potassium cyanide


Gas Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3000. - 6000.
A 61.26590
B 0.509972
C -0.089375
D 0.005515
E -4.709570
F 51.84110
G 315.8810
H 79.49600
ReferenceChase, 1998
Comment Data last reviewed in March, 1966
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
3000.61.62384.6331.5159.3
3100.61.66386.6333.3165.5
3200.61.70388.6335.0171.6
3300.61.74390.5336.6177.8
3400.61.78392.3338.2184.0
3500.61.81394.1339.8190.2
3600.61.84395.9341.3196.4
3700.61.86397.6342.8202.5
3800.61.89399.2344.3208.7
3900.61.91400.8345.7214.9
4000.61.93402.4347.1221.1
4100.61.95403.9348.5227.3
4200.61.97405.4349.8233.5
4300.61.99406.9351.1239.7
4400.62.01408.3352.4245.9
4500.62.02409.7353.7252.1
4600.62.03411.1354.9258.3
4700.62.05412.4356.1264.5
4800.62.06413.7357.3270.7
4900.62.07415.0358.5276.9
5000.62.08416.2359.6283.1
5100.62.09417.5360.7289.3
5200.62.10418.7361.8295.5
5300.62.11419.9362.9301.8
5400.62.12421.0364.0308.0
5500.62.13422.2365.0314.2
5600.62.14423.3366.1320.4
5700.62.15424.4367.1326.6
5800.62.15425.5368.1332.8
5900.62.16426.5369.1339.0
6000.62.17427.6370.0345.3

References

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), References