1,5-Cyclooctadiene, (Z,Z)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas101.0 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid57.7 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 
Quantity Value Units Method Reference Comment
Δcliquid-4920.8 ± 1.3kJ/molCcbKozina, Timofeeva, et al., 1976Corresponding Δfliquid = 57.70 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-4880.6kJ/molCcrRauh, Geyer, et al., 1973Corresponding Δfliquid = 18. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil420.KN/ATreboganov, Mitsner, et al., 1965Uncertainty assigned by TRC = 2. K; TRC
Tboil421.KN/AZakharkin and Zhigareva, 1963Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tfus203.KN/AZiegler and Wilms, 1948Uncertainty assigned by TRC = 5. K; stereochemistry not certain; TRC
Quantity Value Units Method Reference Comment
Δvap43.39kJ/molN/AMajer and Svoboda, 1985 
Δvap43.4 ± 0.1kJ/molCVarushchenko, Pashchenko, et al., 1996AC
Δvap43.3kJ/molN/AKozina, Timofeeva, et al., 1976DRB
Δvap41.0kJ/molVRauh, Geyer, et al., 1973ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Timofeeva, et al., 1976
Kozina, M.P.; Timofeeva, L.P.; Gal'chenko, G.L.; Gvozdeva, E.A.; Cherednichenko, V.M., The determination of the enthalphy of combustion of cis, cis-cyclooctadiene-1,5, Termodin. Org. Soedin., 1976, 9-11. [all data]

Rauh, Geyer, et al., 1973
Rauh, H.J.; Geyer, W.; Schmidt, H.; Geiseler, G., Bildungsenthalpien und mesomerieenergien von π-bindungssystemen, Z. Phys. Chem. (Leipzig), 1973, 253, 43-48. [all data]

Treboganov, Mitsner, et al., 1965
Treboganov, A.D.; Mitsner, B.I.; Zinkevich, E.P.; Kraevskii, A.A.; Preobrazhenskii, N.A., Macrocyclic compounds. I. Synthesis of cyclooctane and cyclododecane, Zh. Organ. Khim., 1965, 1, 1583-6. [all data]

Zakharkin and Zhigareva, 1963
Zakharkin, L.I.; Zhigareva, G.G., Dimerization of butadiene to cis-cis-1,5-cyclooctadiene catalyzed by pi-complex compounds of nickel, Izv. Akad. Nauk SSSR, 1963, Otd. Khim. Nauk 386 1963 1963. [all data]

Ziegler and Wilms, 1948
Ziegler, K.; Wilms, H., Stereoisomerism of Eight-membered Cycloolefin Rings, Naturwissenschaften, 1948, 35, 157-8. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Varushchenko, Pashchenko, et al., 1996
Varushchenko, R.M.; Pashchenko, L.L.; Druzhinina, A.I., Enthalpies of vaporization of some mono- and polycyclic hydrocarbons, Zh. Fiz. Khim., 1996, 70, 2, 228. [all data]


Notes

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