Lead ion (1+)
- Formula: Pb+
- Molecular weight: 207.2
- IUPAC Standard InChI: InChI=1S/Pb/q+1
- IUPAC Standard InChIKey: OQWVGEZAIDNFMR-UHFFFAOYSA-N
- CAS Registry Number: 14701-27-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Lead cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
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Reaction thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H3N) + H3N = (Pb+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.0 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.4 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 3
) +
= (
• 4
)
By formula: (Pb+ • 3H3N) + H3N = (Pb+ • 4H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.7 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( •
) +
= (
• 2
)
By formula: (Pb+ • H3N) + H3N = (Pb+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.2 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
+
= (
•
)
By formula: Pb+ + H3N = (Pb+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.3 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H2O) + H2O = (Pb+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.2 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.2 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 4
) +
= (
• 5
)
By formula: (Pb+ • 4H2O) + H2O = (Pb+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.0 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 5
) +
= (
• 6
)
By formula: (Pb+ • 5H2O) + H2O = (Pb+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.6 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • H2O) + H2O = (Pb+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.9 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH4O) + CH4O = (Pb+ • 2CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.2 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.6 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH5N) + CH5N = (Pb+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.5 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH4O = (Pb+ • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.3 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.3 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH5N = (Pb+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.4 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.0 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + H2O = (Pb+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.4 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.5 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
+
= (
•
)
By formula: Pb+ + C6H6 = (Pb+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.2 | kcal/mol | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.6 | cal/mol*K | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+
= (
•
)
By formula: Pb+ + CH4O = (Pb+ • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.3 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.3 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH4O) + CH4O = (Pb+ • 2CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.2 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.6 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + CH5N = (Pb+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.4 ± 0.3 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.0 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • CH5N) + CH5N = (Pb+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 ± 0.2 | kcal/mol | HPMS | Guo and Castleman, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.5 | cal/mol*K | HPMS | Guo and Castleman, 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + C6H6 = (Pb+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.2 | kcal/mol | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.6 | cal/mol*K | PHPMS | Guo, Purnell, et al., 1990 | gas phase |
+
= (
•
)
By formula: Pb+ + H2O = (Pb+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.4 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.5 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( •
) +
= (
• 2
)
By formula: (Pb+ • H2O) + H2O = (Pb+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.9 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H2O) + H2O = (Pb+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.2 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.2 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 4
) +
= (
• 5
)
By formula: (Pb+ • 4H2O) + H2O = (Pb+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.0 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.3 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
( • 5
) +
= (
• 6
)
By formula: (Pb+ • 5H2O) + H2O = (Pb+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.6 | kcal/mol | HPMS | Tang and Castleman, 1972 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1972 | gas phase |
+
= (
•
)
By formula: Pb+ + H3N = (Pb+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.3 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( •
) +
= (
• 2
)
By formula: (Pb+ • H3N) + H3N = (Pb+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.2 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 2
) +
= (
• 3
)
By formula: (Pb+ • 2H3N) + H3N = (Pb+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.0 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.4 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
( • 3
) +
= (
• 4
)
By formula: (Pb+ • 3H3N) + H3N = (Pb+ • 4H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.7 | kcal/mol | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; ΔrS from graph |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W.,
The Clustering Reactions of Na+ and Pb+ with Several Important Ligands,
Zeit. Phys. D., 1991, 19, 1-4, 397, https://doi.org/10.1007/BF01448337
. [all data]
Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of the Gas - Phase Hydration of the Monovalent Lead Ion,
J. Chem. Phys., 1972, 57, 9, 3638, https://doi.org/10.1063/1.1678820
. [all data]
Guo and Castleman, 1990
Guo, B.C.; Castleman, A.W.,
The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase,
Int. J. Mass Spectrom. Ion Proc., 1990, 100, 665, https://doi.org/10.1016/0168-1176(90)85101-7
. [all data]
Guo, Purnell, et al., 1990
Guo, B.C.; Purnell, J.W.; Castleman, A.W.,
The Clustering Reactions of Benzene with Sodium and Lead Ions,
Chem. Phys. Lett., 1990, 168, 2, 155, https://doi.org/10.1016/0009-2614(90)85122-S
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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