chlorotrimethylgermane


Condensed phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-299.9 ± 8.4kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -569. ± 17. kJ/mol for the estimated enthalpy of formation of [Ge(Me)3]2O(l) Baldwin, Lappert, et al., 1972.

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap33.5kJ/molRSCBaldwin, Lappert, et al., 1972MS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
36.3308.N/ADitsent, Skorokhodov, et al., 1972Based on data from 293. to 363. K.; AC
34.4307.SGGriffiths and Onyszchuk, 1961Based on data from 273. to 341. K.; AC

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Ditsent, Skorokhodov, et al., 1972
Ditsent, V.E.; Skorokhodov, I.I.; Terent'eva, N.A.; Zolotareva, M.N., Zh. Fiz. Khim., 1972, 46, 7, 1888. [all data]

Griffiths and Onyszchuk, 1961
Griffiths, J.E.; Onyszchuk, M., ORGANOGERMANIUM COMPOUNDS: PART I. THE INTERACTION OF HEXAMETHYLDIGERMOXANE AND TRIMETHYLMETHOXYGERMANE WITH BORON TRIFLUORIDE, Can. J. Chem., 1961, 39, 2, 339-347, https://doi.org/10.1139/v61-040 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References