HS anion
- Formula: HS-
- Molecular weight: 33.073
- CAS Registry Number: 15035-72-0
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Clustering reactions
By formula: HS- + CHN = (HS- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.9 ± 4.2 | kJ/mol | IMRE | Meot-ner, 1988 | gas phase; See also H2S..CN-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 62.8 ± 4.2 | kJ/mol | IMRE | Meot-ner, 1988 | gas phase; See also H2S..CN-; B |
By formula: HS- + CH4O = (HS- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.0 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: HS- + C2H3F3O = (HS- C2H3F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 112.1 ± 2.1 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.1 ± 6.3 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
By formula: HS- + C2H6O = (HS- C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.20 ± 0.42 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B,M |
![]() | 67.8 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 82.8 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 1.7 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
![]() | 43.1 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: HS- + C4H5N = (HS- C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 96.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 65.7 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: HS- + C4H10O = (HS- C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.3 ± 1.3 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 5.0 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
By formula: HS- + C6H11NO3 = (HS- C6H11NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: HS- + C6H11NO3 = (HS- C6H11NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 ± 8.4 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: HS- + H2O = (HS- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
![]() | 59.4 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.2 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 78.2 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 36. ± 8.4 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: (HS- H2O) + H2O = (HS-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.7 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 52.7 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 85.4 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: (HS- 2H2O) + H2O = (HS-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 49.0 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.3 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
![]() | 98.3 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: HS- + H2S = (HS- H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.4 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: (HS- 4294967295S) + S = HS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 502.62 | kJ/mol | N/A | Chaibi, Delsart, et al., 2006 | gas phase; For H(32)S-. Given: 2.3147282(17) eV; B |
![]() | 502.83 ± 0.75 | kJ/mol | Ther | Breyer, Frey, et al., 1981 | gas phase; B |
![]() | 503.8 ± 9.2 | kJ/mol | Ther | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
![]() | 358.0 | kJ/mol | Ther | Shiell, Hu, et al., 1900 | gas phase; 0K:350.125±0.009 kcal/mol, corr to 298K from Gurvich, Veyts, et al., With EA( Breyer, Frey, et al., 1981)BDE(0K)=89.97±0.05; B |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-ner, 1988
Meot-ner, M.,
Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-,
J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022
. [all data]
Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M.,
Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities.,
J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079
. [all data]
Chaibi, Delsart, et al., 2006
Chaibi, W.; Delsart, C.; Drag, C.; Blondel, C.,
High precision measurement of the (SH)-S-32 electron affinity by laser detachment microscopy,
J. Molec. Spectros., 2006, 239, 1, 11-15, https://doi.org/10.1016/j.jms.2006.05.012
. [all data]
Breyer, Frey, et al., 1981
Breyer, F.; Frey, P.; Hotop, H.,
High Resolution Photoelectron Spectrometry of Negative Ions: Rotational Transitions in Laser-Photodetachment of OH-, SH-, and SD-,
Z. Phys. A, 1981, 300, 1, 7, https://doi.org/10.1007/BF01412609
. [all data]
Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr.,
The gas phase acidity scale from methanol to phenol,
J. Am. Chem. Soc., 1979, 101, 6047. [all data]
Shiell, Hu, et al., 1900
Shiell, R.C.; Hu, X.K.; Hu, Q.J.; Hepburn, J.W.,
A determination of the bond dissociation energy (D-0(H-SH)): Threshold ion-pair production spectroscopy (TIPPS) of a triatomic molecule,
J. Phys. Chem. A, 1900, 104, 19, 4339-4342, https://doi.org/10.1021/jp000025k
. [all data]
Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.,
Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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