Tri-ruthenium dodecacarbonyl
- Formula: C12O12Ru3
- Molecular weight: 639.33
- IUPAC Standard InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
- CAS Registry Number: 15243-33-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Ru3(CO)12; Ruthenium, dodecacarbonyltri-, triangulo; Ruthenium,dodecacarbonyltri-; Ruthenium carbonyl
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -433.9 ± 6.3 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -429.7 ± 5.7 | kcal/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -459.0 ± 4.1 | kcal/mol | Review | Martinho Simões | |
ΔfH°solid | -454.8 ± 3.2 | kcal/mol | Review | Martinho Simões | Selected data |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 25.1 ± 4.8 | kcal/mol | TD-HFC | Baev, Connor, et al., 1981 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(solution) + 3 (solution) = 3C5O5Ru (solution)
By formula: C12O12Ru3 (solution) + 3CO (solution) = 3C5O5Ru (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -3.11 ± 0.26 | kcal/mol | EqS | Koelliker and Bor, 1991 | solvent: Isooctane; Temperature range: 373-448 K |
ΔrH° | -6.48 ± 0.45 | kcal/mol | EqS | Bor, 1986 | solvent: n-Hexane; Temperature range: ca. 348-448 K |
By formula: C12O12Ru3 (cr) = 12CO (g) + 3Ru (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 137.8 ± 3.1 | kcal/mol | TD-HFC | Baev, Connor, et al., 1981 | |
ΔrH° | 142.0 ± 4.1 | kcal/mol | TD-HFC | Connor, Skinner, et al., 1973 | Please also see Pedley and Rylance, 1977. |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Baev, Connor, et al., 1981
Baev, A.K.; Connor, J.A.; El-Saied, N.I.; Skinner H.A.,
J. Organometal. Chem., 1981, 213, 151. [all data]
Koelliker and Bor, 1991
Koelliker, R.; Bor, G.,
J. Organometal. Chem., 1991, 417, 439. [all data]
Bor, 1986
Bor, G.,
Pure & Appl. Chem., 1986, 58, 543. [all data]
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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