Ethylene, 1,2-dichloro-, (Z)-
- Formula: C2H2Cl2
- Molecular weight: 96.943
- IUPAC Standard InChIKey: KFUSEUYYWQURPO-UPHRSURJSA-N
- CAS Registry Number: 156-59-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Stereoisomers:
- Other names: Ethene, 1,2-dichloro-, (Z)-; (Z)-1,2-Dichloroethylene; cis-Di-1,2-Chloroethylene; cis-Dichloroethylene; cis-1,2-Dichloroethene; cis-1,2-Dichloroethylene; 1,2-cis-Dichloroethylene; (Z)-CHCl=CHCl; (Z)-1,2-Dichloroethene; 1,2-cis-Dichloroethene; Acetylene dichloride, cis-; 1,cis-2-Dichloroethene; Ethylene, 1,2-dichloro-, cis-; Ethene, 1,2-dichloro-, (1Z)-; HCC 1130c; R 1130c
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Reaction thermochemistry data
Go To: Top, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C2H2Cl2 = C2H2Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -0.48 | kcal/mol | Eqk | Rozhnov, Levanova, et al., 1974 | liquid phase; GC |
ΔrH° | -0.72 ± 0.16 | kcal/mol | Eqk | Craig, Piper, et al., 1971 | gas phase |
ΔrH° | 0.723 | kcal/mol | Eqk | Wood and Stevenson, 1941 | gas phase; Heat of isomerization |
ΔrH° | 0.62 | kcal/mol | Eqk | Maroney, 1935 | gas phase; At 300-975 K |
By formula: C2H2Cl2 = C2H2Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.2 | kcal/mol | Kin | Laursen and Pimentel, 1989 | gas phase; Photolysis |
ΔrH° | 0.44 ± 0.09 | kcal/mol | Eqk | Craig, Piper, et al., 1971 | gas phase |
ΔrH° | 0.445 ± 0.020 | kcal/mol | Eqk | Pitzer and Hollenberg, 1954 | liquid phase; Heat of isomerization at 0K |
By formula: C2H2Cl2 = C2H2Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -1.32 | kcal/mol | Eqk | Rozhnov, Levanova, et al., 1974 | liquid phase; solvent: Dichloromethylene; GC |
By formula: C2H2Cl2 + Cl2 = C2H2Cl4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -40.4 | kcal/mol | Cm | Kirkbride, 1956 | liquid phase; Heat of chlorination |
By formula: C2H2Cl2 = H2 + C2Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.9 | kcal/mol | Kin | Laursen and Pimentel, 1989 | gas phase; Photolysis |
By formula: C2H2Cl2 = C2HCl + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.3 | kcal/mol | Kin | Laursen and Pimentel, 1989 | gas phase; Photolysis |
By formula: C2H2Cl2 = C2H2 + Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.1 | kcal/mol | Kin | Laursen and Pimentel, 1989 | gas phase; Photolyses |
By formula: C2H2Cl2 + HCl = C2H3Cl3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -14.6 | kcal/mol | Cm | Levanova, Treger, et al., 1975 | liquid phase |
Mass spectrum (electron ionization)
Go To: Top, Reaction thermochemistry data, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | NIST Mass Spectrometry Data Center, 1998. |
NIST MS number | 291425 |
UV/Visible spectrum
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
View spectrum image in SVG format.
Download spectrum in JCAMP-DX format.
Source | Perkampus and Braunschweig, 1966 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 19933 |
Instrument | Zeis PMQ II |
Boiling point | 60 |
References
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rozhnov, Levanova, et al., 1974
Rozhnov, A.M.; Levanova, S.V.; Dvornikova, G.A.; Sadovnikova, S.L.,
Equilibrium of isomerization of dichloroethylenes,
J. Appl. Chem. USSR, 1974, 47, 667-669. [all data]
Craig, Piper, et al., 1971
Craig, N.C.; Piper, L.G.; Wheeler, V.L.,
Thermodynamics of cis-trans isomerizations. II. The 1-chloro-2-fluoroethylenes, 1,2-difluorocyclopropanes, and related molecules,
J. Phys. Chem., 1971, 75, 1453-1460. [all data]
Wood and Stevenson, 1941
Wood, R.E.; Stevenson, D.P.,
The energy of isomerization of cis- and trans-dichloroethylene,
J. Am. Chem. Soc., 1941, 63, 1650-1653. [all data]
Maroney, 1935
Maroney, W.,
The thermal equilibrium of the cis-trans isomers of dichloroethylene at high temperatures,
J. Am. Chem. Soc., 1935, 57, 2397-2398. [all data]
Laursen and Pimentel, 1989
Laursen, S.L.; Pimentel, G.C.,
Matrix-induced intersystem crossing in the photochemistry of the 1,2-dichloroethenes,
J. Phys. Chem., 1989, 93, 2328-2333. [all data]
Pitzer and Hollenberg, 1954
Pitzer, K.S.; Hollenberg, J.L.,
Cis- and trans-dichloroethylenes. The infrared spectra from 130-400 cm.-1 and the thermodynamic properties,
J. Am. Chem. Soc., 1954, 76, 1493-1496. [all data]
Kirkbride, 1956
Kirkbride, F.W.,
The heats of chlorination of some hydrocarbons and their chloro-derivatives,
J. Appl. Chem., 1956, 6, 11-21. [all data]
Levanova, Treger, et al., 1975
Levanova, S.V.; Treger, Yu.A.; Velichko, S.M.; Rozhnov, A.M.; Khlestkov, A.I.; Pisarev, V.V.,
Liquid-phase hydrochlorination of symmetrical dichloroethylenes,
J. Appl. Chem. USSR, 1975, 48, 1628-1631, In original 1574. [all data]
Perkampus and Braunschweig, 1966
Perkampus, H.-H.; Braunschweig, T.H.,
UV atlas of organic compounds, 1966, 1, A1/4. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.