Argon cation
- Formula: Ar+
- Molecular weight: 39.947
- CAS Registry Number: 14791-69-6
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 39.771 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1982 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: Ar+ + Ar = (Ar+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. ± 20. | kcal/mol | AVG | N/A | Average of 5 out of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 12.8 | cal/mol*K | PHPMS | Teng and Conway, 1973 | gas phase; switching reaction(N2+)Ar; Turner and Conway, 1979, Liu and Conway, 1975 |
By formula: (Ar+ • 2Ar) + Ar = (Ar+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.9 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
2.0 | 77. | PHPMS | Teng and Conway, 1973 | gas phase |
By formula: (Ar+ • Ar) + Ar = (Ar+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.06 ± 0.08 | kcal/mol | PHPMS | Turner and Conway, 1979 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.3 | cal/mol*K | PHPMS | Turner and Conway, 1979 | gas phase |
By formula: (Ar+ • 10Ar) + Ar = (Ar+ • 11Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 9Ar) + Ar = (Ar+ • 10Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.55 ± 0.20 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 3Ar) + Ar = (Ar+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.7 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 13.9 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 4Ar) + Ar = (Ar+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 5Ar) + Ar = (Ar+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.0 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 6Ar) + Ar = (Ar+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 7Ar) + Ar = (Ar+ • 8Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 8Ar) + Ar = (Ar+ • 9Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • CO) + CO = (Ar+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. | kcal/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; approximate value from Ar+(2P3/2) 2CO -> Ar+(2P3/2) + 2CO |
By formula: Ar+ + H2 = (Ar+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.4 | kcal/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + N2 = (Ar+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.2 | kcal/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + CO = (Ar+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. ± 4. | kcal/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; Ar+(2P3/2) |
By formula: Ar+ + He = (Ar+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.60 | kcal/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
By formula: Ar+ + Ne = (Ar+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.8 | kcal/mol | PI | Dehmer and Pratt, 1982 | gas phase |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Ar+ + Ar = (Ar+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. ± 20. | kcal/mol | AVG | N/A | Average of 5 out of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 12.8 | cal/mol*K | PHPMS | Teng and Conway, 1973 | gas phase; switching reaction(N2+)Ar; Turner and Conway, 1979, Liu and Conway, 1975 |
By formula: (Ar+ • Ar) + Ar = (Ar+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.06 ± 0.08 | kcal/mol | PHPMS | Turner and Conway, 1979 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.3 | cal/mol*K | PHPMS | Turner and Conway, 1979 | gas phase |
By formula: (Ar+ • 2Ar) + Ar = (Ar+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.9 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
2.0 | 77. | PHPMS | Teng and Conway, 1973 | gas phase |
By formula: (Ar+ • 3Ar) + Ar = (Ar+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.7 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 13.9 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 4Ar) + Ar = (Ar+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 5Ar) + Ar = (Ar+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.0 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 6Ar) + Ar = (Ar+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 7Ar) + Ar = (Ar+ • 8Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 8Ar) + Ar = (Ar+ • 9Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 9Ar) + Ar = (Ar+ • 10Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.55 ± 0.20 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (Ar+ • 10Ar) + Ar = (Ar+ • 11Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: Ar+ + CO = (Ar+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. ± 4. | kcal/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; Ar+(2P3/2) |
By formula: (Ar+ • CO) + CO = (Ar+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. | kcal/mol | PIPECO | Norwood, Guo, et al., 1989 | gas phase; approximate value from Ar+(2P3/2) 2CO -> Ar+(2P3/2) + 2CO |
By formula: Ar+ + H2 = (Ar+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.4 | kcal/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + He = (Ar+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.60 | kcal/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
By formula: Ar+ + N2 = (Ar+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.2 | kcal/mol | FA | Shul, Passarella, et al., 1987 | gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982 |
By formula: Ar+ + Ne = (Ar+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.8 | kcal/mol | PI | Dehmer and Pratt, 1982 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Teng and Conway, 1973
Teng, H.H.; Conway, D.C.,
Ion - Molecule Equilibria in Mixtures of N2 and Ar,
J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338
. [all data]
Turner and Conway, 1979
Turner, D.L.; Conway, D.C.,
Study of the 2Ar + Ar2+ = Ar + Ar3+ Reaction,
J. Chem. Phys., 1979, 71, 4, 1899, https://doi.org/10.1063/1.438544
. [all data]
Liu and Conway, 1975
Liu, W.F.; Conway, D.C.,
Ion - Molecule Reactions in Ar at 296, 195, and 77 K,
J. Chem. Phys., 1975, 62, 8, 3070, https://doi.org/10.1063/1.430906
. [all data]
Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T.,
Formation and Stabilities of Cluster Ions Arn+,
J. Chem. Phys., 1989, 90, 12, 7143, https://doi.org/10.1063/1.456245
. [all data]
Norwood, Guo, et al., 1989
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y.,
A Study of Intramolecular Charge Transfer in Mixed Ar/Co Dimer and Trimer Ions Using the Photoion - Photoelectron Coincidence Method,
Chem. Phys., 1989, 129, 1, 109, https://doi.org/10.1016/0301-0104(89)80023-0
. [all data]
Shul, Passarella, et al., 1987
Shul, R.J.; Passarella, R.; Upshulte, B.L.; Keesee, R.G.; Castleman, A.W.,
Thermal Energy Reactions Invoving Ar+ Monomer and Dimer with N2, H2, Xe, and Kr,
J. Chem. Phys., 1987, 86, 8, 4446, https://doi.org/10.1063/1.452718
. [all data]
Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T.,
Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions,
J. Chem. Phys., 1982, 77, 4804. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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