1,5-Cyclooctadiene, (Z,Z)-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C18H27ClRu (solution) + Benzeneethanamine, 3,4-dimethoxy- (solution) = C16H31ClP2Ru (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution)

By formula: C18H27ClRu (solution) + C10H15NO2 (solution) = C16H31ClP2Ru (solution) + C8H12 (solution)

Quantity Value Units Method Reference Comment
Δr-34.8 ± 0.2kcal/molRSCLuo, Zhu, et al., 1994solvent: Tetrahydrofuran; The enthalpy of solution of Ru(Cp*)(cod)(Cl)(cr) was measured as 4.9 ± 0.2 kcal/mol Luo, Nolan, et al., 1993.

Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]- (solution) = 21,5-Cyclooctadiene, (Z,Z)- (solution) + nickel (cr)

By formula: (Ni(C8H12)2) (solution) = 2C8H12 (solution) + Ni (cr)

Quantity Value Units Method Reference Comment
Δr-3.0 ± 1.0kcal/molRSCTolman, Reutter D.W., et al., 1976solvent: Toluene; The toluene solution contained catalytic amounts of carbon tetrachloride.

Rhodium, bis(η2-ethene)(2,4-pentanedionato-O,O')- (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution) = C13H19O2Rh (solution) + 2Ethylene (solution)

By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)

Quantity Value Units Method Reference Comment
Δr-2.2 ± 0.1kcal/molRSCJesse, Cordfunke, et al., 1979solvent: n-Heptane

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Luo, Zhu, et al., 1994
Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E.D.; Nolan, S.P.; Fagan, P.J., Organometallics, 1994, 13, 669. [all data]

Luo, Nolan, et al., 1993
Luo, L.; Nolan, S.P.; Fagan, P.J., Organometallics, 1993, 12, 4305. [all data]

Tolman, Reutter D.W., et al., 1976
Tolman, C.A.; Reutter D.W.; Seidel, W.C., J. Organometal. Chem., 1976, 117, C30. [all data]

Jesse, Cordfunke, et al., 1979
Jesse, A.C.; Cordfunke, E.H.P.; Ouweltjes, W., Thermochim. Acta, 1979, 30, 293. [all data]


Notes

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