Thiazyl trifluoride
- Formula: F3NS
- Molecular weight: 103.067
- IUPAC Standard InChI: InChI=1S/F3NS/c1-5(2,3)4
- IUPAC Standard InChIKey: UQUPGRNSXINWBS-UHFFFAOYSA-N
- CAS Registry Number: 15930-75-3
- Chemical structure:
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IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Gas Phase Spectrum
Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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| Owner | COBLENTZ SOC. Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | DOW CHEMICAL COMPANY |
| Source reference | COBLENTZ NO. 08763 |
| Date | 1964 |
| Name(s) | trifluoro(nitrilo)-.lambda.<6>-sulfane |
| State | GAS (40 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg) |
| Instrument | DOW KBr FOREPRISM-GRATING |
| Instrument parameters | GRATING CHANGED AT 5.0, 7.5, 15.0 MICRON |
| Path length | 5 CM |
| Resolution | 2 |
| Sampling procedure | TRANSMISSION |
| Data processing | DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY |
Vibrational and/or electronic energy levels
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: C3ν Symmetry Number σ = 3
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a1 | 1 | NS str | 1515 | B | 1515 | gas | 1512 p | liq. | ||
| a1 | 2 | NF3 s-str | 775 | B | 775 | gas | 768 p | liq. | ||
| a1 | 3 | NF3 s-deform | 521 | B | 521 | gas | 520 dp | liq. | ||
| e | 4 | NF3 d-str | 811 | B | 811 | gas | 812 dp | liq. | ||
| e | 5 | NF3 d-deform | 429 | B | 429 | gas | 430 dp | liq. | ||
| e | 6 | NF3 rock | 342 | B | 342 | gas | 340 dp | liq. | ||
Source: Shimanouchi, 1972
Notes
| p | Polarized |
| dp | Depolarized |
| B | 1~3 cm-1 uncertainty |
References
Go To: Top, IR Spectrum, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, IR Spectrum, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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