NO3 anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.09 ± 0.84kJ/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr59.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr51.88kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.9kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr80.3kJ/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr89.1J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr79.9J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr30.5 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr28.0kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M
29.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(NO3 anion • Nitric acid) + Nitric acid = (NO3 anion • 2Nitric acid)

By formula: (NO3- • HNO3) + HNO3 = (NO3- • 2HNO3)

Quantity Value Units Method Reference Comment
Δr76.6 ± 4.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr66.9 ± 3.3kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr77.0kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr74.1kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Δr83.7kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr92.5J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr96.7J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr49.0 ± 9.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr37.7 ± 1.3kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
52.7233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
57.7250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M

NO3 anion + Sulfur dioxide = (NO3 anion • Sulfur dioxide)

By formula: NO3- + O2S = (NO3- • O2S)

Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr76.1 ± 5.0kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Δr132.J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr40. ± 8.4kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr41.84 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr36.8 ± 3.8kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Δr44.4kJ/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(NO3-)SO2, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • 2Nitric acid) + Nitric acid = (NO3 anion • 3Nitric acid)

By formula: (NO3- • 2HNO3) + HNO3 = (NO3- • 3HNO3)

Quantity Value Units Method Reference Comment
Δr67.4 ± 4.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr58.2 ± 5.9kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr66.9kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr66.9kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr121.J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr112.J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr31. ± 9.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B
Δr24.7 ± 1.7kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr29.kJ/molFAFehsenfeld, Howard, et al., 1975gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
42.7233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr59.8kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.8 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
21.296.FAFehsenfeld and Ferguson, 1974gas phase; M

NO3 anion + Hydrogen cation = Nitric acid

By formula: NO3- + H+ = HNO3

Quantity Value Units Method Reference Comment
Δr1357.7 ± 0.84kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B
Δr1380. ± 20.kJ/molNBAEMathur, Rothe, et al., 1976gas phase; From HNO3; B
Δr1377. ± 24.kJ/molEndoRefaey and Franklin, 1976gas phase; I- + HNO3 ->.; B
Δr1357.7 ± 2.1kJ/molTDEqFerguson, Dunkin, et al., 1972gas phase; B
Δr1490.8kJ/molEndoBerkowitz, Chupka, et al., 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr1329.7 ± 0.84kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.7kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr139.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr16.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

NO3 anion + Hydrogen bromide = (NO3 anion • Hydrogen bromide)

By formula: NO3- + HBr = (NO3- • HBr)

Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr73. ± 16.kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Anchored to HBr..Br- in Caldwell and Kebarle, 1985.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
53.1367.FADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M

(NO3 anion • Nitric acid) + Water = (NO3 anion • Water • Nitric acid)

By formula: (NO3- • HNO3) + H2O = (NO3- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • 3Nitric acid) + Nitric acid = (NO3 anion • 4Nitric acid)

By formula: (NO3- • 3HNO3) + HNO3 = (NO3- • 4HNO3)

Quantity Value Units Method Reference Comment
Δr39. ± 5.4kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr83.3J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr13.4 ± 1.7kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr29. ± 4.2kJ/molIMREFehsenfeld, Howard, et al., 1975gas phase; B

(NO3 anion • Nitric acid) + Hydrogen bromide = (NO3 anion • Hydrogen bromide • Nitric acid)

By formula: (NO3- • HNO3) + HBr = (NO3- • HBr • HNO3)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr38.kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M

(NO3 anion • 5Nitric acid) + Nitric acid = (NO3 anion • 6Nitric acid)

By formula: (NO3- • 5HNO3) + HNO3 = (NO3- • 6HNO3)

Quantity Value Units Method Reference Comment
Δr19.2 ± 3.8kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr31.J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr10.0 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

NO3 anion + Hydrogen peroxide = (NO3 anion • Hydrogen peroxide)

By formula: NO3- + H2O2 = (NO3- • H2O2)

Quantity Value Units Method Reference Comment
Δr80.3 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Δr53.6 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B

(NO3 anion • 4Nitric acid) + Nitric acid = (NO3 anion • 5Nitric acid)

By formula: (NO3- • 4HNO3) + HNO3 = (NO3- • 5HNO3)

Quantity Value Units Method Reference Comment
Δr31. ± 5.0kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr7.9 ± 4.2kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • Sulfur dioxide) + Sulfur dioxide = (NO3 anion • 2Sulfur dioxide)

By formula: (NO3- • O2S) + O2S = (NO3- • 2O2S)

Quantity Value Units Method Reference Comment
Δr37.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr59.0J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(NO3 anion • Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (NO3 anion • 2Nitric acid, ethyl ester)

By formula: (NO3- • C2H5NO3) + C2H5NO3 = (NO3- • 2C2H5NO3)

Quantity Value Units Method Reference Comment
Δr30.kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr36.J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr18.0 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Hydrogen bromide) + Nitric acid = (NO3 anion • Nitric acid • Hydrogen bromide)

By formula: (NO3- • HBr) + HNO3 = (NO3- • HNO3 • HBr)

Quantity Value Units Method Reference Comment
Δr66.9 ± 8.4kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B
Quantity Value Units Method Reference Comment
Δr40. ± 12.kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr30.1 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr72.0 ± 2.5kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr31.8 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(NO3 anion • Water) + Sulfur dioxide = (NO3 anion • Sulfur dioxide • Water)

By formula: (NO3- • H2O) + O2S = (NO3- • O2S • H2O)

Quantity Value Units Method Reference Comment
Δr30.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

NO3 anion + Nitric acid = (NO3 anion • Nitric acid)

By formula: NO3- + HNO3 = (NO3- • HNO3)

Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M

NO3 anion + Nitric acid, ethyl ester = (NO3 anion • Nitric acid, ethyl ester)

By formula: NO3- + C2H5NO3 = (NO3- • C2H5NO3)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr135.J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M

NO3 anion + Carbon dioxide = (NO3 anion • Carbon dioxide)

By formula: NO3- + CO2 = (NO3- • CO2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B,M

NO3 anion + Water + Butanoic acid = C4H10NO6-

By formula: NO3- + H2O + C4H8O2 = C4H10NO6-

Quantity Value Units Method Reference Comment
Δr15.9 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Water + Propanoic acid = C3H8NO6-

By formula: NO3- + H2O + C3H6O2 = C3H8NO6-

Quantity Value Units Method Reference Comment
Δr16.3 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Δr85. ± 24.kJ/molIMRBWincel, Mereand, et al., 1997gas phase; B

NO3 anion + Butanoic acid = C4H8NO5-

By formula: NO3- + C4H8O2 = C4H8NO5-

Quantity Value Units Method Reference Comment
Δr53.56 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Propanoic acid = C3H6NO5-

By formula: NO3- + C3H6O2 = C3H6NO5-

Quantity Value Units Method Reference Comment
Δr50.21 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Formic acid = CH2NO5-

By formula: NO3- + CH2O2 = CH2NO5-

Quantity Value Units Method Reference Comment
Δr47.70 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Acetic acid = C2H4NO5-

By formula: NO3- + C2H4O2 = C2H4NO5-

Quantity Value Units Method Reference Comment
Δr49.37 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase; B

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

NO3 anion + Hydrogen cation = Nitric acid

By formula: NO3- + H+ = HNO3

Quantity Value Units Method Reference Comment
Δr1357.7 ± 0.84kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.
Δr1380. ± 20.kJ/molNBAEMathur, Rothe, et al., 1976gas phase; From HNO3
Δr1377. ± 24.kJ/molEndoRefaey and Franklin, 1976gas phase; I- + HNO3 ->.
Δr1357.7 ± 2.1kJ/molTDEqFerguson, Dunkin, et al., 1972gas phase
Δr1490.8kJ/molEndoBerkowitz, Chupka, et al., 1971gas phase
Quantity Value Units Method Reference Comment
Δr1329.7 ± 0.84kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NO3 anion + Formic acid = CH2NO5-

By formula: NO3- + CH2O2 = CH2NO5-

Quantity Value Units Method Reference Comment
Δr47.70 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Carbon dioxide = (NO3 anion • Carbon dioxide)

By formula: NO3- + CO2 = (NO3- • CO2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B,M

NO3 anion + Acetic acid = C2H4NO5-

By formula: NO3- + C2H4O2 = C2H4NO5-

Quantity Value Units Method Reference Comment
Δr49.37 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Nitric acid, ethyl ester = (NO3 anion • Nitric acid, ethyl ester)

By formula: NO3- + C2H5NO3 = (NO3- • C2H5NO3)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr135.J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M

(NO3 anion • Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (NO3 anion • 2Nitric acid, ethyl ester)

By formula: (NO3- • C2H5NO3) + C2H5NO3 = (NO3- • 2C2H5NO3)

Quantity Value Units Method Reference Comment
Δr30.kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr36.J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

NO3 anion + Propanoic acid = C3H6NO5-

By formula: NO3- + C3H6O2 = C3H6NO5-

Quantity Value Units Method Reference Comment
Δr50.21 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Butanoic acid = C4H8NO5-

By formula: NO3- + C4H8O2 = C4H8NO5-

Quantity Value Units Method Reference Comment
Δr53.56 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Δr85. ± 24.kJ/molIMRBWincel, Mereand, et al., 1997gas phase; B

NO3 anion + Hydrogen bromide = (NO3 anion • Hydrogen bromide)

By formula: NO3- + HBr = (NO3- • HBr)

Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr73. ± 16.kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Anchored to HBr..Br- in Caldwell and Kebarle, 1985.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
53.1367.FADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M

(NO3 anion • Hydrogen bromide) + Nitric acid = (NO3 anion • Nitric acid • Hydrogen bromide)

By formula: (NO3- • HBr) + HNO3 = (NO3- • HNO3 • HBr)

Quantity Value Units Method Reference Comment
Δr66.9 ± 8.4kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B
Quantity Value Units Method Reference Comment
Δr40. ± 12.kJ/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B

NO3 anion + Nitric acid = (NO3 anion • Nitric acid)

By formula: NO3- + HNO3 = (NO3- • HNO3)

Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M

(NO3 anion • Nitric acid) + Hydrogen bromide = (NO3 anion • Hydrogen bromide • Nitric acid)

By formula: (NO3- • HNO3) + HBr = (NO3- • HBr • HNO3)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr38.kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M

(NO3 anion • Nitric acid) + Nitric acid = (NO3 anion • 2Nitric acid)

By formula: (NO3- • HNO3) + HNO3 = (NO3- • 2HNO3)

Quantity Value Units Method Reference Comment
Δr76.6 ± 4.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr66.9 ± 3.3kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr77.0kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr74.1kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Δr83.7kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr92.5J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr96.7J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr49.0 ± 9.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr37.7 ± 1.3kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
52.7233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
57.7250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M

(NO3 anion • 2Nitric acid) + Nitric acid = (NO3 anion • 3Nitric acid)

By formula: (NO3- • 2HNO3) + HNO3 = (NO3- • 3HNO3)

Quantity Value Units Method Reference Comment
Δr67.4 ± 4.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr58.2 ± 5.9kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr66.9kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr66.9kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr121.J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr112.J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr31. ± 9.2kJ/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B
Δr24.7 ± 1.7kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr29.kJ/molFAFehsenfeld, Howard, et al., 1975gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
42.7233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • 3Nitric acid) + Nitric acid = (NO3 anion • 4Nitric acid)

By formula: (NO3- • 3HNO3) + HNO3 = (NO3- • 4HNO3)

Quantity Value Units Method Reference Comment
Δr39. ± 5.4kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr83.3J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr13.4 ± 1.7kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr29. ± 4.2kJ/molIMREFehsenfeld, Howard, et al., 1975gas phase; B

(NO3 anion • 4Nitric acid) + Nitric acid = (NO3 anion • 5Nitric acid)

By formula: (NO3- • 4HNO3) + HNO3 = (NO3- • 5HNO3)

Quantity Value Units Method Reference Comment
Δr31. ± 5.0kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr7.9 ± 4.2kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • 5Nitric acid) + Nitric acid = (NO3 anion • 6Nitric acid)

By formula: (NO3- • 5HNO3) + HNO3 = (NO3- • 6HNO3)

Quantity Value Units Method Reference Comment
Δr19.2 ± 3.8kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr31.J/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr10.0 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • Nitric acid) + Water = (NO3 anion • Water • Nitric acid)

By formula: (NO3- • HNO3) + H2O = (NO3- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.09 ± 0.84kJ/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr59.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr51.88kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.9kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr80.3kJ/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr89.1J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr79.9J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr30.5 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr28.0kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M
29.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

NO3 anion + Water + Propanoic acid = C3H8NO6-

By formula: NO3- + H2O + C3H6O2 = C3H8NO6-

Quantity Value Units Method Reference Comment
Δr16.3 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Water + Butanoic acid = C4H10NO6-

By formula: NO3- + H2O + C4H8O2 = C4H10NO6-

Quantity Value Units Method Reference Comment
Δr15.9 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr59.8kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.8 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
21.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.7kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr139.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr16.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(NO3 anion • Water) + Sulfur dioxide = (NO3 anion • Sulfur dioxide • Water)

By formula: (NO3- • H2O) + O2S = (NO3- • O2S • H2O)

Quantity Value Units Method Reference Comment
Δr30.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

NO3 anion + Hydrogen peroxide = (NO3 anion • Hydrogen peroxide)

By formula: NO3- + H2O2 = (NO3- • H2O2)

Quantity Value Units Method Reference Comment
Δr80.3 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Δr53.6 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr72.0 ± 2.5kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr31.8 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr30.1 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

NO3 anion + Sulfur dioxide = (NO3 anion • Sulfur dioxide)

By formula: NO3- + O2S = (NO3- • O2S)

Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr76.1 ± 5.0kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Δr132.J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr40. ± 8.4kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr41.84 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr36.8 ± 3.8kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Δr44.4kJ/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(NO3-)SO2, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr18.0 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Sulfur dioxide) + Sulfur dioxide = (NO3 anion • 2Sulfur dioxide)

By formula: (NO3- • O2S) + O2S = (NO3- • 2O2S)

Quantity Value Units Method Reference Comment
Δr37.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr59.0J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H2O and HNOx clustering on NOx-, J. Chem. Phys., 1980, 72, 1089. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H2O, SO2, H2O2, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Payzant, Cunningham, et al., 1972
Payzant, J.D.; Cunningham, A.J.; Kebarle, P., Kinetics and Rate Constants of Reactions Leading to Hydration of NO2- and NO3- in Gaseous Oxygen, Argon, and Helium Containing Traces of Water, Can. J. Chem., 1972, 50, 14, 2230, https://doi.org/10.1139/v72-358 . [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO3- and NO3- association complexes with HNO3 and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Wlodek, Luczynski, et al., 1980
Wlodek, S.; Luczynski, Z.; Wincel, H., Stabilities of gas-phase NO3-.(HNO3)n,n ≤ 6, clusters, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 39. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO2- and NO3- with SO2, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]

Fehsenfeld, Howard, et al., 1975
Fehsenfeld, F.C.; Howard, C.J.; Schmeltkopf, A.L., Gas Phase Ion Chemistry of HNO3, J. Chem. Phys., 1975, 63, 7, 2835, https://doi.org/10.1063/1.431722 . [all data]

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Mahajan, K.; Reck, G.P., Negative gaseous ions from nitric acid, J. Chem. Phys., 1976, 64, 1247. [all data]

Refaey and Franklin, 1976
Refaey, K.M.A.; Franklin, J.L., Endoergic ion-molecule-collision processes of negative ions. V. Collision of I- on HNO3. The electron affinity of NO3, J. Chem. Phys., 1976, 64, 4810. [all data]

Ferguson, Dunkin, et al., 1972
Ferguson, E.E.; Dunkin, D.B.; Fehsenfeld, F.C., Reactions of NO2- and NO3- with HCl and HBr, J. Chem. Phys., 1972, 57, 1459. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D., Electron Affinities of O2, O3, NO, NO2, and NO3 by Endothermic Charge Transfer, J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Viidanoja, Reiner, et al., 2000
Viidanoja, J.; Reiner, T.; Kiendler, A.; Grimm, F.; Arnold, F., Laboratory investigations of negative ion molecule reactions of propionic, butyric, glyoxylic, pyruvic, and pinonic acids, Int. J. Mass Spectrom., 2000, 194, 1, 53-68, https://doi.org/10.1016/S1387-3806(99)00172-4 . [all data]

Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W., Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-, J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146 . [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References