Lithium anion
- Formula: Li-
- Molecular weight: 6.942
- CAS Registry Number: 14808-04-9
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 356.01 ± 0.10 | kcal/mol | D-EA | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 350.88 ± 0.32 | kcal/mol | H-TS | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
0.618069 ± 0.000044 | N/A | Haeffler, Hanstorp, et al., 1996 | Given: 0.618049(20) eV |
0.61759 ± 0.00022 | LPD | Dellwo, Liu, et al., 1992 | |
0.6200 ± 0.0070 | LPES | Patterson, Hotop, et al., 1974 | |
0.61820 ± 0.00050 | LPD | Feldmann, 1976 |
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 356.01 ± 0.10 | kcal/mol | D-EA | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 350.88 ± 0.32 | kcal/mol | H-TS | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Haeffler, Hanstorp, et al., 1996
Haeffler, G.; Hanstorp, G.; Kiyan, I.; Klinkm|ller, A.E.; Ljungblad, U.; Pegg, D.J.,
Electron affinity of Li: A state-selective measurement,
Phys. Rev. A, 1996, 53, 6, 4127-4131, https://doi.org/10.1103/PhysRevA.53.4127
. [all data]
Dellwo, Liu, et al., 1992
Dellwo, J.; Liu, Y.; Pegg, D.J.; Alton, G.D.,
Near-Threshold Photodetachment of the Li- Ion,
Phys. Rev. A, 1992, 45, 3, 1544, https://doi.org/10.1103/PhysRevA.45.1544
. [all data]
Patterson, Hotop, et al., 1974
Patterson, T.A.; Hotop, H.; Kasdan, A.; Norcross, D.W.; Lineberger, W.C.,
Resonances in Alkali Negative-Ion Photodetachment and Electron Affinities of the Corresponding Neutrals,
Phys. Rev. Lett., 1974, 32, 5, 189, https://doi.org/10.1103/PhysRevLett.32.189
. [all data]
Feldmann, 1976
Feldmann, D.,
Infrared Photodetachment Threshold Measurements: Li- and P-,
Z. Physik A, 1976, 277, 1, 19-25, https://doi.org/10.1007/BF01547496
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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