Nickel ion (1+)

• Formula: Ni⁺
• Molecular weight: 58.6929
• IUPAC Standard InChI: InChI=1S/Ni/q+1 Copy

  
• IUPAC Standard InChIKey: YWMAPNNZOCSAPF-UHFFFAOYSA-N Copy
• CAS Registry Number: 14903-34-5
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Nickel cation
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data (reactions 1 to 50)
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data: reactions 51 to 53
  • Ion clustering data
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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2He) + He = (Ni⁺ • 3He)

( • ) +  = ( • 2)

By formula: (Ni⁺ • He) + He = (Ni⁺ • 2He)

 +  = ( • )

By formula: Ni⁺ + Ne = (Ni⁺ • Ne)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + He = (Ni⁺ • He)

 +  = ( • )

By formula: Ni⁺ + CO = (Ni⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • Ne) + Ne = (Ni⁺ • 2Ne)

 +  = ( • )

By formula: Ni⁺ + H₂O = (Ni⁺ • H₂O)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2CO) + CO = (Ni⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ni⁺ • 3CO) + CO = (Ni⁺ • 4CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • CO) + CO = (Ni⁺ • 2CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • H₂O) + H₂O = (Ni⁺ • 2H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + C₂H₄ = (Ni⁺ • C₂H₄)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + C₂H₂ = (Ni⁺ • C₂H₂)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • C₆H₆) + C₆H₆ = (Ni⁺ • 2C₆H₆)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + C₆H₆ = (Ni⁺ • C₆H₆)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2H₃N) + H₃N = (Ni⁺ • 3H₃N)

( • ) +  = ( • 2)

By formula: (Ni⁺ • H₃N) + H₃N = (Ni⁺ • 2H₃N)

 +  = ( • )

By formula: Ni⁺ + H₃N = (Ni⁺ • H₃N)

 +  = ( • )

By formula: Ni⁺ + CH₃ = (Ni⁺ • CH₃)

( • ) +  = ( • 2)

By formula: (Ni⁺ • NO) + NO = (Ni⁺ • 2NO)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2N₂) + N₂ = (Ni⁺ • 3N₂)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ni⁺ • 3N₂) + N₂ = (Ni⁺ • 4N₂)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • N₂) + N₂ = (Ni⁺ • 2N₂)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2H₂O) + H₂O = (Ni⁺ • 3H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ni⁺ • 3H₂O) + H₂O = (Ni⁺ • 4H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + NO = (Ni⁺ • NO)

Enthalpy of reaction

( • 10) +  = ( • 11)

By formula: (Ni⁺ • 10Ni) + Ni = (Ni⁺ • 11Ni)

Enthalpy of reaction

( • 11) +  = ( • 12)

By formula: (Ni⁺ • 11Ni) + Ni = (Ni⁺ • 12Ni)

Enthalpy of reaction

( • 12) +  = ( • 13)

By formula: (Ni⁺ • 12Ni) + Ni = (Ni⁺ • 13Ni)

Enthalpy of reaction

( • 13) +  = ( • 14)

By formula: (Ni⁺ • 13Ni) + Ni = (Ni⁺ • 14Ni)

Enthalpy of reaction

( • 14) +  = ( • 15)

By formula: (Ni⁺ • 14Ni) + Ni = (Ni⁺ • 15Ni)

Enthalpy of reaction

( • 15) +  = ( • 16)

By formula: (Ni⁺ • 15Ni) + Ni = (Ni⁺ • 16Ni)

Enthalpy of reaction

( • 16) +  = ( • 17)

By formula: (Ni⁺ • 16Ni) + Ni = (Ni⁺ • 17Ni)

Enthalpy of reaction

( • 9) +  = ( • 10)

By formula: (Ni⁺ • 9Ni) + Ni = (Ni⁺ • 10Ni)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + N₂ = (Ni⁺ • N₂)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ni⁺ • 2Ni) + Ni = (Ni⁺ • 3Ni)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ni⁺ • 3Ni) + Ni = (Ni⁺ • 4Ni)

Enthalpy of reaction

( • 4) +  = ( • 5)

By formula: (Ni⁺ • 4Ni) + Ni = (Ni⁺ • 5Ni)

Enthalpy of reaction

( • 5) +  = ( • 6)

By formula: (Ni⁺ • 5Ni) + Ni = (Ni⁺ • 6Ni)

Enthalpy of reaction

( • 6) +  = ( • 7)

By formula: (Ni⁺ • 6Ni) + Ni = (Ni⁺ • 7Ni)

Enthalpy of reaction

( • 7) +  = ( • 8)

By formula: (Ni⁺ • 7Ni) + Ni = (Ni⁺ • 8Ni)

Enthalpy of reaction

( • 8) +  = ( • 9)

By formula: (Ni⁺ • 8Ni) + Ni = (Ni⁺ • 9Ni)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ni⁺ • Ni) + Ni = (Ni⁺ • 2Ni)

Enthalpy of reaction

 +  = ( • )

By formula: Ni⁺ + Ni = (Ni⁺ • Ni)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ni⁺ • 3H₃N) + H₃N = (Ni⁺ • 4H₃N)

 +  = ( • )

By formula: Ni⁺ + C₂H₆ = (Ni⁺ • C₂H₆)

( • ) +  = ( • 2)

By formula: (Ni⁺ • C₂H₄) + C₂H₄ = (Ni⁺ • 2C₂H₄)

( • ) +  = ( • 2)

By formula: (Ni⁺ • C₄H₅N) + C₄H₅N = (Ni⁺ • 2C₄H₅N)

 +  = ( • )

By formula: Ni⁺ + C₅H₅N = (Ni⁺ • C₅H₅N)

 +  = ( • )

By formula: Ni⁺ + CS = (Ni⁺ • CS)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Khan, Steele, et al., 1995
Khan, F.A.; Steele, D.L.; Armentrout, P.B., Ligand effects in organometallic thermochemistry: The sequential bond energies of Ni(CO)_x⁺ and Ni(N₂)_x⁺ (x = 1-4) and Ni(NO)_x⁺ (x = 1-3) [Data derived from reported bond energies taking value of 8.273±0.046 eV for IE[Ni(CO)₄]], J. Phys. Chem., 1995, 99, 7819. [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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