SiH3 anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

(H3Si- • 4294967295Silylene) + Silylene = H3Si-

By formula: (H3Si- • 4294967295H2Si) + H2Si = H3Si-

Quantity Value Units Method Reference Comment
Δr84.5 ± 1.4kcal/molN/ANimlos and Ellison, 1986gas phase
Δr50.6 ± 2.5kcal/molTherBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B., Photoelectron spectroscopy of SiH3- and SiD3-, J. Am. Chem. Soc., 1986, 108, 6522. [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]


Notes

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