Silver ion (1+)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Silver ion (1+) + Ethylene = (Silver ion (1+) • Ethylene)

By formula: Ag+ + C2H4 = (Ag+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°33.7kcal/molHPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.1cal/mol*KN/AGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.1750.HPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

(Silver ion (1+) • 2Ammonia) + Ammonia = (Silver ion (1+) • 3Ammonia)

By formula: (Ag+ • 2H3N) + H3N = (Ag+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°14.6kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Water) + Water = (Silver ion (1+) • 3Water)

By formula: (Ag+ • 2H2O) + H2O = (Ag+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°15.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Ammonia) + Ammonia = (Silver ion (1+) • 4Ammonia)

By formula: (Ag+ • 3H3N) + H3N = (Ag+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°13.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Water) + Water = (Silver ion (1+) • 4Water)

By formula: (Ag+ • 3H2O) + H2O = (Ag+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°14.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.5cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 4Ammonia) + Ammonia = (Silver ion (1+) • 5Ammonia)

By formula: (Ag+ • 4H3N) + H3N = (Ag+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°12.8kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°34.1cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 4Water) + Water = (Silver ion (1+) • 5Water)

By formula: (Ag+ • 4H2O) + H2O = (Ag+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°13.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 5Water) + Water = (Silver ion (1+) • 6Water)

By formula: (Ag+ • 5H2O) + H2O = (Ag+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°13.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°32.2cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Ammonia) + Ammonia = (Silver ion (1+) • 2Ammonia)

By formula: (Ag+ • H3N) + H3N = (Ag+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°36.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°32.7cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Water) + Water = (Silver ion (1+) • 2Water)

By formula: (Ag+ • H2O) + H2O = (Ag+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°25.4kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Pyridine) + Pyridine = (Silver ion (1+) • 3Pyridine)

By formula: (Ag+ • 2C5H5N) + C5H5N = (Ag+ • 3C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°16.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Pyridine) + Pyridine = (Silver ion (1+) • 4Pyridine)

By formula: (Ag+ • 3C5H5N) + C5H5N = (Ag+ • 4C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°17.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°40.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Ethylene) + Ethylene = (Silver ion (1+) • 2Ethylene)

By formula: (Ag+ • C2H4) + C2H4 = (Ag+ • 2C2H4)

Quantity Value Units Method Reference Comment
ΔrH°32.4kcal/molHPMSGuo and Castleman, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.2cal/mol*KHPMSGuo and Castleman, 1991gas phase; M

Silver ion (1+) + Water = (Silver ion (1+) • Water)

By formula: Ag+ + H2O = (Ag+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°33.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.4cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 3Carbon monoxide)

By formula: (Ag+ • 2CO) + CO = (Ag+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.8,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 4Carbon monoxide)

By formula: (Ag+ • 3CO) + CO = (Ag+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
10.8 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 2Carbon monoxide)

By formula: (Ag+ • CO) + CO = (Ag+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.1 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Silver ion (1+) + Benzene = (Silver ion (1+) • Benzene)

By formula: Ag+ + C6H6 = (Ag+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°37.3 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monoxide = (Silver ion (1+) • Carbon monoxide)

By formula: Ag+ + CO = (Ag+ • CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.2 (+1.2,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • Benzene) + Benzene = (Silver ion (1+) • 2Benzene)

By formula: (Ag+ • C6H6) + C6H6 = (Ag+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
ΔrH°36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000RCD

(Silver ion (1+) • Acetonitrile) + Acetonitrile = (Silver ion (1+) • 2Acetonitrile)

By formula: (Ag+ • C2H3N) + C2H3N = (Ag+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°34.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

Silver ion (1+) + 2-Pentene, (E)- = (Silver ion (1+) • 2-Pentene, (E)-)

By formula: Ag+ + C5H10 = (Ag+ • C5H10)

Quantity Value Units Method Reference Comment
ΔrH°37.8 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetone = (Silver ion (1+) • Acetone)

By formula: Ag+ + C3H6O = (Ag+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°38.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetaldehyde = (Silver ion (1+) • Acetaldehyde)

By formula: Ag+ + C2H4O = (Ag+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°43.5 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Isoprene = (Silver ion (1+) • Isoprene)

By formula: Ag+ + C5H8 = (Ag+ • C5H8)

Quantity Value Units Method Reference Comment
ΔrH°39.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetonitrile = (Silver ion (1+) • Acetonitrile)

By formula: Ag+ + C2H3N = (Ag+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°38.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Ho, Yang, et al., 1997
Ho, Y.-P.; Yang, Y.-C.; Klippenstein, S.J.; Dunbar, R.C., Binding Energies of Ag+ and Cd+ Complexes from Analysis of Radiative Association Kinetics, J. Phys. Chem. A, 1997, 101, 18, 3338, https://doi.org/10.1021/jp9637284 . [all data]

Shoieb, Aribi, et al., 2001
Shoieb, T.; Aribi, H.; Siu, K.W.M.; Hopkinson, A.C., A Study of Silver(I) Ion-Organometallic Complexes: Ion Structures, Binding Energies, and Substituent Effects, J. Phys. Chem. A, 2001, 105, 4, 710, https://doi.org/10.1021/jp002676m . [all data]

Notes

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