Lead ion (1+)
- Formula: Pb+
- Molecular weight: 207.2
- IUPAC Standard InChI: InChI=1S/Pb/q+1
- IUPAC Standard InChIKey: OQWVGEZAIDNFMR-UHFFFAOYSA-N
- CAS Registry Number: 14701-27-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Lead cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| S°gas,1 bar | 43.293 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1983 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H3N) + H3N = (Pb+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.0 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.4 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 3
) +
= (
• 4
)
By formula: (Pb+ • 3H3N) + H3N = (Pb+ • 4H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.7 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( •
) +
= (
• 2
)
By formula: (Pb+ • H3N) + H3N = (Pb+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.2 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
+
= (
•
)
By formula: Pb+ + H3N = (Pb+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.3 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H2O) + H2O = (Pb+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.2 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.2 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 4
) +
= (
• 5
)
By formula: (Pb+ • 4H2O) + H2O = (Pb+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.0 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 5
) +
= (
• 6
)
By formula: (Pb+ • 5H2O) + H2O = (Pb+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.6 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • H2O) + H2O = (Pb+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.9 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH4O) + CH4O = (Pb+ • 2CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.2 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.6 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH5N) + CH5N = (Pb+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.5 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH4O = (Pb+ • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.3 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.3 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH5N = (Pb+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.4 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.0 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + H2O = (Pb+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.4 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.5 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
+
= (
•
)
By formula: Pb+ + C6H6 = (Pb+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.2 | kcal/mol | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.6 | cal/mol*K | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W.,
The Clustering Reactions of Na+ and Pb+ with Several Important Ligands,
Zeit. Phys. D., 1991, 19, 1-4, 397, https://doi.org/10.1007/BF01448337
. [all data]
Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of the Gas - Phase Hydration of the Monovalent Lead Ion,
J. Chem. Phys., 1972, 57, 9, 3638, https://doi.org/10.1063/1.1678820
. [all data]
Guo and Castleman, 1990
Guo, B.C.; Castleman, A.W.,
The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase,
Int. J. Mass Spectrom. Ion Proc., 1990, 100, 665, https://doi.org/10.1016/0168-1176(90)85101-7
. [all data]
Guo, Purnell, et al., 1990
Guo, B.C.; Purnell, J.W.; Castleman, A.W.,
The Clustering Reactions of Benzene with Sodium and Lead Ions,
Chem. Phys. Lett., 1990, 168, 2, 155, https://doi.org/10.1016/0009-2614(90)85122-S
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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