dicyclohexyl peroxydicarbonate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-1002. ± 13.kJ/molCcbKiparisova and Rabinovich, 1971 
Δfgas-1000. ± 20.kJ/molCcbRabinovoch, Tel'noy, et al., 1962 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-1103. ± 10.kJ/molCcbKiparisova and Rabinovich, 1971 
Δfsolid-1100. ± 20.kJ/molCcbRabinovoch, Tel'noy, et al., 1962 
Quantity Value Units Method Reference Comment
Δcsolid-7550. ± 10.kJ/molCcbKiparisova and Rabinovich, 1971Corresponding Δfsolid = -1103. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcsolid-7550. ± 20.kJ/molCcbRabinovoch, Tel'noy, et al., 1962Corresponding Δfsolid = -1100. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub101.0kJ/molN/AKiparisova and Rabinovich, 1971DRB
Δsub100. ± 2.kJ/molVRabinovoch, Tel'noy, et al., 1962ALS
Δsub100.0kJ/molN/ARabinovoch, Tel'noy, et al., 1962DRB

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
100.4 ± 8.3303.MERabinovich, Tel'noi, et al., 1962Based on data from 293. to 313. K. See also Cox and Pilcher, 1970.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiparisova and Rabinovich, 1971
Kiparisova, E.G.; Rabinovich, I.B., Thermochemistry of a series of acyl peroxides, Dokl. Phys. Chem. (Engl. Transl.), 1971, 199, 675-677, In original 1075. [all data]

Rabinovoch, Tel'noy, et al., 1962
Rabinovoch, N.B.; Tel'noy, V.I.; Terman, L.M.; Kirillova, A.S.; Razuvaev, G.A., The heats of decomposition and formation of dicyclohexyl- and dimethylperoxidecarbonate, Dokl. Akad. Nauk SSSR, 1962, 143, 133-136. [all data]

Rabinovich, Tel'noi, et al., 1962
Rabinovich, I.B.; Tel'noi, V.I.; Terman, L.M.; Kirillova, A.S.; Razuvaev, G.A., Dokl. Akad. Nauk SSSR, 1962, 143, 133. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]


Notes

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