Vanadium ion (1+)


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar43.829cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Vanadium ion (1+) + Water = (Vanadium ion (1+) • Water)

By formula: V+ + H2O = (V+ • H2O)

Quantity Value Units Method Reference Comment
Δr36. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Δr35.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
35.1 (+8.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Carbon monoxide = (Vanadium ion (1+) • Carbon monoxide)

By formula: V+ + CO = (V+ • CO)

Quantity Value Units Method Reference Comment
Δr28.7 ± 3.3kcal/molCIDArmentrout and Kickel, 1994gas phase; ΔrH(0 K0, guided ion beam CID; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
27.0 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

Vanadium ion (1+) + Benzene = (Vanadium ion (1+) • Benzene)

By formula: V+ + C6H6 = (V+ • C6H6)

Quantity Value Units Method Reference Comment
Δr>55.kcal/molRAKGapeev and Dunbar, 2002RCD
Δr55.9 ± 2.4kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
55.8 (+2.3,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 3Carbon monoxide)

By formula: (V+ • 2CO) + CO = (V+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.6 (+0.9,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
14.6 (+2.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 4Carbon monoxide)

By formula: (V+ • 3CO) + CO = (V+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
20.5 (+2.3,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.7 (+3.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 5Carbon monoxide)

By formula: (V+ • 4CO) + CO = (V+ • 5CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 6Carbon monoxide)

By formula: (V+ • 5CO) + CO = (V+ • 6CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
23.8 (+1.6,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
29.6 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 2Carbon monoxide)

By formula: (V+ • CO) + CO = (V+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
25.3 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Water) + Water = (Vanadium ion (1+) • 3Water)

By formula: (V+ • 2H2O) + H2O = (V+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr12.2kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.3 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Water) + Water = (Vanadium ion (1+) • 2Water)

By formula: (V+ • H2O) + H2O = (V+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr35.5kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.1 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Ethylene = (Vanadium ion (1+) • Ethylene)

By formula: V+ + C2H4 = (V+ • C2H4)

Quantity Value Units Method Reference Comment
Δr29.9 ± 1.9kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
28.0 CIDArmentrout and Kickel, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Vanadium ion (1+) • 2Ammonia) + Ammonia = (Vanadium ion (1+) • 3Ammonia)

By formula: (V+ • 2H3N) + H3N = (V+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr24.9 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr22.6kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • 3Ammonia) + Ammonia = (Vanadium ion (1+) • 4Ammonia)

By formula: (V+ • 3H3N) + H3N = (V+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr22.7 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr18.7kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • Ammonia) + Ammonia = (Vanadium ion (1+) • 2Ammonia)

By formula: (V+ • H3N) + H3N = (V+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr39.2 ± 2.2kcal/molCIDTWalter and Armentrout, 1998RCD
Δr45.0kcal/molCIDMarinelli and Squires, 1989gas phase; M

Vanadium ion (1+) + Ammonia = (Vanadium ion (1+) • Ammonia)

By formula: V+ + H3N = (V+ • H3N)

Quantity Value Units Method Reference Comment
Δr45.4 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr51.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • Benzene) + Benzene = (Vanadium ion (1+) • 2Benzene)

By formula: (V+ • C6H6) + C6H6 = (V+ • 2C6H6)

Quantity Value Units Method Reference Comment
Δr58.8 ± 4.4kcal/molCIDMeyer, Khan, et al., 1995gas phase; ΔrH(0k), guided ion beam CID; M,RCD

(Vanadium ion (1+) • 3Water) + Water = (Vanadium ion (1+) • 4Water)

By formula: (V+ • 3H2O) + H2O = (V+ • 4H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 7Carbon monoxide)

By formula: (V+ • 6CO) + CO = (V+ • 7CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.0 (+2.1,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 11vanadium) + vanadium = (Vanadium ion (1+) • 12vanadium)

By formula: (V+ • 11V) + V = (V+ • 12V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
107.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 13vanadium) + vanadium = (Vanadium ion (1+) • 14vanadium)

By formula: (V+ • 13V) + V = (V+ • 14V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
108.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 18vanadium) + vanadium = (Vanadium ion (1+) • 19vanadium)

By formula: (V+ • 18V) + V = (V+ • 19V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
105.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 10vanadium) + vanadium = (Vanadium ion (1+) • 11vanadium)

By formula: (V+ • 10V) + V = (V+ • 11V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 12vanadium) + vanadium = (Vanadium ion (1+) • 13vanadium)

By formula: (V+ • 12V) + V = (V+ • 13V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
92.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 14vanadium) + vanadium = (Vanadium ion (1+) • 15vanadium)

By formula: (V+ • 14V) + V = (V+ • 15V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
89.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 15vanadium) + vanadium = (Vanadium ion (1+) • 16vanadium)

By formula: (V+ • 15V) + V = (V+ • 16V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
96.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 16vanadium) + vanadium = (Vanadium ion (1+) • 17vanadium)

By formula: (V+ • 16V) + V = (V+ • 17V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 17vanadium) + vanadium = (Vanadium ion (1+) • 18vanadium)

By formula: (V+ • 17V) + V = (V+ • 18V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
97.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 9vanadium) + vanadium = (Vanadium ion (1+) • 10vanadium)

By formula: (V+ • 9V) + V = (V+ • 10V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2vanadium) + vanadium = (Vanadium ion (1+) • 3vanadium)

By formula: (V+ • 2V) + V = (V+ • 3V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
81.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3vanadium) + vanadium = (Vanadium ion (1+) • 4vanadium)

By formula: (V+ • 3V) + V = (V+ • 4V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
74.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4vanadium) + vanadium = (Vanadium ion (1+) • 5vanadium)

By formula: (V+ • 4V) + V = (V+ • 5V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5vanadium) + vanadium = (Vanadium ion (1+) • 6vanadium)

By formula: (V+ • 5V) + V = (V+ • 6V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
88.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6vanadium) + vanadium = (Vanadium ion (1+) • 7vanadium)

By formula: (V+ • 6V) + V = (V+ • 7V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
92.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 7vanadium) + vanadium = (Vanadium ion (1+) • 8vanadium)

By formula: (V+ • 7V) + V = (V+ • 8V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 8vanadium) + vanadium = (Vanadium ion (1+) • 9vanadium)

By formula: (V+ • 8V) + V = (V+ • 9V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Xenon = (Vanadium ion (1+) • Xenon)

By formula: V+ + Xe = (V+ • Xe)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
7.8 (+1.4,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • vanadium) + vanadium = (Vanadium ion (1+) • 2vanadium)

By formula: (V+ • V) + V = (V+ • 2V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
52.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Acetylene = (Vanadium ion (1+) • Acetylene)

By formula: V+ + C2H2 = (V+ • C2H2)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
49.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + vanadium = (Vanadium ion (1+) • vanadium)

By formula: V+ + V = (V+ • V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
72.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Sulfur dimer) + Sulfur dimer = (Vanadium ion (1+) • 2Sulfur dimer)

By formula: (V+ • S2) + S2 = (V+ • 2S2)

Quantity Value Units Method Reference Comment
Δr68.4 ± 4.4kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

(Vanadium ion (1+) • Ethylene) + Ethylene = (Vanadium ion (1+) • 2Ethylene)

By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)

Quantity Value Units Method Reference Comment
Δr30.4 ± 3.3kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Vanadium ion (1+) + Sulfur dimer = (Vanadium ion (1+) • Sulfur dimer)

By formula: V+ + S2 = (V+ • S2)

Quantity Value Units Method Reference Comment
Δr74.8 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + Adenine = (Vanadium ion (1+) • Adenine)

By formula: V+ + C5H5N5 = (V+ • C5H5N5)

Quantity Value Units Method Reference Comment
Δr≤63.4 ± 2.5kcal/molCIDTRodgers and Armentrout, 2002RCD

Vanadium ion (1+) + Pyridine = (Vanadium ion (1+) • Pyridine)

By formula: V+ + C5H5N = (V+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr52.2 ± 3.2kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Vanadium ion (1+) + 1,3-Diazine = (Vanadium ion (1+) • 1,3-Diazine)

By formula: V+ + C4H4N2 = (V+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr48.8 ± 1.7kcal/molCIDTAmunugama and Rodgers, 2001RCD

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) • Carbon disulfide)

By formula: V+ + CS2 = (V+ • CS2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + Pyrrole = (Vanadium ion (1+) • Pyrrole)

By formula: V+ + C4H5N = (V+ • C4H5N)

Quantity Value Units Method Reference Comment
Δr>41.kcal/molRAKGapeev and Yang, 2000RCD

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Vanadium ion (1+) + Carbon monoxide = (Vanadium ion (1+) • Carbon monoxide)

By formula: V+ + CO = (V+ • CO)

Quantity Value Units Method Reference Comment
Δr28.7 ± 3.3kcal/molCIDArmentrout and Kickel, 1994gas phase; ΔrH(0 K0, guided ion beam CID; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
27.0 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 2Carbon monoxide)

By formula: (V+ • CO) + CO = (V+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
25.3 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 3Carbon monoxide)

By formula: (V+ • 2CO) + CO = (V+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.6 (+0.9,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
14.6 (+2.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 4Carbon monoxide)

By formula: (V+ • 3CO) + CO = (V+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
20.5 (+2.3,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.7 (+3.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 5Carbon monoxide)

By formula: (V+ • 4CO) + CO = (V+ • 5CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 6Carbon monoxide)

By formula: (V+ • 5CO) + CO = (V+ • 6CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
23.8 (+1.6,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
29.6 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 7Carbon monoxide)

By formula: (V+ • 6CO) + CO = (V+ • 7CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.0 (+2.1,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) • Carbon disulfide)

By formula: V+ + CS2 = (V+ • CS2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + Acetylene = (Vanadium ion (1+) • Acetylene)

By formula: V+ + C2H2 = (V+ • C2H2)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
49.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Ethylene = (Vanadium ion (1+) • Ethylene)

By formula: V+ + C2H4 = (V+ • C2H4)

Quantity Value Units Method Reference Comment
Δr29.9 ± 1.9kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
28.0 CIDArmentrout and Kickel, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Vanadium ion (1+) • Ethylene) + Ethylene = (Vanadium ion (1+) • 2Ethylene)

By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)

Quantity Value Units Method Reference Comment
Δr30.4 ± 3.3kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Vanadium ion (1+) + 1,3-Diazine = (Vanadium ion (1+) • 1,3-Diazine)

By formula: V+ + C4H4N2 = (V+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr48.8 ± 1.7kcal/molCIDTAmunugama and Rodgers, 2001RCD

Vanadium ion (1+) + Pyrrole = (Vanadium ion (1+) • Pyrrole)

By formula: V+ + C4H5N = (V+ • C4H5N)

Quantity Value Units Method Reference Comment
Δr>41.kcal/molRAKGapeev and Yang, 2000RCD

Vanadium ion (1+) + Pyridine = (Vanadium ion (1+) • Pyridine)

By formula: V+ + C5H5N = (V+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr52.2 ± 3.2kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Vanadium ion (1+) + Adenine = (Vanadium ion (1+) • Adenine)

By formula: V+ + C5H5N5 = (V+ • C5H5N5)

Quantity Value Units Method Reference Comment
Δr≤63.4 ± 2.5kcal/molCIDTRodgers and Armentrout, 2002RCD

Vanadium ion (1+) + Benzene = (Vanadium ion (1+) • Benzene)

By formula: V+ + C6H6 = (V+ • C6H6)

Quantity Value Units Method Reference Comment
Δr>55.kcal/molRAKGapeev and Dunbar, 2002RCD
Δr55.9 ± 2.4kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
55.8 (+2.3,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Benzene) + Benzene = (Vanadium ion (1+) • 2Benzene)

By formula: (V+ • C6H6) + C6H6 = (V+ • 2C6H6)

Quantity Value Units Method Reference Comment
Δr58.8 ± 4.4kcal/molCIDMeyer, Khan, et al., 1995gas phase; ΔrH(0k), guided ion beam CID; M,RCD

Vanadium ion (1+) + Water = (Vanadium ion (1+) • Water)

By formula: V+ + H2O = (V+ • H2O)

Quantity Value Units Method Reference Comment
Δr36. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Δr35.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
35.1 (+8.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Water) + Water = (Vanadium ion (1+) • 2Water)

By formula: (V+ • H2O) + H2O = (V+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr35.5kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.1 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Water) + Water = (Vanadium ion (1+) • 3Water)

By formula: (V+ • 2H2O) + H2O = (V+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr12.2kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.3 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Water) + Water = (Vanadium ion (1+) • 4Water)

By formula: (V+ • 3H2O) + H2O = (V+ • 4H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Ammonia = (Vanadium ion (1+) • Ammonia)

By formula: V+ + H3N = (V+ • H3N)

Quantity Value Units Method Reference Comment
Δr45.4 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr51.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • Ammonia) + Ammonia = (Vanadium ion (1+) • 2Ammonia)

By formula: (V+ • H3N) + H3N = (V+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr39.2 ± 2.2kcal/molCIDTWalter and Armentrout, 1998RCD
Δr45.0kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • 2Ammonia) + Ammonia = (Vanadium ion (1+) • 3Ammonia)

By formula: (V+ • 2H3N) + H3N = (V+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr24.9 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr22.6kcal/molCIDMarinelli and Squires, 1989gas phase; M

(Vanadium ion (1+) • 3Ammonia) + Ammonia = (Vanadium ion (1+) • 4Ammonia)

By formula: (V+ • 3H3N) + H3N = (V+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr22.7 ± 2.6kcal/molCIDTWalter and Armentrout, 1998RCD
Δr18.7kcal/molCIDMarinelli and Squires, 1989gas phase; M

Vanadium ion (1+) + Sulfur dimer = (Vanadium ion (1+) • Sulfur dimer)

By formula: V+ + S2 = (V+ • S2)

Quantity Value Units Method Reference Comment
Δr74.8 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

(Vanadium ion (1+) • Sulfur dimer) + Sulfur dimer = (Vanadium ion (1+) • 2Sulfur dimer)

By formula: (V+ • S2) + S2 = (V+ • 2S2)

Quantity Value Units Method Reference Comment
Δr68.4 ± 4.4kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Vanadium ion (1+) + vanadium = (Vanadium ion (1+) • vanadium)

By formula: V+ + V = (V+ • V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
72.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • vanadium) + vanadium = (Vanadium ion (1+) • 2vanadium)

By formula: (V+ • V) + V = (V+ • 2V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
52.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2vanadium) + vanadium = (Vanadium ion (1+) • 3vanadium)

By formula: (V+ • 2V) + V = (V+ • 3V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
81.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3vanadium) + vanadium = (Vanadium ion (1+) • 4vanadium)

By formula: (V+ • 3V) + V = (V+ • 4V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
74.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4vanadium) + vanadium = (Vanadium ion (1+) • 5vanadium)

By formula: (V+ • 4V) + V = (V+ • 5V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5vanadium) + vanadium = (Vanadium ion (1+) • 6vanadium)

By formula: (V+ • 5V) + V = (V+ • 6V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
88.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6vanadium) + vanadium = (Vanadium ion (1+) • 7vanadium)

By formula: (V+ • 6V) + V = (V+ • 7V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
92.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 7vanadium) + vanadium = (Vanadium ion (1+) • 8vanadium)

By formula: (V+ • 7V) + V = (V+ • 8V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 8vanadium) + vanadium = (Vanadium ion (1+) • 9vanadium)

By formula: (V+ • 8V) + V = (V+ • 9V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 9vanadium) + vanadium = (Vanadium ion (1+) • 10vanadium)

By formula: (V+ • 9V) + V = (V+ • 10V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 10vanadium) + vanadium = (Vanadium ion (1+) • 11vanadium)

By formula: (V+ • 10V) + V = (V+ • 11V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
95.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 11vanadium) + vanadium = (Vanadium ion (1+) • 12vanadium)

By formula: (V+ • 11V) + V = (V+ • 12V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
107.3 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 12vanadium) + vanadium = (Vanadium ion (1+) • 13vanadium)

By formula: (V+ • 12V) + V = (V+ • 13V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
92.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 13vanadium) + vanadium = (Vanadium ion (1+) • 14vanadium)

By formula: (V+ • 13V) + V = (V+ • 14V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
108.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 14vanadium) + vanadium = (Vanadium ion (1+) • 15vanadium)

By formula: (V+ • 14V) + V = (V+ • 15V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
89.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 15vanadium) + vanadium = (Vanadium ion (1+) • 16vanadium)

By formula: (V+ • 15V) + V = (V+ • 16V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
96.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 16vanadium) + vanadium = (Vanadium ion (1+) • 17vanadium)

By formula: (V+ • 16V) + V = (V+ • 17V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
91.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 17vanadium) + vanadium = (Vanadium ion (1+) • 18vanadium)

By formula: (V+ • 17V) + V = (V+ • 18V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
97.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 18vanadium) + vanadium = (Vanadium ion (1+) • 19vanadium)

By formula: (V+ • 18V) + V = (V+ • 19V)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
105.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Xenon = (Vanadium ion (1+) • Xenon)

By formula: V+ + Xe = (V+ • Xe)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
7.8 (+1.4,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Sievers and Armentrout, 1995
Sievers, M.R.; Armentrout, P.B., Collision-Induced Dissociation Studies of V(CO)x+, x = 1-7: Sequential Bond Energies and the Heat of Formation of V(CO)6, J. Phys. Chem., 1995, 99, 20, 8135, https://doi.org/10.1021/j100020a041 . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References