N-tert-Butylmethylamine

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil346.65KN/ABortnick, Luskin, et al., 1956Uncertainty assigned by TRC = 1.5 K; TRC
Tboil332.15KN/ASabatier and Mailhe, 1907Uncertainty assigned by TRC = 4. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
32.3 ± 1.4297.Verevkin, 1997Based on data from 270. to 288. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L100.607.Golovnya, Zhuravleva, et al., 1981N2, Chromosorb GAW; Column length: 2.7 m

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bortnick, Luskin, et al., 1956
Bortnick, N.; Luskin, L.S.; Hurwitz, M.D.; Craig, W.E.; Exner, L.J.; Mirza, J., T-carbinamines, rr'r''cnh(2): I reaction with alkyl halides and alkylene oxides, J. Am. Chem. Soc., 1956, 78, 4039. [all data]

Sabatier and Mailhe, 1907
Sabatier, P.; Mailhe, A., C. R. Hebd. Seances Acad. Sci., 1907, 144, 955. [all data]

Verevkin, 1997
Verevkin, Sergey P., Thermochemistry of amines: experimental standard molar enthalpies of formation of some aliphatic and aromatic amines, The Journal of Chemical Thermodynamics, 1997, 29, 8, 891-899, https://doi.org/10.1006/jcht.1997.0212 . [all data]

Golovnya, Zhuravleva, et al., 1981
Golovnya, R.V.; Zhuravleva, I.L.; Svetlova, N.I.; Grigor'eva, D.N.; Terenina, M.B.; Gutnik, S.B., Gas-chromatographic behavior of secondary isoaliphatic and alicyclic amines, J. Anal. Chem. USSR (Engl. Transl.), 1981, 36, 4, 501-505. [all data]


Notes

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