NO3 anion

• Formula: NO₃^-
• Molecular weight: 62.0054
• IUPAC Standard InChI: InChI=1S/NO3/c2-1(3)4/q-1 Copy

  
• IUPAC Standard InChIKey: NHNBFGGVMKEFGY-UHFFFAOYSA-N Copy
• CAS Registry Number: 14797-55-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
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• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
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Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = CH₂NO₅^-

By formula: NO₃^- + CH₂O₂ = CH₂NO₅^-

 +  = ( • )

By formula: NO₃^- + CO₂ = (NO₃^- • CO₂)

 +  = C₂H₄NO₅^-

By formula: NO₃^- + C₂H₄O₂ = C₂H₄NO₅^-

 +  = ( • )

By formula: NO₃^- + C₂H₅NO₃ = (NO₃^- • C₂H₅NO₃)

( • ) +  = ( • 2)

By formula: (NO₃^- • C₂H₅NO₃) + C₂H₅NO₃ = (NO₃^- • 2C₂H₅NO₃)

 +  = C₃H₆NO₅^-

By formula: NO₃^- + C₃H₆O₂ = C₃H₆NO₅^-

 +  = C₄H₈NO₅^-

By formula: NO₃^- + C₄H₈O₂ = C₄H₈NO₅^-

 +  = ClN₂O₆^-

By formula: NO₃^- + ClNO₃ = ClN₂O₆^-

 +  = ( • )

By formula: NO₃^- + HBr = (NO₃^- • HBr)

Free energy of reaction

( • ) +  = ( •  • )

By formula: (NO₃^- • HBr) + HNO₃ = (NO₃^- • HNO₃ • HBr)

 +  = ( • )

By formula: NO₃^- + HNO₃ = (NO₃^- • HNO₃)

( • ) +  = ( •  • )

By formula: (NO₃^- • HNO₃) + HBr = (NO₃^- • HBr • HNO₃)

( • ) +  = ( • 2)

By formula: (NO₃^- • HNO₃) + HNO₃ = (NO₃^- • 2HNO₃)

Free energy of reaction

( • 2) +  = ( • 3)

By formula: (NO₃^- • 2HNO₃) + HNO₃ = (NO₃^- • 3HNO₃)

Free energy of reaction

( • 3) +  = ( • 4)

By formula: (NO₃^- • 3HNO₃) + HNO₃ = (NO₃^- • 4HNO₃)

( • 4) +  = ( • 5)

By formula: (NO₃^- • 4HNO₃) + HNO₃ = (NO₃^- • 5HNO₃)

( • 5) +  = ( • 6)

By formula: (NO₃^- • 5HNO₃) + HNO₃ = (NO₃^- • 6HNO₃)

( • ) +  = ( •  • )

By formula: (NO₃^- • HNO₃) + H₂O = (NO₃^- • H₂O • HNO₃)

Free energy of reaction

 +  = ( • )

By formula: NO₃^- + H₂O = (NO₃^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

 +  +  = C₃H₈NO₆^-

By formula: NO₃^- + H₂O + C₃H₆O₂ = C₃H₈NO₆^-

 +  +  = C₄H₁₀NO₆^-

By formula: NO₃^- + H₂O + C₄H₈O₂ = C₄H₁₀NO₆^-

( • ) +  = ( • 2)

By formula: (NO₃^- • H₂O) + H₂O = (NO₃^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

( • 2) +  = ( • 3)

By formula: (NO₃^- • 2H₂O) + H₂O = (NO₃^- • 3H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

( • ) +  = ( •  • )

By formula: (NO₃^- • H₂O) + O₂S = (NO₃^- • O₂S • H₂O)

 +  = ( • )

By formula: NO₃^- + H₂O₂ = (NO₃^- • H₂O₂)

 +  = ( • )

By formula: NO₃^- + H₂Se = (NO₃^- • H₂Se)

( • ) +  = ( • 2)

By formula: (NO₃^- • H₂Se) + H₂Se = (NO₃^- • 2H₂Se)

 +  = ( • )

By formula: NO₃^- + O₂S = (NO₃^- • O₂S)

Free energy of reaction

( • ) +  = ( •  • )

By formula: (NO₃^- • O₂S) + H₂O = (NO₃^- • H₂O • O₂S)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (NO₃^- • O₂S) + O₂S = (NO₃^- • 2O₂S)

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Viidanoja, Reiner, et al., 2000
Viidanoja, J.; Reiner, T.; Kiendler, A.; Grimm, F.; Arnold, F., Laboratory investigations of negative ion molecule reactions of propionic, butyric, glyoxylic, pyruvic, and pinonic acids, Int. J. Mass Spectrom., 2000, 194, 1, 53-68, https://doi.org/10.1016/S1387-3806(99)00172-4 . [all data]

Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W., Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-, J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146 . [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO₃- and NO₃- association complexes with HNO₃ and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Wlodek, Luczynski, et al., 1980
Wlodek, S.; Luczynski, Z.; Wincel, H., Stabilities of gas-phase NO₃-.(HNO₃)n,n ≤ 6, clusters, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 39. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H₂O and HNO_x clustering on NO_x-, J. Chem. Phys., 1980, 72, 1089. [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Fehsenfeld, Howard, et al., 1975
Fehsenfeld, F.C.; Howard, C.J.; Schmeltkopf, A.L., Gas Phase Ion Chemistry of HNO3, J. Chem. Phys., 1975, 63, 7, 2835, https://doi.org/10.1063/1.431722 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO₂-, NO₃-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H₂O, SO₂, H₂O₂, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Payzant, Cunningham, et al., 1972
Payzant, J.D.; Cunningham, A.J.; Kebarle, P., Kinetics and Rate Constants of Reactions Leading to Hydration of NO2- and NO3- in Gaseous Oxygen, Argon, and Helium Containing Traces of Water, Can. J. Chem., 1972, 50, 14, 2230, https://doi.org/10.1139/v72-358 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO₂^- and NO₃^- with SO₂, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]

Notes

Go To: Top, Ion clustering data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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