Silver ion (1+)


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Silver ion (1+) + Ethylene = (Silver ion (1+) • Ethylene)

By formula: Ag+ + C2H4 = (Ag+ • C2H4)

Quantity Value Units Method Reference Comment
Δr33.7kcal/molHPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr22.1cal/mol*KN/AGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.1750.HPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

(Silver ion (1+) • 2Ammonia) + Ammonia = (Silver ion (1+) • 3Ammonia)

By formula: (Ag+ • 2H3N) + H3N = (Ag+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr14.6kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr24.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Water) + Water = (Silver ion (1+) • 3Water)

By formula: (Ag+ • 2H2O) + H2O = (Ag+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr15.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr21.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Ammonia) + Ammonia = (Silver ion (1+) • 4Ammonia)

By formula: (Ag+ • 3H3N) + H3N = (Ag+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr13.0kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr30.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Water) + Water = (Silver ion (1+) • 4Water)

By formula: (Ag+ • 3H2O) + H2O = (Ag+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr14.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr29.5cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 4Ammonia) + Ammonia = (Silver ion (1+) • 5Ammonia)

By formula: (Ag+ • 4H3N) + H3N = (Ag+ • 5H3N)

Quantity Value Units Method Reference Comment
Δr12.8kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr34.1cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 4Water) + Water = (Silver ion (1+) • 5Water)

By formula: (Ag+ • 4H2O) + H2O = (Ag+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr13.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr30.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 5Water) + Water = (Silver ion (1+) • 6Water)

By formula: (Ag+ • 5H2O) + H2O = (Ag+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr13.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr32.2cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Ammonia) + Ammonia = (Silver ion (1+) • 2Ammonia)

By formula: (Ag+ • H3N) + H3N = (Ag+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr36.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr32.7cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Water) + Water = (Silver ion (1+) • 2Water)

By formula: (Ag+ • H2O) + H2O = (Ag+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr25.4kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr22.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Pyridine) + Pyridine = (Silver ion (1+) • 3Pyridine)

By formula: (Ag+ • 2C5H5N) + C5H5N = (Ag+ • 3C5H5N)

Quantity Value Units Method Reference Comment
Δr16.7kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr28.0cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Pyridine) + Pyridine = (Silver ion (1+) • 4Pyridine)

By formula: (Ag+ • 3C5H5N) + C5H5N = (Ag+ • 4C5H5N)

Quantity Value Units Method Reference Comment
Δr17.9kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr40.3cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Ethylene) + Ethylene = (Silver ion (1+) • 2Ethylene)

By formula: (Ag+ • C2H4) + C2H4 = (Ag+ • 2C2H4)

Quantity Value Units Method Reference Comment
Δr32.4kcal/molHPMSGuo and Castleman, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr30.2cal/mol*KHPMSGuo and Castleman, 1991gas phase; M

Silver ion (1+) + Water = (Silver ion (1+) • Water)

By formula: Ag+ + H2O = (Ag+ • H2O)

Quantity Value Units Method Reference Comment
Δr33.3kcal/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr28.4cal/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 3Carbon monoxide)

By formula: (Ag+ • 2CO) + CO = (Ag+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.8,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 4Carbon monoxide)

By formula: (Ag+ • 3CO) + CO = (Ag+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
10.8 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 2Carbon monoxide)

By formula: (Ag+ • CO) + CO = (Ag+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.1 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Silver ion (1+) + Benzene = (Silver ion (1+) • Benzene)

By formula: Ag+ + C6H6 = (Ag+ • C6H6)

Quantity Value Units Method Reference Comment
Δr37.3 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
Δr39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monoxide = (Silver ion (1+) • Carbon monoxide)

By formula: Ag+ + CO = (Ag+ • CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.2 (+1.2,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • Benzene) + Benzene = (Silver ion (1+) • 2Benzene)

By formula: (Ag+ • C6H6) + C6H6 = (Ag+ • 2C6H6)

Quantity Value Units Method Reference Comment
Δr39.9 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000RCD

(Silver ion (1+) • Acetonitrile) + Acetonitrile = (Silver ion (1+) • 2Acetonitrile)

By formula: (Ag+ • C2H3N) + C2H3N = (Ag+ • 2C2H3N)

Quantity Value Units Method Reference Comment
Δr34.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

Silver ion (1+) + 2-Pentene, (E)- = (Silver ion (1+) • 2-Pentene, (E)-)

By formula: Ag+ + C5H10 = (Ag+ • C5H10)

Quantity Value Units Method Reference Comment
Δr37.8 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetone = (Silver ion (1+) • Acetone)

By formula: Ag+ + C3H6O = (Ag+ • C3H6O)

Quantity Value Units Method Reference Comment
Δr38.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetaldehyde = (Silver ion (1+) • Acetaldehyde)

By formula: Ag+ + C2H4O = (Ag+ • C2H4O)

Quantity Value Units Method Reference Comment
Δr43.5 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Isoprene = (Silver ion (1+) • Isoprene)

By formula: Ag+ + C5H8 = (Ag+ • C5H8)

Quantity Value Units Method Reference Comment
Δr39.2 ± 4.5kcal/molRAKHo, Yang, et al., 1997RCD

Silver ion (1+) + Acetonitrile = (Silver ion (1+) • Acetonitrile)

By formula: Ag+ + C2H3N = (Ag+ • C2H3N)

Quantity Value Units Method Reference Comment
Δr38.7kcal/molCIDTShoieb, Aribi, et al., 2001RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Ho, Yang, et al., 1997
Ho, Y.-P.; Yang, Y.-C.; Klippenstein, S.J.; Dunbar, R.C., Binding Energies of Ag+ and Cd+ Complexes from Analysis of Radiative Association Kinetics, J. Phys. Chem. A, 1997, 101, 18, 3338, https://doi.org/10.1021/jp9637284 . [all data]

Shoieb, Aribi, et al., 2001
Shoieb, T.; Aribi, H.; Siu, K.W.M.; Hopkinson, A.C., A Study of Silver(I) Ion-Organometallic Complexes: Ion Structures, Binding Energies, and Substituent Effects, J. Phys. Chem. A, 2001, 105, 4, 710, https://doi.org/10.1021/jp002676m . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References