Benzenamine, 2,4,6-tribromo-

• Formula: C₆H₄Br₃N
• Molecular weight: 329.815
• IUPAC Standard InChI: InChI=1S/C6H4Br3N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2 Copy

  
• IUPAC Standard InChIKey: GVPODVKBTHCGFU-UHFFFAOYSA-N Copy
• CAS Registry Number: 147-82-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Aniline, 2,4,6-tribromo-; s-Tribromoaniline; 2,4,6-Tribromoaniline; 2,4,6-Tribomoaniline; 2,4,6-Tribromoanine; USAF do-43; 2,4,6-Tribromophenylamine; sym-Tribromoaniline; 2,4,6-Tribromobenzenamine
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• Information on this page:
  • Phase change data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • IR Spectrum
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Enthalpy of fusion

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Snyder and Geller, 1952
Snyder, H.R.; Geller, H.C., Cleavage of Sulfonamides with Aqueous Hydrobromic Acid and Phenol II., J. Am. Chem. Soc., 1952, 74, 4864. [all data]

Few and Smith, 1949
Few, A.V.; Smith, J.W., Molecular Polarization and Molecular Interaction. II. Apparent Dipole Moments of p-chloro-, 2,4,6-tribromo-, and 2,4,6-tribromo-N-dimethyl-aniline, n- and tert- butylamine in benzene and dioxane., J. Chem. Soc., 1949, 1949, 2663. [all data]

Robertson, 1902
Robertson, P.W., Atomic and molecular heats of fusion., J. Chem. Soc., 1902, 81, 1233. [all data]

Ribeiro da Silva, Ferreira, et al., 2006
Ribeiro da Silva, Manuel A.V.; Ferreira, Ana I.M.C.L.; Gomes, José R.B., Experimental and Computational Study on the Thermochemistry of Bromoanilines, Bull. Chem. Soc. Jpn., 2006, 79, 12, 1852-1859, https://doi.org/10.1246/bcsj.79.1852 . [all data]

Allot and Finch, 1987
Allot, P.H.; Finch, A., Enthalpies of formation of 2,4,6-tribromophenol and of 2,4,6-tribromoaniline, J. Chem. Thermodyn., 1987, 19, 771-779. [all data]

Gruzdev, Alferova, et al., 2011
Gruzdev, I.V.; Alferova, M.V.; Kondratenok, B.M.; Zenkevich, I.G., Gas-chromatographic identification of chloro- and bromosubstituted anilines using retention indices, Rus. J. Anal. Chem., 2011, 66, 5, 519-524. [all data]

Gruzdev, Alferova, et al., 2011, 2
Gruzdev, I.V.; Alferova, M.V.; Kondratenok, B.M.; Zenkevich, I.G., Quantification of chloroanilines in drinking water by gas chromatography as bromo derivatives, Rus. J. Anal. Chem., 2011, 66, 10, 955-962, https://doi.org/10.1134/S1061934811100042 . [all data]

Gruzdev, Filippova, et al., 2011
Gruzdev, I.V.; Filippova, M.V.; Zenkevich, I.G.; Kondratenok, B.M., Identification of bromination products of chlorosubstituted anilines in aqueous media by using gas chromatography, Rus. J. Applied Chem., 2011, 84, 10, 1656-1667, https://doi.org/10.1134/S1070427211100132 . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]

Notes

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• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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