Stannane, tetrabutyl-
- Formula: C16H36Sn
- Molecular weight: 347.167
- IUPAC Standard InChI: InChI=1S/4C4H9.Sn/c4*1-3-4-2;/h4*1,3-4H2,2H3;
- IUPAC Standard InChIKey: AFCAKJKUYFLYFK-UHFFFAOYSA-N
- CAS Registry Number: 1461-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tetra-n-butyltin; Tetrabutylstannane; Tetrabutyltin; (C4H9)4Sn; Tin, tetrabutyl-
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Condensed phase thermochemistry data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -72.0 ± 1.7 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | -71.44 ± 0.86 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | -71.75 ± 0.96 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Davies, Pope, et al., 1963 and Lautsch, Tröber, et al., 1963. |
| ΔfH°liquid | -56.5 ± 4.0 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | -99.55 | kcal/mol | Review | Martinho Simões | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -2800.5 ± 1.6 | kcal/mol | CC-SB | Davies, Pope, et al., 1963 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
| ΔcH°liquid | -2801.10 ± 0.69 | kcal/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Cox and Pilcher, 1970. |
| ΔcH°liquid | -2816.0 ± 4.0 | kcal/mol | CC-SB | Dillard, McNeill, et al., 1958 | |
| ΔcH°liquid | -2772.99 | kcal/mol | CC-SB | Jones, Evans, et al., 1935 |
Gas Chromatography
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Apiezon L | 190. | 1599. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | Apiezon L | 1588. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
| Packed | Apiezon L | 1594. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
| Packed | Apiezon L | 1593. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Dillard, McNeill, et al., 1958
Dillard, C.R.; McNeill, E.H.; Simmons, D.E.; Yeldell, J.B.,
J. Am. Chem. Soc., 1958, 80, 3607. [all data]
Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C.,
J. Chem. Soc., 1935, 39.. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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