Phenol, TMS derivative


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 152292

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Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySE-30180.1058.Shakirov, Tsypysheva, et al., 1988Column length: 20. m; Column diameter: 0.2 mm

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryVF-5MS1057.Zheng, 201130. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C
CapillaryDB-51051.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51051.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51053.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51053.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1038.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1039.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1039.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1041.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1046.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1046.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-51052.Isidorov and Vinogorova, 2003He, 5. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tstart: 50. C; Tend: 250. C
CapillaryDB-51053.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51053.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51056.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51057.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillarySE-521056.Lefevere, Verhaeghe, et al., 198925. m/0.32 mm/0.52 μm, He, 5. K/min; Tstart: 70. C; Tend: 270. C
CapillarySE-521055.Lefevere, Verhaeghe, et al., 198825. m/0.20 mm/0.40 μm, He, 5. K/min; Tstart: 50. C; Tend: 270. C
CapillaryUltra-21055.Tuchman, Bowers, et al., 198425. m/0.31 mm/0.52 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C
PackedOV-11039.Tanaka, Hine, et al., 1980N2, 100-120 mesh, 70. C @ 0.5 min, 28. K/min; Column length: 1.8 m; Tend: 290. C
PackedOV-11033.Mattsson and Petersson, 1977N2, Supelcoport, 4. K/min; Column length: 2. m; Tstart: 80. C; Tend: 240. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone1043.Peng, Yang, et al., 1991Program: not specified
PackedOV-1011039.Tanaka and Hine, 1982Program: not specified

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-51056.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 μm, He; Tstart: 50. C; Tend: 300. C
CapillaryHP-51055.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C
CapillaryMethyl Silicone1037.Tóth and Garay, 199410. m/0.32 mm/0.1 μm, He, 60. C @ 1. min, 12. K/min, 380. C @ 15. min

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySE-301055.Zimmermann, Lauterbach, et al., 1985Program: not specified

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shakirov, Tsypysheva, et al., 1988
Shakirov, L.G.; Tsypysheva, L.G.; Suleimamova, R.A.; Naimushin, A.I.; Tsypyshev, O.Yu., Gas chromatographic determination of the products of the synthesis of chlorine-substituted salicylic acids, Zh. Anal. Khim., 1988, 43, 143-146. [all data]

Zheng, 2011
Zheng, Yufang, Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]

Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T., The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase, Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024 . [all data]

Isidorov and Vinogorova, 2003
Isidorov, V.A.; Vinogorova, V.T., GC-MS analysis of compounds extracted from buds of Populus balsamifera and Populus nigra, Z. Naturforsch. C:, 2003, 58, 355-360. [all data]

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Lefevere, Verhaeghe, et al., 1988
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.M.; de Leenheer, A.P., Automated profiling of urinary organic acids by dual-column gas chromatography and gas chromatography/mass spectrometry, Biomed. Environ. Mass Spectrom., 1988, 15, 6, 311-322, https://doi.org/10.1002/bms.1200150603 . [all data]

Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W., Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column, J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198 . [all data]

Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B., Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds, Clin. Chem., 1980, 26, 13, 1839-1846. [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Maltby, D., Prediction of retention indexes. III. Silylated derivatives of polar compounds, J. Chromatogr., 1991, 586, 1, 113-129, https://doi.org/10.1016/0021-9673(91)80029-G . [all data]

Tanaka and Hine, 1982
Tanaka, K.; Hine, D.G., Compilation of Gas Chromatographic Retention Indices of 163 Metabolically Important Organic Acids, and Their Use in Detection of Patients with Organic Acidurias, J. Chromatogr., 1982, 239, 301-322, https://doi.org/10.1016/S0021-9673(00)81990-1 . [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Tóth and Garay, 1994
Tóth, T.; Garay, F., Separation of novolac resin oligomers and related industrial materials by high temperature capillary gas chromatography, J. Hi. Res. Chromatogr., 1994, 17, 3, 177-179, https://doi.org/10.1002/jhrc.1240170312 . [all data]

Zimmermann, Lauterbach, et al., 1985
Zimmermann, V.; Lauterbach, M.; Jaeger, G., Analytical characterization phenolic compounds obtained from phenosolvan-extracts by use of gas-chromatography with capillary columns, Chem. Tech. (Leipzig), 1985, 37, 11, 476-478. [all data]


Notes

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