Silver ion (1+)

• Formula: Ag⁺
• Molecular weight: 107.8677
• IUPAC Standard InChI: InChI=1S/Ag/q+1 Copy

  
• IUPAC Standard InChIKey: FOIXSVOLVBLSDH-UHFFFAOYSA-N Copy
• CAS Registry Number: 14701-21-4
• Chemical structure:
  This structure is also available as a 2d Mol file
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
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  • Switch to SI units

Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Ag⁺ + C₂H₄ = (Ag⁺ • C₂H₄)

Free energy of reaction

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2H₃N) + H₃N = (Ag⁺ • 3H₃N)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2H₂O) + H₂O = (Ag⁺ • 3H₂O)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3H₃N) + H₃N = (Ag⁺ • 4H₃N)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3H₂O) + H₂O = (Ag⁺ • 4H₂O)

( • 4) +  = ( • 5)

By formula: (Ag⁺ • 4H₃N) + H₃N = (Ag⁺ • 5H₃N)

( • 4) +  = ( • 5)

By formula: (Ag⁺ • 4H₂O) + H₂O = (Ag⁺ • 5H₂O)

( • 5) +  = ( • 6)

By formula: (Ag⁺ • 5H₂O) + H₂O = (Ag⁺ • 6H₂O)

( • ) +  = ( • 2)

By formula: (Ag⁺ • H₃N) + H₃N = (Ag⁺ • 2H₃N)

( • ) +  = ( • 2)

By formula: (Ag⁺ • H₂O) + H₂O = (Ag⁺ • 2H₂O)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2C₅H₅N) + C₅H₅N = (Ag⁺ • 3C₅H₅N)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3C₅H₅N) + C₅H₅N = (Ag⁺ • 4C₅H₅N)

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₂H₄) + C₂H₄ = (Ag⁺ • 2C₂H₄)

 +  = ( • )

By formula: Ag⁺ + H₂O = (Ag⁺ • H₂O)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2CO) + CO = (Ag⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3CO) + CO = (Ag⁺ • 4CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ag⁺ • CO) + CO = (Ag⁺ • 2CO)

Enthalpy of reaction

 +  = ( • )

By formula: Ag⁺ + C₆H₆ = (Ag⁺ • C₆H₆)

 +  = ( • )

By formula: Ag⁺ + CO = (Ag⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₆H₆) + C₆H₆ = (Ag⁺ • 2C₆H₆)

 +  = ( • )

By formula: Ag⁺ + CS = (Ag⁺ • CS)

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₂H₃N) + C₂H₃N = (Ag⁺ • 2C₂H₃N)

 +  = ( • )

By formula: Ag⁺ + C₅H₁₀ = (Ag⁺ • C₅H₁₀)

 +  = ( • )

By formula: Ag⁺ + C₃H₆O = (Ag⁺ • C₃H₆O)

 +  = ( • )

By formula: Ag⁺ + C₂H₄O = (Ag⁺ • C₂H₄O)

 +  = ( • )

By formula: Ag⁺ + C₅H₈ = (Ag⁺ • C₅H₈)

 +  = ( • )

By formula: Ag⁺ + C₂H₃N = (Ag⁺ • C₂H₃N)

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Ag⁺ + CO = (Ag⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Ag⁺ • CO) + CO = (Ag⁺ • 2CO)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2CO) + CO = (Ag⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3CO) + CO = (Ag⁺ • 4CO)

Enthalpy of reaction

 +  = ( • )

By formula: Ag⁺ + CS = (Ag⁺ • CS)

 +  = ( • )

By formula: Ag⁺ + C₂H₃N = (Ag⁺ • C₂H₃N)

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₂H₃N) + C₂H₃N = (Ag⁺ • 2C₂H₃N)

 +  = ( • )

By formula: Ag⁺ + C₂H₄O = (Ag⁺ • C₂H₄O)

 +  = ( • )

By formula: Ag⁺ + C₂H₄ = (Ag⁺ • C₂H₄)

Free energy of reaction

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₂H₄) + C₂H₄ = (Ag⁺ • 2C₂H₄)

 +  = ( • )

By formula: Ag⁺ + C₃H₆O = (Ag⁺ • C₃H₆O)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2C₅H₅N) + C₅H₅N = (Ag⁺ • 3C₅H₅N)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3C₅H₅N) + C₅H₅N = (Ag⁺ • 4C₅H₅N)

 +  = ( • )

By formula: Ag⁺ + C₅H₈ = (Ag⁺ • C₅H₈)

 +  = ( • )

By formula: Ag⁺ + C₅H₁₀ = (Ag⁺ • C₅H₁₀)

 +  = ( • )

By formula: Ag⁺ + C₆H₆ = (Ag⁺ • C₆H₆)

( • ) +  = ( • 2)

By formula: (Ag⁺ • C₆H₆) + C₆H₆ = (Ag⁺ • 2C₆H₆)

 +  = ( • )

By formula: Ag⁺ + H₂O = (Ag⁺ • H₂O)

( • ) +  = ( • 2)

By formula: (Ag⁺ • H₂O) + H₂O = (Ag⁺ • 2H₂O)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2H₂O) + H₂O = (Ag⁺ • 3H₂O)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3H₂O) + H₂O = (Ag⁺ • 4H₂O)

( • 4) +  = ( • 5)

By formula: (Ag⁺ • 4H₂O) + H₂O = (Ag⁺ • 5H₂O)

( • 5) +  = ( • 6)

By formula: (Ag⁺ • 5H₂O) + H₂O = (Ag⁺ • 6H₂O)

( • ) +  = ( • 2)

By formula: (Ag⁺ • H₃N) + H₃N = (Ag⁺ • 2H₃N)

( • 2) +  = ( • 3)

By formula: (Ag⁺ • 2H₃N) + H₃N = (Ag⁺ • 3H₃N)

( • 3) +  = ( • 4)

By formula: (Ag⁺ • 3H₃N) + H₃N = (Ag⁺ • 4H₃N)

( • 4) +  = ( • 5)

By formula: (Ag⁺ • 4H₃N) + H₃N = (Ag⁺ • 5H₃N)

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Ho, Yang, et al., 1997
Ho, Y.-P.; Yang, Y.-C.; Klippenstein, S.J.; Dunbar, R.C., Binding Energies of Ag+ and Cd+ Complexes from Analysis of Radiative Association Kinetics, J. Phys. Chem. A, 1997, 101, 18, 3338, https://doi.org/10.1021/jp9637284 . [all data]

Shoieb, Aribi, et al., 2001
Shoieb, T.; Aribi, H.; Siu, K.W.M.; Hopkinson, A.C., A Study of Silver(I) Ion-Organometallic Complexes: Ion Structures, Binding Energies, and Substituent Effects, J. Phys. Chem. A, 2001, 105, 4, 710, https://doi.org/10.1021/jp002676m . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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