Furan, 2,3-dihydro-5-methyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-29.30kcal/molEqkCocks and Egger, 1973 
Δfgas-31.11 ± 0.84kcal/molCcbPihlaja and Heikkila, 1969 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-39.43 ± 0.54kcal/molCcbPihlaja and Heikkila, 1969 
Quantity Value Units Method Reference Comment
Δcliquid-704.09 ± 0.54kcal/molCcbPihlaja and Heikkila, 1969Corresponding Δfliquid = -39.43 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil355.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil354.65KN/APaul and Tchelitcheff, 1950Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δvap8.3 ± 0.3kcal/molVPihlaja and Heikkila, 1969ALS
Δvap8.32kcal/molN/APihlaja and Heikkila, 1969DRB

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cocks and Egger, 1973
Cocks, A.T.; Egger, K.W., Gas-phase thermal unimolecular isomerizations of acetylcyclopropane. Part I. The equilibrium between 2,3-dihydro-5-methylfuran and acetylcyclopropane, J. Chem. Soc. Perkin Trans. 2, 1973, 197-199. [all data]

Pihlaja and Heikkila, 1969
Pihlaja, K.; Heikkila, J., Heats of formation of cyclic vinyl ethers, Suom. Kemistil. B, 1969, 42, 338-342. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Paul and Tchelitcheff, 1950
Paul, R.; Tchelitcheff, S., The Methylenyl-2-tetrahydrofuran. Application to the Preparation of beta-Ethylenic Alcohols. Synthesis of Sylvanne, Bull. Soc. Chim. Fr., 1950, 1950, 520. [all data]


Notes

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