8-Hydroxyquinoline

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas1.6 ± 0.41kcal/molCcbRibeiro Da Silva, Monte, et al., 1989Author was aware that data differs from previously reported values
Δfgas6.60 ± 0.62kcal/molCcrSakiyama, Nakano, et al., 1975 

Phase change data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus347.65KN/AManske, Ledingham, et al., 1949Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub23. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
540.20.989Aldrich Chemical Company Inc., 1990BS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
26.00 ± 0.41308. to 328.MEHorton and Wendlandt, 1963See also Cox and Pilcher, 1970 and Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
9.63345.7ACWANG, TAN, et al., 2008AC
5.28346.8N/AZorel, Costalonga, et al., 2001AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro Da Silva, Monte, et al., 1989
Ribeiro Da Silva, M.A.V.; Monte, M.J.S.; Matos, M.A.R., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 8-hydroxyquinoline, 5-nitro-8-hydroxyquinoline, and 2-methyl-8-hydroxyquinoline, J. Chem. Thermodyn., 1989, 21, 159-166. [all data]

Sakiyama, Nakano, et al., 1975
Sakiyama, M.; Nakano, T.; Seki, S., Enthalpies of combustion of organic compounds. I. 8-Quinolinol., Bull. Chem. Soc. Jpn., 1975, 48, 1705-1708. [all data]

Manske, Ledingham, et al., 1949
Manske, R.H.F.; Ledingham, A.E.; Ashford, W.R., The preparation of quinolins by a modified Skraup reaction., Can. J. Res., 1949, 27F, 359. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Horton and Wendlandt, 1963
Horton, G.R.; Wendlandt, W.W., The heats of dissociation of the 8-quinolinol and substituted 8-quinolinol metal chelates of uranium (VI), thorium (IV) and scandium (III), J. Inorg. Nucl. Chem., 1963, 25, 241-245. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

WANG, TAN, et al., 2008
WANG, Shao-Xu; TAN, Zhi-Cheng; LI, Yan-Sheng; TONG, Bo; LI, Ying; SHI, Quan; ZHANG, Jing-Nan, Thermodynamic Study of 8-Hydroxyquinoline by Adiabatic Calorimetry and Thermal Analysis, Chin. J. Chem., 2008, 26, 11, 2016-2020, https://doi.org/10.1002/cjoc.200890360 . [all data]

Zorel, Costalonga, et al., 2001
Zorel, H.E., Jr.; Costalonga, A.G.C.; Crespi, M.S.; Ribiero, C.A., Quim. Nova, 2001, 24, 5, 599. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, References