exo,endo-Tetracyclo[6.2.1.1(3,6).0(2,7)]dodecane


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Hydrogen + exo,endo-Tetracyclo[6.2.1.1(3,6).0(2,7)]dodeca-4,9-diene = exo,endo-Tetracyclo[6.2.1.1(3,6).0(2,7)]dodecane

By formula: 2H2 + C12H14 = C12H18

Quantity Value Units Method Reference Comment
Δr-289. ± 1.kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid

Hydrogen + 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,4a,5,8,8a-octahydro-, (1α,4α,4aα,5β,8β,8aα)- = exo,endo-Tetracyclo[6.2.1.1(3,6).0(2,7)]dodecane

By formula: H2 + C12H16 = C12H18

Quantity Value Units Method Reference Comment
Δr-133.6 ± 0.88kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid

Hydrogen + 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,4a,5,8,8a-octahydro-, (1α,4α,5β,8β)- = exo,endo-Tetracyclo[6.2.1.1(3,6).0(2,7)]dodecane

By formula: H2 + C12H16 = C12H18

Quantity Value Units Method Reference Comment
Δr-149.1kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner, Jarrett, et al., 1973
Turner, R.B.; Jarrett, A.D.; Goebel, P.; Mallon, B.J., Heats of hydrogenation. 9. Cyclic acetylenes and some miscellaneous olefins, J. Am. Chem. Soc., 1973, 95, 790-792. [all data]


Notes

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