Au25
- Formula: Au25
- Molecular weight: 4924.164225
- CAS Registry Number: 146703-21-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.87 ± 0.23 | CIDT | Herlert and Schweikhard, 2012 | |
| 3.837 ± 0.050 | LPES | Taylor, Pettiettehall, et al., 1992 | EA set as 0.2 eV above onset to correct for unresolved hot bands. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Herlert and Schweikhard, 2012
Herlert, A.; Schweikhard, L.,
Electron binding energies from collisional activation of metal-cluster dianions,
Appl. Phys. B, 2012, 107, 4, 1131-1143, https://doi.org/10.1007/s00340-011-4792-9
. [all data]
Taylor, Pettiettehall, et al., 1992
Taylor, K.J.; Pettiettehall, C.L.; Cheshnovsky, O.; Smalley, R.E.,
Ultraviolet Photoelectron Spectra of Coinage Metal Clusters,
J. Chem. Phys., 1992, 96, 4, 3319, https://doi.org/10.1063/1.461927
. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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