Aluminum ion (1+)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar149.96J/mol*KReviewChase, 1998Data last reviewed in June, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Aluminum ion (1+) • Acetone) + Acetone = (Aluminum ion (1+) • 2Acetone)

By formula: (Al+ • C3H6O) + C3H6O = (Al+ • 2C3H6O)

Quantity Value Units Method Reference Comment
Δr118.kJ/molHPMSBauschlicher, Bouchard, et al., 1991gas phase; laser desorption; M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KHPMSBauschlicher, Bouchard, et al., 1991gas phase; laser desorption; M

(Aluminum ion (1+) • 2Water) + Water = (Aluminum ion (1+) • 3Water)

By formula: (Al+ • 2H2O) + H2O = (Al+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
63.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • 3Water) + Water = (Aluminum ion (1+) • 4Water)

By formula: (Al+ • 3H2O) + H2O = (Al+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
52.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • Water) + Water = (Aluminum ion (1+) • 2Water)

By formula: (Al+ • H2O) + H2O = (Al+ • 2H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+5.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

Aluminum ion (1+) + Water = (Aluminum ion (1+) • Water)

By formula: Al+ + H2O = (Al+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
104. (+15.,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • 10Aluminum) + Aluminum = (Aluminum ion (1+) • 11Aluminum)

By formula: (Al+ • 10Al) + Al = (Al+ • 11Al)

Quantity Value Units Method Reference Comment
Δr300.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 11Aluminum) + Aluminum = (Aluminum ion (1+) • 12Aluminum)

By formula: (Al+ • 11Al) + Al = (Al+ • 12Al)

Quantity Value Units Method Reference Comment
Δr340.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 12Aluminum) + Aluminum = (Aluminum ion (1+) • 13Aluminum)

By formula: (Al+ • 12Al) + Al = (Al+ • 13Al)

Quantity Value Units Method Reference Comment
Δr300.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 13Aluminum) + Aluminum = (Aluminum ion (1+) • 14Aluminum)

By formula: (Al+ • 13Al) + Al = (Al+ • 14Al)

Quantity Value Units Method Reference Comment
Δr250.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 14Aluminum) + Aluminum = (Aluminum ion (1+) • 15Aluminum)

By formula: (Al+ • 14Al) + Al = (Al+ • 15Al)

Quantity Value Units Method Reference Comment
Δr280.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 15Aluminum) + Aluminum = (Aluminum ion (1+) • 16Aluminum)

By formula: (Al+ • 15Al) + Al = (Al+ • 16Al)

Quantity Value Units Method Reference Comment
Δr290.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 9Aluminum) + Aluminum = (Aluminum ion (1+) • 10Aluminum)

By formula: (Al+ • 9Al) + Al = (Al+ • 10Al)

Quantity Value Units Method Reference Comment
Δr280.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 6Aluminum) + Aluminum = (Aluminum ion (1+) • 7Aluminum)

By formula: (Al+ • 6Al) + Al = (Al+ • 7Al)

Quantity Value Units Method Reference Comment
Δr180.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 8Aluminum) + Aluminum = (Aluminum ion (1+) • 9Aluminum)

By formula: (Al+ • 8Al) + Al = (Al+ • 9Al)

Quantity Value Units Method Reference Comment
Δr270.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

Aluminum ion (1+) + Ethylene = (Aluminum ion (1+) • Ethylene)

By formula: Al+ + C2H4 = (Al+ • C2H4)

Quantity Value Units Method Reference Comment
Δr54.4 ± 8.4kJ/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

Aluminum ion (1+) + Acetylene = (Aluminum ion (1+) • Acetylene)

By formula: Al+ + C2H2 = (Al+ • C2H2)

Quantity Value Units Method Reference Comment
Δr54.4 ± 8.4kJ/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

Aluminum ion (1+) + Ethane = (Aluminum ion (1+) • Ethane)

By formula: Al+ + C2H6 = (Al+ • C2H6)

Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

(Aluminum ion (1+) • 5Aluminum) + Aluminum = (Aluminum ion (1+) • 6Aluminum)

By formula: (Al+ • 5Al) + Al = (Al+ • 6Al)

Quantity Value Units Method Reference Comment
Δr431.4kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 2Aluminum) + Aluminum = (Aluminum ion (1+) • 3Aluminum)

By formula: (Al+ • 2Al) + Al = (Al+ • 3Al)

Quantity Value Units Method Reference Comment
Δr196.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 3Aluminum) + Aluminum = (Aluminum ion (1+) • 4Aluminum)

By formula: (Al+ • 3Al) + Al = (Al+ • 4Al)

Quantity Value Units Method Reference Comment
Δr248.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 4Aluminum) + Aluminum = (Aluminum ion (1+) • 5Aluminum)

By formula: (Al+ • 4Al) + Al = (Al+ • 5Al)

Quantity Value Units Method Reference Comment
Δr231.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • Aluminum) + Aluminum = (Aluminum ion (1+) • 2Aluminum)

By formula: (Al+ • Al) + Al = (Al+ • 2Al)

Quantity Value Units Method Reference Comment
Δr108.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

Aluminum ion (1+) + Aluminum = (Aluminum ion (1+) • Aluminum)

By formula: Al+ + Al = (Al+ • Al)

Quantity Value Units Method Reference Comment
Δr87.0kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

Aluminum ion (1+) + Pyridine = (Aluminum ion (1+) • Pyridine)

By formula: Al+ + C5H5N = (Al+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr190. ± 10.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Aluminum ion (1+) + 1,3-Diazine = (Aluminum ion (1+) • 1,3-Diazine)

By formula: Al+ + C4H4N2 = (Al+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr159. ± 5.9kJ/molCIDTAmunugama and Rodgers, 2001RCD

Aluminum ion (1+) + Methyl fluoride = (Aluminum ion (1+) • Methyl fluoride)

By formula: Al+ + CH3F = (Al+ • CH3F)

Quantity Value Units Method Reference Comment
Δr90.0 ± 8.4kJ/molEqGBouchard, Brenner, et al., 1997RCD

Aluminum ion (1+) + Formaldehyde = (Aluminum ion (1+) • Formaldehyde)

By formula: Al+ + CH2O = (Al+ • CH2O)

Quantity Value Units Method Reference Comment
Δr115. ± 10.kJ/molEqGBouchard, Brenner, et al., 1997RCD

Aluminum ion (1+) + Benzene = (Aluminum ion (1+) • Benzene)

By formula: Al+ + C6H6 = (Al+ • C6H6)

Quantity Value Units Method Reference Comment
Δr147. ± 7.9kJ/molRAKDunbar, Klippenstein, et al., 1996RCD

Aluminum ion (1+) + Pyrrole = (Aluminum ion (1+) • Pyrrole)

By formula: Al+ + C4H5N = (Al+ • C4H5N)

Quantity Value Units Method Reference Comment
Δr184.kJ/molRAKGapeev and Yang, 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Bauschlicher, Bouchard, et al., 1991
Bauschlicher, C.W.; Bouchard, F.; Hepburn, J.W.; McMahon, T.B.; Surjasasmita, I.; Roth, L.M.; Gord, J.R., On the Structure of Al(Acetone)2+, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 15, https://doi.org/10.1016/0168-1176(91)85094-3 . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]

Jarrold, Ray, et al., 1990
Jarrold, M.F.; Ray, U.; Bower, J.E.; Creegan, K.M., Photodissociation of Metal Cluster Ions. Dissociation Energies and Optical Spectroscopy, J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2537, https://doi.org/10.1039/ft9908602537 . [all data]

Stockigt, Schwarz, et al., 1996
Stockigt, D.; Schwarz, J.; Schwarz, H., Theoretical and Experimental Studies on the Bond Dissociation Energies of Al(methane)+, Al(acetylene)+, Al(ethene)+, and Al(ethane)+, J. Phys. Chem., 1996, 100, 21, 8786, https://doi.org/10.1021/jp960060k . [all data]

Hanley, Ruatta, et al., 1987
Hanley, L.; Ruatta, S.A.; Anderson, S.L., Collision - Induced Dissciation of Aluminum Cluster Ions: Fragmentation Patterns, Bond Energies, and Structures for Al2+ - Al7+, J. Chem. Phys., 1987, 87, 1, 260, https://doi.org/10.1063/1.453623 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Bouchard, Brenner, et al., 1997
Bouchard, F.; Brenner, V.; Carra, C.; Hepburn, J.W.; Koyanagi, G.K.; McMahon, T.B.; Ohanessian, G.; Peschke, M., Energetics and Structure of Complexes of Al+ with Small Organic Molecules in the Gas Phase, J. Phys. Chem. A, 1997, 101, 33, 5885, https://doi.org/10.1021/jp9703465 . [all data]

Dunbar, Klippenstein, et al., 1996
Dunbar, R.C.; Klippenstein, S.J.; Hrusak, J.; Stockigt, D.; Schwarz, H., Binding Energy of Al(C6H6)+ from the Analysis of Radiative Association Kinetics, J. Am. Chem. Soc., 1996, 118, 22, 5277, https://doi.org/10.1021/ja953235x . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]


Notes

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