [all data]
Abell and Adolf, 1969
Abell, P.I.; Adolf, P.K.,
HBr catalyzed photoisomerization of allyl halides,
J. Chem. Thermodyn., 1969, 1, 333-338. [all data]
Alfassi, Golden, et al., 1973
Alfassi, Z.B.; Golden, D.M.; Benson, S.W.,
The thermochemistry of the isomerization of 3-halopropenes (allyl halides) to 1-halopropenes; entropy and enthalpy of formation contribution of the Cd-(H)(X) group,
J. Chem. Thermodyn., 1973, 5, 411-420. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Tboil Boiling point ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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