Nitrogen oxide anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

Nitrogen oxide anion + Methane, nitro- = (Nitrogen oxide anion • Methane, nitro-)

By formula: NO2- + CH3NO2 = (NO2- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr14.50 ± 0.50kcal/molTDAsWincel, 2003gas phase; B
Δr14.30 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr15.5cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr7.80kcal/molTDAsWincel, 2003gas phase; B
Δr9.70 ± 0.20kcal/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Methyl Alcohol = (Nitrogen oxide anion • Methyl Alcohol)

By formula: NO2- + CH4O = (NO2- • CH4O)

Quantity Value Units Method Reference Comment
Δr17.40 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.8cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr9.70 ± 0.40kcal/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Carbon dioxide = (Nitrogen oxide anion • Carbon dioxide)

By formula: NO2- + CO2 = (NO2- • CO2)

Quantity Value Units Method Reference Comment
Δr7.30 ± 0.20kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Δr9.30 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr17.2cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Δr24.2cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr2.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B
Δr2.00 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Nitrogen oxide anion • Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 2Carbon dioxide)

By formula: (NO2- • CO2) + CO2 = (NO2- • 2CO2)

Quantity Value Units Method Reference Comment
Δr6.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr1.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 2Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 3Carbon dioxide)

By formula: (NO2- • 2CO2) + CO2 = (NO2- • 3CO2)

Quantity Value Units Method Reference Comment
Δr6.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.3cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-0.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 3Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 4Carbon dioxide)

By formula: (NO2- • 3CO2) + CO2 = (NO2- • 4CO2)

Quantity Value Units Method Reference Comment
Δr6.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-1.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 4Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 5Carbon dioxide)

By formula: (NO2- • 4CO2) + CO2 = (NO2- • 5CO2)

Quantity Value Units Method Reference Comment
Δr5.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.3cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-1.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 5Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 6Carbon dioxide)

By formula: (NO2- • 5CO2) + CO2 = (NO2- • 6CO2)

Quantity Value Units Method Reference Comment
Δr4.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.1cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 6Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 7Carbon dioxide)

By formula: (NO2- • 6CO2) + CO2 = (NO2- • 7CO2)

Quantity Value Units Method Reference Comment
Δr4.4 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion • 7Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion • 8Carbon dioxide)

By formula: (NO2- • 7CO2) + CO2 = (NO2- • 8CO2)

Quantity Value Units Method Reference Comment
Δr4.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

Nitrogen oxide anion + Acetonitrile = (Nitrogen oxide anion • Acetonitrile)

By formula: NO2- + C2H3N = (NO2- • C2H3N)

Quantity Value Units Method Reference Comment
Δr13.40 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr15.3cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr8.80 ± 0.20kcal/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Acetic acid = C2H4NO4-

By formula: NO2- + C2H4O2 = C2H4NO4-

Quantity Value Units Method Reference Comment
Δr12.20 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase; B

Nitrogen oxide anion + Ethane, nitro- = C2H5N2O4-

By formula: NO2- + C2H5NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Δr15.80 ± 0.50kcal/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr8.90kcal/molTDAsWincel, 2004gas phase; B

Nitrogen oxide anion + Nitric acid, ethyl ester = (Nitrogen oxide anion • Nitric acid, ethyl ester)

By formula: NO2- + C2H5NO3 = (NO2- • C2H5NO3)

Quantity Value Units Method Reference Comment
Δr20.9kcal/molHPMSWlodek, Luczynski, et al., 1983gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr35.3cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M

(Nitrogen oxide anion • Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion • 2Nitric acid, ethyl ester)

By formula: (NO2- • C2H5NO3) + C2H5NO3 = (NO2- • 2C2H5NO3)

Quantity Value Units Method Reference Comment
Δr8.5kcal/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr12.8cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(Nitrogen oxide anion • 2Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion • 3Nitric acid, ethyl ester)

By formula: (NO2- • 2C2H5NO3) + C2H5NO3 = (NO2- • 3C2H5NO3)

Quantity Value Units Method Reference Comment
Δr7.3kcal/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr14.1cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

Nitrogen oxide anion + Dimethyl Sulfoxide = (Nitrogen oxide anion • Dimethyl Sulfoxide)

By formula: NO2- + C2H6OS = (NO2- • C2H6OS)

Quantity Value Units Method Reference Comment
Δr19.2 ± 1.0kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/ASieck, 1985gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.7 ± 1.0kcal/molTDAsSieck, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
8.7420.PHPMSSieck, 1985gas phase; Entropy change calculated or estimated; M

Nitrogen oxide anion + Acetone = (Nitrogen oxide anion • Acetone)

By formula: NO2- + C3H6O = (NO2- • C3H6O)

Quantity Value Units Method Reference Comment
Δr15.90 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.9cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr8.20 ± 0.20kcal/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Propanoic acid = C3H6NO4-

By formula: NO2- + C3H6O2 = C3H6NO4-

Quantity Value Units Method Reference Comment
Δr12.50 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

Nitrogen oxide anion + Butanoic acid = C4H8NO4-

By formula: NO2- + C4H8O2 = C4H8NO4-

Quantity Value Units Method Reference Comment
Δr13.30 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

Nitrogen oxide anion + 2-Propanol, 2-methyl- = (Nitrogen oxide anion • 2-Propanol, 2-methyl-)

By formula: NO2- + C4H10O = (NO2- • C4H10O)

Quantity Value Units Method Reference Comment
Δr19.60 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr29.5cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr10.80 ± 0.30kcal/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Benzene, 1-fluoro-4-nitro- = (Nitrogen oxide anion • Benzene, 1-fluoro-4-nitro-)

By formula: NO2- + C6H4FNO2 = (NO2- • C6H4FNO2)

Quantity Value Units Method Reference Comment
Δr15.0 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr9.1 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, 1,3-dinitro- = (Nitrogen oxide anion • Benzene, 1,3-dinitro-)

By formula: NO2- + C6H4N2O4 = (NO2- • C6H4N2O4)

Quantity Value Units Method Reference Comment
Δr21.2 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.6cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr14.4 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, nitro- = (Nitrogen oxide anion • Benzene, nitro-)

By formula: NO2- + C6H5NO2 = (NO2- • C6H5NO2)

Quantity Value Units Method Reference Comment
Δr14.2 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr17.5cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr8.9 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzonitrile, 3,5-dinitro- = (Nitrogen oxide anion • Benzonitrile, 3,5-dinitro-)

By formula: NO2- + C7H3N3O4 = (NO2- • C7H3N3O4)

Quantity Value Units Method Reference Comment
Δr23.5 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.7cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr16.4 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzonitrile, 3-nitro- = (Nitrogen oxide anion • Benzonitrile, 3-nitro-)

By formula: NO2- + C7H4N2O2 = (NO2- • C7H4N2O2)

Quantity Value Units Method Reference Comment
Δr20.0 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr14.0 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzonitrile, 4-nitro- = (Nitrogen oxide anion • Benzonitrile, 4-nitro-)

By formula: NO2- + C7H4N2O2 = (NO2- • C7H4N2O2)

Quantity Value Units Method Reference Comment
Δr18.8 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.5cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr12.4 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, 1-methoxy-4-nitro- = (Nitrogen oxide anion • Benzene, 1-methoxy-4-nitro-)

By formula: NO2- + C7H7NO3 = (NO2- • C7H7NO3)

Quantity Value Units Method Reference Comment
Δr20.5 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr12.6 ± 2.0kcal/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, 1-methoxy-3-nitro- = (Nitrogen oxide anion • Benzene, 1-methoxy-3-nitro-)

By formula: NO2- + C7H7NO3 = (NO2- • C7H7NO3)

Quantity Value Units Method Reference Comment
Δr20.5kcal/molPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr26.3cal/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M

Nitrogen oxide anion + Nitrous acid = (Nitrogen oxide anion • Nitrous acid)

By formula: NO2- + HNO2 = (NO2- • HNO2)

Quantity Value Units Method Reference Comment
Δr32.5 ± 1.0kcal/molTDAsLee, Keesee, et al., 1980gas phase; B

Nitrogen oxide anion + Water = (Nitrogen oxide anion • Water)

By formula: NO2- + H2O = (NO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr16. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr20.3cal/mol*KPHPMSSieck, 1985gas phase; M
Δr20.0cal/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O; Lee, Keesee, et al., 1980; M
Δr23.8cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr21.cal/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr8.50 ± 0.20kcal/molTDAsSieck, 1985gas phase; B
Δr8.50 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr8.1 ± 5.8kcal/molEndoPaulson and Dale, 1982gas phase; B
Δr8.10 ± 0.20kcal/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr8.00kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
8.0296.FAFehsenfeld and Ferguson, 1974gas phase; M
8.4300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion • Water) + Water = (Nitrogen oxide anion • 2Water)

By formula: (NO2- • H2O) + H2O = (NO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr13.0 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr12.9 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr12.9 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr13.6kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr26.4cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr23.7cal/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr6.00 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr5.8 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr5.80kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr6.1 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9296.FAFehsenfeld and Ferguson, 1974gas phase; M
5.8300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion • 2Water) + Water = (Nitrogen oxide anion • 3Water)

By formula: (NO2- • 2H2O) + H2O = (NO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.5 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr10.4 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr10.4 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr11.7kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr25.8cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr21.2cal/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr4.50 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr4.0 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr4.10kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr4.5 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Nitrogen oxide anion • 3Water) + Water = (Nitrogen oxide anion • 4Water)

By formula: (NO2- • 3H2O) + H2O = (NO2- • 4H2O)

Quantity Value Units Method Reference Comment
Δr11.6kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr29.0cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M

Nitrogen oxide anion + Hydrogen peroxide = (Nitrogen oxide anion • Hydrogen peroxide)

By formula: NO2- + H2O2 = (NO2- • H2O2)

Quantity Value Units Method Reference Comment
Δr20.2 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Δr14.3 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B

Nitrogen oxide anion + dihydrogen selenide = (Nitrogen oxide anion • dihydrogen selenide)

By formula: NO2- + H2Se = (NO2- • H2Se)

Quantity Value Units Method Reference Comment
Δr20.9 ± 1.0kcal/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-; B
Quantity Value Units Method Reference Comment
Δr10.3 ± 3.5kcal/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-; B

(Nitrogen oxide anion • dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 2dihydrogen selenide)

By formula: (NO2- • H2Se) + H2Se = (NO2- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr8.50 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Quantity Value Units Method Reference Comment
Δr4.70 ± 0.30kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B

(Nitrogen oxide anion • 2dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 3dihydrogen selenide)

By formula: (NO2- • 2H2Se) + H2Se = (NO2- • 3H2Se)

Quantity Value Units Method Reference Comment
Δr7.30 ± 0.70kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Quantity Value Units Method Reference Comment
Δr3.10 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B

(Nitrogen oxide anion • 4294967295Nitrogen dioxide) + Nitrogen dioxide = Nitrogen oxide anion

By formula: (NO2- • 4294967295NO2) + NO2 = NO2-

Quantity Value Units Method Reference Comment
Δr107.31 ± 0.30kcal/molN/ADavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B
Δr<46.10kcal/molPDisSmith, Lee, et al., 1979gas phase; Isomer: O4- + NO ->.; B
Δr66.0 ± 5.0kcal/molPDisSmith, Lee, et al., 1978gas phase; B

Nitrogen oxide anion + Sulfur dioxide = (Nitrogen oxide anion • Sulfur dioxide)

By formula: NO2- + O2S = (NO2- • O2S)

Quantity Value Units Method Reference Comment
Δr25.90 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Δr24.3 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B,M
Quantity Value Units Method Reference Comment
Δr36.8cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Δr31.6cal/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr14.90 ± 0.30kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Nitrogen oxide anion • Sulfur dioxide) + Nitric acid, ethyl ester = (Nitrogen oxide anion • Nitric acid, ethyl ester • Sulfur dioxide)

By formula: (NO2- • O2S) + C2H5NO3 = (NO2- • C2H5NO3 • O2S)

Quantity Value Units Method Reference Comment
Δr7.4kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr10.4cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(Nitrogen oxide anion • Sulfur dioxide) + Sulfur dioxide = (Nitrogen oxide anion • 2Sulfur dioxide)

By formula: (NO2- • O2S) + O2S = (NO2- • 2O2S)

Quantity Value Units Method Reference Comment
Δr9.00 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Δr9.8kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr21.5cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Δr16.8cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr4.00 ± 0.40kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Nitrogen oxide anion • 2Sulfur dioxide) + Sulfur dioxide = (Nitrogen oxide anion • 3Sulfur dioxide)

By formula: (NO2- • 2O2S) + O2S = (NO2- • 3O2S)

Quantity Value Units Method Reference Comment
Δr6.60 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr13.4cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr2.60 ± 0.80kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wincel, 2003
Wincel, H., Gas-phase Solvation of Cl-, NO2-, CH2NO2-, CH3NO2-, and CH3NO4- by CH3NO2, Int. J. Mass Spectrom., 2003, 226, 3, 341-353, https://doi.org/10.1016/S1387-3806(03)00066-6 . [all data]

Sieck, 1985
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Hiraoka and Yamabe, 1992
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Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

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Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Viidanoja, Reiner, et al., 2000
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Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H2O and HNOx clustering on NOx-, J. Chem. Phys., 1980, 72, 1089. [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H2O, SO2, H2O2, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Paulson and Dale, 1982
Paulson, J.F.; Dale, J., Reactions of OH-.H2O with NO2, J. Chem. Phys., 1982, 77, 4006. [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Payzant, Cunningham, et al., 1972
Payzant, J.D.; Cunningham, A.J.; Kebarle, P., Kinetics and Rate Constants of Reactions Leading to Hydration of NO2- and NO3- in Gaseous Oxygen, Argon, and Helium Containing Traces of Water, Can. J. Chem., 1972, 50, 14, 2230, https://doi.org/10.1139/v72-358 . [all data]

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Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO2- and NO3- with SO2, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]


Notes

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