Benzene, tetradecyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus282.83KN/AJangkamolkulchai and Luks, 1989Uncertainty assigned by TRC = 0.07 K; TRC
Tfus281.8KN/AJu, Shen, et al., 1940Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap99.6kJ/molN/AReid, 1972AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
468. to 469.0.01Frinton Laboratories Inc., 1986BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
74.5500.Dykyj, Svoboda, et al., 1999Based on data from 485. to 665. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101210.2082.Kusmierz, Malinski, et al., 1985Column length: 22. m; Column diameter: 0.3 mm
CapillarySE-52210.2089.9Kusmierz, Malinski, et al., 1985He; Column length: 40. m; Column diameter: 0.3 mm

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryRTX-12056.Arey J.S., Nelson R.K., et al., 20057. m/0.1 mm/0.4 μm, 35. C @ 5. min, 0.66 K/min; Tend: 180. C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jangkamolkulchai and Luks, 1989
Jangkamolkulchai, A.; Luks, K.D., Partial miscibility behavior of the methane + ethane + n-docosane and the methane + ethane + n-tetradecylbenzene ternary mixtures, J. Chem. Eng. Data, 1989, 34, 92. [all data]

Ju, Shen, et al., 1940
Ju, T.Y.; Shen, G.; Wood, C.E., Synthesis and properties of mononormal-alkylbenzenes. II. preparation and properties of the intermediate ketones and corresponding hydrocarbons., J. Inst. Pet., 1940, 26, 514. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Kusmierz, Malinski, et al., 1985
Kusmierz, J.; Malinski, E.; Czerwiec, W.; Szafranek, J., Kováts retention indices of high-molecular-weight monomethyl-, cyclopentyl-, cyclohexyl- and phenylalkanes, J. Chromatogr., 1985, 331, 219-228, https://doi.org/10.1016/0021-9673(85)80027-3 . [all data]

Arey J.S., Nelson R.K., et al., 2005
Arey J.S.; Nelson R.K.; Xu L.; Reddy C.M., Using comprehensive two-dimensional gas chromatography retention indices to estimate environmental partitioning properties for a complete set of diesel fuel hydrocarbons, Anal. Chem., 2005, 77, 22, 7172-7182, https://doi.org/10.1021/ac051051n . [all data]


Notes

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