Argon cation
- Formula: Ar+
- Molecular weight: 39.947
- CAS Registry Number: 14791-69-6
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
By formula: Ar+ + Ar = (Ar+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. ± 90. | kJ/mol | AVG | N/A | Average of 5 out of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 53.6 | J/mol*K | PHPMS | Teng and Conway, 1973 | gas phase; switching reaction(N2+)Ar; Turner and Conway, 1979, Liu and Conway, 1975 |
By formula: (Ar+ • 2Ar) + Ar = (Ar+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. ± 1. | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.4 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
8.4 | 77. | PHPMS | Teng and Conway, 1973 | gas phase |
By formula: (Ar+ • Ar) + Ar = (Ar+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.2 ± 0.3 | kJ/mol | PHPMS | Turner and Conway, 1979 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.9 | J/mol*K | PHPMS | Turner and Conway, 1979 | gas phase |
By formula: (Ar+ • 10Ar) + Ar = (Ar+ • 11Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.5 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 9Ar) + Ar = (Ar+ • 10Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.49 ± 0.84 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.5 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 3Ar) + Ar = (Ar+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 58.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 4Ar) + Ar = (Ar+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.8 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 67.4 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 5Ar) + Ar = (Ar+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.8 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 6Ar) + Ar = (Ar+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 7Ar) + Ar = (Ar+ • 8Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 8Ar) + Ar = (Ar+ • 9Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.4 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • CO) + CO = (Ar+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10. | kJ/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; approximate value from Ar+(2P3/2) 2CO -> Ar+(2P3/2) + 2CO |
By formula: Ar+ + H2 = (Ar+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 93.7 | kJ/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + N2 = (Ar+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. | kJ/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + CO = (Ar+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 80. ± 20. | kJ/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; Ar+(2P3/2) |
By formula: Ar+ + He = (Ar+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.5 | kJ/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
By formula: Ar+ + Ne = (Ar+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.5 | kJ/mol | PI | Dehmer and Pratt, 1982 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Teng and Conway, 1973
Teng, H.H.; Conway, D.C.,
Ion - Molecule Equilibria in Mixtures of N2 and Ar,
J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338
. [all data]
Turner and Conway, 1979
Turner, D.L.; Conway, D.C.,
Study of the 2Ar + Ar2+ = Ar + Ar3+ Reaction,
J. Chem. Phys., 1979, 71, 4, 1899, https://doi.org/10.1063/1.438544
. [all data]
Liu and Conway, 1975
Liu, W.F.; Conway, D.C.,
Ion - Molecule Reactions in Ar at 296, 195, and 77 K,
J. Chem. Phys., 1975, 62, 8, 3070, https://doi.org/10.1063/1.430906
. [all data]
Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T.,
Formation and Stabilities of Cluster Ions Arn+,
J. Chem. Phys., 1989, 90, 12, 7143, https://doi.org/10.1063/1.456245
. [all data]
Norwood, Guo, et al., 1989
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y.,
A Study of Intramolecular Charge Transfer in Mixed Ar/Co Dimer and Trimer Ions Using the Photoion - Photoelectron Coincidence Method,
Chem. Phys., 1989, 129, 1, 109, https://doi.org/10.1016/0301-0104(89)80023-0
. [all data]
Shul, Passarella, et al., 1987
Shul, R.J.; Passarella, R.; Upshulte, B.L.; Keesee, R.G.; Castleman, A.W.,
Thermal Energy Reactions Invoving Ar+ Monomer and Dimer with N2, H2, Xe, and Kr,
J. Chem. Phys., 1987, 86, 8, 4446, https://doi.org/10.1063/1.452718
. [all data]
Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T.,
Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions,
J. Chem. Phys., 1982, 77, 4804. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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