Lead ion (1+)
- Formula: Pb+
- Molecular weight: 207.2
- IUPAC Standard InChI: InChI=1S/Pb/q+1
- IUPAC Standard InChIKey: OQWVGEZAIDNFMR-UHFFFAOYSA-N
- CAS Registry Number: 14701-27-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Lead cation
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H3N) + H3N = (Pb+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.0 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.4 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 3
) +
= (
• 4
)
By formula: (Pb+ • 3H3N) + H3N = (Pb+ • 4H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.7 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( •
) +
= (
• 2
)
By formula: (Pb+ • H3N) + H3N = (Pb+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.2 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
+
= (
•
)
By formula: Pb+ + H3N = (Pb+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.3 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H2O) + H2O = (Pb+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.2 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.2 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 4
) +
= (
• 5
)
By formula: (Pb+ • 4H2O) + H2O = (Pb+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.0 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 5
) +
= (
• 6
)
By formula: (Pb+ • 5H2O) + H2O = (Pb+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.6 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • H2O) + H2O = (Pb+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.9 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH4O) + CH4O = (Pb+ • 2CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.2 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.6 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH5N) + CH5N = (Pb+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.5 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH4O = (Pb+ • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.3 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.3 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH5N = (Pb+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.4 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.0 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + H2O = (Pb+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.4 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.5 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
+
= (
•
)
By formula: Pb+ + C6H6 = (Pb+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.2 | kcal/mol | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.6 | cal/mol*K | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W.,
The Clustering Reactions of Na+ and Pb+ with Several Important Ligands,
Zeit. Phys. D., 1991, 19, 1-4, 397, https://doi.org/10.1007/BF01448337
. [all data]
Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of the Gas - Phase Hydration of the Monovalent Lead Ion,
J. Chem. Phys., 1972, 57, 9, 3638, https://doi.org/10.1063/1.1678820
. [all data]
Guo and Castleman, 1990
Guo, B.C.; Castleman, A.W.,
The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase,
Int. J. Mass Spectrom. Ion Proc., 1990, 100, 665, https://doi.org/10.1016/0168-1176(90)85101-7
. [all data]
Guo, Purnell, et al., 1990
Guo, B.C.; Purnell, J.W.; Castleman, A.W.,
The Clustering Reactions of Benzene with Sodium and Lead Ions,
Chem. Phys. Lett., 1990, 168, 2, 155, https://doi.org/10.1016/0009-2614(90)85122-S
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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