NO3 anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr14.60 ± 0.20kcal/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr14.1 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr12.40kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr14.8kcal/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr19.2kcal/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr25.0cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr25.cal/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr21.3cal/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr19.1cal/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20 ± 0.30kcal/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr7.10 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr7.30 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B
Δr6.70kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
8.8250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
6.8296.FAFehsenfeld and Ferguson, 1974gas phase; M
7.0300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(NO3 anion • Nitric acid) + Nitric acid = (NO3 anion • 2Nitric acid)

By formula: (NO3- • HNO3) + HNO3 = (NO3- • 2HNO3)

Quantity Value Units Method Reference Comment
Δr18.3 ± 1.0kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr16.00 ± 0.80kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr18.4kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr17.7kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Δr20.0kcal/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr22.1cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr25.cal/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr23.1cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr11.7 ± 2.2kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr9.00 ± 0.30kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
12.6233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
13.8250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M

NO3 anion + Sulfur dioxide = (NO3 anion • Sulfur dioxide)

By formula: NO3- + O2S = (NO3- • O2S)

Quantity Value Units Method Reference Comment
Δr17.2 ± 2.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr18.2 ± 1.2kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.2cal/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Δr31.6cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 2.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr10.00 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B
Δr8.80 ± 0.90kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Δr10.6kcal/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(NO3-)SO2, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • 2Nitric acid) + Nitric acid = (NO3 anion • 3Nitric acid)

By formula: (NO3- • 2HNO3) + HNO3 = (NO3- • 3HNO3)

Quantity Value Units Method Reference Comment
Δr16.1 ± 1.0kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr13.9 ± 1.4kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr16.0kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr16.0kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr28.9cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr26.7cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr7.4 ± 2.2kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B
Δr5.90 ± 0.40kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr6.9kcal/molFAFehsenfeld, Howard, et al., 1975gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.2233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.2 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr14.3kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr30.3cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr5.20 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr5.20 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.2301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
5.0296.FAFehsenfeld and Ferguson, 1974gas phase; M

NO3 anion + Hydrogen cation = Nitric acid

By formula: NO3- + H+ = HNO3

Quantity Value Units Method Reference Comment
Δr324.50 ± 0.20kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B
Δr329.9 ± 4.8kcal/molNBAEMathur, Rothe, et al., 1976gas phase; From HNO3; B
Δr329.1 ± 5.8kcal/molEndoRefaey and Franklin, 1976gas phase; I- + HNO3 ->.; B
Δr324.50 ± 0.50kcal/molTDEqFerguson, Dunkin, et al., 1972gas phase; B
Δr356.30kcal/molEndoBerkowitz, Chupka, et al., 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr317.80 ± 0.20kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.9 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr13.8kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr33.2cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr3.90 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

NO3 anion + Hydrogen bromide = (NO3 anion • Hydrogen bromide)

By formula: NO3- + HBr = (NO3- • HBr)

Quantity Value Units Method Reference Comment
Δr23.cal/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr17.4 ± 3.9kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Anchored to HBr..Br- in Caldwell and Kebarle, 1985.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
12.7367.FADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M

(NO3 anion • Nitric acid) + Water = (NO3 anion • Water • Nitric acid)

By formula: (NO3- • HNO3) + H2O = (NO3- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr13.0kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.3233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • 3Nitric acid) + Nitric acid = (NO3 anion • 4Nitric acid)

By formula: (NO3- • 3HNO3) + HNO3 = (NO3- • 4HNO3)

Quantity Value Units Method Reference Comment
Δr9.3 ± 1.3kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr3.20 ± 0.40kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr6.9 ± 1.0kcal/molIMREFehsenfeld, Howard, et al., 1975gas phase; B

(NO3 anion • Nitric acid) + Hydrogen bromide = (NO3 anion • Hydrogen bromide • Nitric acid)

By formula: (NO3- • HNO3) + HBr = (NO3- • HBr • HNO3)

Quantity Value Units Method Reference Comment
Δr16.0kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr22.9cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr9.2kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M

(NO3 anion • 5Nitric acid) + Nitric acid = (NO3 anion • 6Nitric acid)

By formula: (NO3- • 5HNO3) + HNO3 = (NO3- • 6HNO3)

Quantity Value Units Method Reference Comment
Δr4.60 ± 0.90kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr7.3cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr2.40 ± 0.70kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

NO3 anion + Hydrogen peroxide = (NO3 anion • Hydrogen peroxide)

By formula: NO3- + H2O2 = (NO3- • H2O2)

Quantity Value Units Method Reference Comment
Δr19.2 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Δr12.8 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B

(NO3 anion • 4Nitric acid) + Nitric acid = (NO3 anion • 5Nitric acid)

By formula: (NO3- • 4HNO3) + HNO3 = (NO3- • 5HNO3)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.2kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.6cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr1.9 ± 1.0kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • Sulfur dioxide) + Sulfur dioxide = (NO3 anion • 2Sulfur dioxide)

By formula: (NO3- • O2S) + O2S = (NO3- • 2O2S)

Quantity Value Units Method Reference Comment
Δr8.8kcal/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr14.1cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(NO3 anion • Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (NO3 anion • 2Nitric acid, ethyl ester)

By formula: (NO3- • C2H5NO3) + C2H5NO3 = (NO3- • 2C2H5NO3)

Quantity Value Units Method Reference Comment
Δr7.2kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr8.7cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr4.30 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.3299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Hydrogen bromide) + Nitric acid = (NO3 anion • Nitric acid • Hydrogen bromide)

By formula: (NO3- • HBr) + HNO3 = (NO3- • HNO3 • HBr)

Quantity Value Units Method Reference Comment
Δr16.0 ± 2.0kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B
Quantity Value Units Method Reference Comment
Δr9.6 ± 2.8kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr7.20 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr4.60 ± 0.70kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr17.20 ± 0.60kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr7.60 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(NO3 anion • Water) + Sulfur dioxide = (NO3 anion • Sulfur dioxide • Water)

By formula: (NO3- • H2O) + O2S = (NO3- • O2S • H2O)

Quantity Value Units Method Reference Comment
Δr7.2kcal/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

NO3 anion + Nitric acid = (NO3 anion • Nitric acid)

By formula: NO3- + HNO3 = (NO3- • HNO3)

Quantity Value Units Method Reference Comment
Δr24.cal/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M

NO3 anion + Nitric acid, ethyl ester = (NO3 anion • Nitric acid, ethyl ester)

By formula: NO3- + C2H5NO3 = (NO3- • C2H5NO3)

Quantity Value Units Method Reference Comment
Δr17.2kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr32.2cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M

NO3 anion + Carbon dioxide = (NO3 anion • Carbon dioxide)

By formula: NO3- + CO2 = (NO3- • CO2)

Quantity Value Units Method Reference Comment
Δr2.70 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B,M

NO3 anion + Water + Butanoic acid = C4H10NO6-

By formula: NO3- + H2O + C4H8O2 = C4H10NO6-

Quantity Value Units Method Reference Comment
Δr3.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Water + Propanoic acid = C3H8NO6-

By formula: NO3- + H2O + C3H6O2 = C3H8NO6-

Quantity Value Units Method Reference Comment
Δr3.90 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Δr20.3 ± 5.7kcal/molIMRBWincel, Mereand, et al., 1997gas phase; B

NO3 anion + Butanoic acid = C4H8NO5-

By formula: NO3- + C4H8O2 = C4H8NO5-

Quantity Value Units Method Reference Comment
Δr12.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Propanoic acid = C3H6NO5-

By formula: NO3- + C3H6O2 = C3H6NO5-

Quantity Value Units Method Reference Comment
Δr12.00 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Formic acid = CH2NO5-

By formula: NO3- + CH2O2 = CH2NO5-

Quantity Value Units Method Reference Comment
Δr11.40 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Acetic acid = C2H4NO5-

By formula: NO3- + C2H4O2 = C2H4NO5-

Quantity Value Units Method Reference Comment
Δr11.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase; B

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

NO3 anion + Hydrogen cation = Nitric acid

By formula: NO3- + H+ = HNO3

Quantity Value Units Method Reference Comment
Δr324.50 ± 0.20kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.
Δr329.9 ± 4.8kcal/molNBAEMathur, Rothe, et al., 1976gas phase; From HNO3
Δr329.1 ± 5.8kcal/molEndoRefaey and Franklin, 1976gas phase; I- + HNO3 ->.
Δr324.50 ± 0.50kcal/molTDEqFerguson, Dunkin, et al., 1972gas phase
Δr356.30kcal/molEndoBerkowitz, Chupka, et al., 1971gas phase
Quantity Value Units Method Reference Comment
Δr317.80 ± 0.20kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NO3 anion + Formic acid = CH2NO5-

By formula: NO3- + CH2O2 = CH2NO5-

Quantity Value Units Method Reference Comment
Δr11.40 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Carbon dioxide = (NO3 anion • Carbon dioxide)

By formula: NO3- + CO2 = (NO3- • CO2)

Quantity Value Units Method Reference Comment
Δr2.70 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B,M

NO3 anion + Acetic acid = C2H4NO5-

By formula: NO3- + C2H4O2 = C2H4NO5-

Quantity Value Units Method Reference Comment
Δr11.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase; B

NO3 anion + Nitric acid, ethyl ester = (NO3 anion • Nitric acid, ethyl ester)

By formula: NO3- + C2H5NO3 = (NO3- • C2H5NO3)

Quantity Value Units Method Reference Comment
Δr17.2kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr32.2cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; M

(NO3 anion • Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (NO3 anion • 2Nitric acid, ethyl ester)

By formula: (NO3- • C2H5NO3) + C2H5NO3 = (NO3- • 2C2H5NO3)

Quantity Value Units Method Reference Comment
Δr7.2kcal/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr8.7cal/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

NO3 anion + Propanoic acid = C3H6NO5-

By formula: NO3- + C3H6O2 = C3H6NO5-

Quantity Value Units Method Reference Comment
Δr12.00 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Butanoic acid = C4H8NO5-

By formula: NO3- + C4H8O2 = C4H8NO5-

Quantity Value Units Method Reference Comment
Δr12.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Chlorine nitrate = ClN2O6-

By formula: NO3- + ClNO3 = ClN2O6-

Quantity Value Units Method Reference Comment
Δr20.3 ± 5.7kcal/molIMRBWincel, Mereand, et al., 1997gas phase; B

NO3 anion + Hydrogen bromide = (NO3 anion • Hydrogen bromide)

By formula: NO3- + HBr = (NO3- • HBr)

Quantity Value Units Method Reference Comment
Δr23.cal/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr17.4 ± 3.9kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; Anchored to HBr..Br- in Caldwell and Kebarle, 1985.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
12.7367.FADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)HNO3, Entropy change calculated or estimated, DG<, ΔrH<; M

(NO3 anion • Hydrogen bromide) + Nitric acid = (NO3 anion • Nitric acid • Hydrogen bromide)

By formula: (NO3- • HBr) + HNO3 = (NO3- • HNO3 • HBr)

Quantity Value Units Method Reference Comment
Δr16.0 ± 2.0kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B
Quantity Value Units Method Reference Comment
Δr9.6 ± 2.8kcal/molTDEqDavidson, Fehsenfeld, et al., 1977gas phase; B

NO3 anion + Nitric acid = (NO3 anion • Nitric acid)

By formula: NO3- + HNO3 = (NO3- • HNO3)

Quantity Value Units Method Reference Comment
Δr24.cal/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; Entropy change calculated or estimated, DG>, ΔrH>; M

(NO3 anion • Nitric acid) + Hydrogen bromide = (NO3 anion • Hydrogen bromide • Nitric acid)

By formula: (NO3- • HNO3) + HBr = (NO3- • HBr • HNO3)

Quantity Value Units Method Reference Comment
Δr16.0kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr22.9cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M
Quantity Value Units Method Reference Comment
Δr9.2kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; switching reaction(NO3-)2HNO3; M

(NO3 anion • Nitric acid) + Nitric acid = (NO3 anion • 2Nitric acid)

By formula: (NO3- • HNO3) + HNO3 = (NO3- • 2HNO3)

Quantity Value Units Method Reference Comment
Δr18.3 ± 1.0kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr16.00 ± 0.80kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr18.4kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr17.7kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Δr20.0kcal/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr22.1cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr25.cal/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr23.1cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr11.7 ± 2.2kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr9.00 ± 0.30kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
12.6233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
13.8250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M

(NO3 anion • 2Nitric acid) + Nitric acid = (NO3 anion • 3Nitric acid)

By formula: (NO3- • 2HNO3) + HNO3 = (NO3- • 3HNO3)

Quantity Value Units Method Reference Comment
Δr16.1 ± 1.0kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B,M
Δr13.9 ± 1.4kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Δr16.0kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr16.0kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Δr28.9cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; M
Δr26.7cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr7.4 ± 2.2kcal/molTDAsDavidson, Fehsenfeld, et al., 1977gas phase; B
Δr5.90 ± 0.40kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr6.9kcal/molFAFehsenfeld, Howard, et al., 1975gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.2233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(NO3 anion • 3Nitric acid) + Nitric acid = (NO3 anion • 4Nitric acid)

By formula: (NO3- • 3HNO3) + HNO3 = (NO3- • 4HNO3)

Quantity Value Units Method Reference Comment
Δr9.3 ± 1.3kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr3.20 ± 0.40kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B
Δr6.9 ± 1.0kcal/molIMREFehsenfeld, Howard, et al., 1975gas phase; B

(NO3 anion • 4Nitric acid) + Nitric acid = (NO3 anion • 5Nitric acid)

By formula: (NO3- • 4HNO3) + HNO3 = (NO3- • 5HNO3)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.2kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.6cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr1.9 ± 1.0kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • 5Nitric acid) + Nitric acid = (NO3 anion • 6Nitric acid)

By formula: (NO3- • 5HNO3) + HNO3 = (NO3- • 6HNO3)

Quantity Value Units Method Reference Comment
Δr4.60 ± 0.90kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr7.3cal/mol*KHPMSWlodek, Luczynski, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr2.40 ± 0.70kcal/molTDAsWlodek, Luczynski, et al., 1980gas phase; B

(NO3 anion • Nitric acid) + Water = (NO3 anion • Water • Nitric acid)

By formula: (NO3- • HNO3) + H2O = (NO3- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr13.0kcal/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.3233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr14.60 ± 0.20kcal/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr14.1 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr12.40kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr14.8kcal/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr19.2kcal/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr25.0cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr25.cal/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr21.3cal/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr19.1cal/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20 ± 0.30kcal/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr7.10 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr7.30 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B
Δr6.70kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
8.8250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
6.8296.FAFehsenfeld and Ferguson, 1974gas phase; M
7.0300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

NO3 anion + Water + Propanoic acid = C3H8NO6-

By formula: NO3- + H2O + C3H6O2 = C3H8NO6-

Quantity Value Units Method Reference Comment
Δr3.90 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Water + Butanoic acid = C4H10NO6-

By formula: NO3- + H2O + C4H8O2 = C4H10NO6-

Quantity Value Units Method Reference Comment
Δr3.80 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 2000gas phase; B

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.2 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr14.3kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr30.3cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr5.20 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr5.20 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.2301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
5.0296.FAFehsenfeld and Ferguson, 1974gas phase; M

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.9 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr13.8kcal/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr33.2cal/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr3.90 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(NO3 anion • Water) + Sulfur dioxide = (NO3 anion • Sulfur dioxide • Water)

By formula: (NO3- • H2O) + O2S = (NO3- • O2S • H2O)

Quantity Value Units Method Reference Comment
Δr7.2kcal/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

NO3 anion + Hydrogen peroxide = (NO3 anion • Hydrogen peroxide)

By formula: NO3- + H2O2 = (NO3- • H2O2)

Quantity Value Units Method Reference Comment
Δr19.2 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Δr12.8 ± 1.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr17.20 ± 0.60kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr7.60 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr7.20 ± 0.50kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr4.60 ± 0.70kcal/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

NO3 anion + Sulfur dioxide = (NO3 anion • Sulfur dioxide)

By formula: NO3- + O2S = (NO3- • O2S)

Quantity Value Units Method Reference Comment
Δr17.2 ± 2.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr18.2 ± 1.2kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.2cal/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Δr31.6cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 2.0kcal/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO3-, Keesee, Lee, et al., 1980; B,M
Δr10.00 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B
Δr8.80 ± 0.90kcal/molTDAsWlodek, Luczynski, et al., 1983gas phase; B
Δr10.6kcal/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(NO3-)SO2, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr4.30 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.3299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NO3 anion • Sulfur dioxide) + Sulfur dioxide = (NO3 anion • 2Sulfur dioxide)

By formula: (NO3- • O2S) + O2S = (NO3- • 2O2S)

Quantity Value Units Method Reference Comment
Δr8.8kcal/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr14.1cal/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H2O and HNOx clustering on NOx-, J. Chem. Phys., 1980, 72, 1089. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H2O, SO2, H2O2, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Payzant, Cunningham, et al., 1972
Payzant, J.D.; Cunningham, A.J.; Kebarle, P., Kinetics and Rate Constants of Reactions Leading to Hydration of NO2- and NO3- in Gaseous Oxygen, Argon, and Helium Containing Traces of Water, Can. J. Chem., 1972, 50, 14, 2230, https://doi.org/10.1139/v72-358 . [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO3- and NO3- association complexes with HNO3 and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Wlodek, Luczynski, et al., 1980
Wlodek, S.; Luczynski, Z.; Wincel, H., Stabilities of gas-phase NO3-.(HNO3)n,n ≤ 6, clusters, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 39. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO2- and NO3- with SO2, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]

Fehsenfeld, Howard, et al., 1975
Fehsenfeld, F.C.; Howard, C.J.; Schmeltkopf, A.L., Gas Phase Ion Chemistry of HNO3, J. Chem. Phys., 1975, 63, 7, 2835, https://doi.org/10.1063/1.431722 . [all data]

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Mahajan, K.; Reck, G.P., Negative gaseous ions from nitric acid, J. Chem. Phys., 1976, 64, 1247. [all data]

Refaey and Franklin, 1976
Refaey, K.M.A.; Franklin, J.L., Endoergic ion-molecule-collision processes of negative ions. V. Collision of I- on HNO3. The electron affinity of NO3, J. Chem. Phys., 1976, 64, 4810. [all data]

Ferguson, Dunkin, et al., 1972
Ferguson, E.E.; Dunkin, D.B.; Fehsenfeld, F.C., Reactions of NO2- and NO3- with HCl and HBr, J. Chem. Phys., 1972, 57, 1459. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D., Electron Affinities of O2, O3, NO, NO2, and NO3 by Endothermic Charge Transfer, J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Viidanoja, Reiner, et al., 2000
Viidanoja, J.; Reiner, T.; Kiendler, A.; Grimm, F.; Arnold, F., Laboratory investigations of negative ion molecule reactions of propionic, butyric, glyoxylic, pyruvic, and pinonic acids, Int. J. Mass Spectrom., 2000, 194, 1, 53-68, https://doi.org/10.1016/S1387-3806(99)00172-4 . [all data]

Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W., Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-, J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146 . [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References