Benzenamine, 2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)-


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C12F10N- + Hydrogen cation = Benzenamine, 2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)-

By formula: C12F10N- + H+ = C12HF10N

Quantity Value Units Method Reference Comment
Δr316.4 ± 2.0kcal/molIMREKoppel, Koppel, et al., 1998gas phase; Slightly revised value of Koppel, Taft, et al., 1994

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C12F10N- + Hydrogen cation = Benzenamine, 2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)-

By formula: C12F10N- + H+ = C12HF10N

Quantity Value Units Method Reference Comment
Δr316.4 ± 2.0kcal/molIMREKoppel, Koppel, et al., 1998gas phase; Slightly revised value of Koppel, Taft, et al., 1994

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin J.M. MILLER,BROCK UNIVERSITY,ONTARIO,CANADA
NIST MS number 54123

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References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Koppel, et al., 1998
Koppel, I.; Koppel, J.; Maria, P.C.; Gal, J.F.; Notario, R.; Vlasov, V.M.; Taft, R.W., Comparison of Bronsted acidities of neutral NH-acids in gas phase, dimethyl sulfoxide and water, Int. J. Mass Spectrom., 1998, 175, 1-2, 61-69, https://doi.org/10.1016/S0168-1176(98)00113-X . [all data]

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References