Magnesium ion (1+)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar154.41J/mol*KReviewChase, 1998Data last reviewed in September, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Magnesium ion (1+) • 2Water) + Water = (Magnesium ion (1+) • 3Water)

By formula: (Mg+ • 2H2O) + H2O = (Mg+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr72.4 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
72.4 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) • 3Water) + Water = (Magnesium ion (1+) • 4Water)

By formula: (Mg+ • 3H2O) + H2O = (Mg+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr48.1 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
48.1 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) • Water) + Water = (Magnesium ion (1+) • 2Water)

By formula: (Mg+ • H2O) + H2O = (Mg+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr93.3 ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
93.7 (+6.7,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Water = (Magnesium ion (1+) • Water)

By formula: Mg+ + H2O = (Mg+ • H2O)

Quantity Value Units Method Reference Comment
Δr118. ± 13.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
119. (+13.,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

Magnesium ion (1+) + Methyl Alcohol = (Magnesium ion (1+) • Methyl Alcohol)

By formula: Mg+ + CH4O = (Mg+ • CH4O)

Quantity Value Units Method Reference Comment
Δr145. ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD
Δr260. ± 20.kJ/molPDissOperti, Tews, et al., 1988gas phase; M

Magnesium ion (1+) + Tetrahydrofuran = (Magnesium ion (1+) • Tetrahydrofuran)

By formula: Mg+ + C4H8O = (Mg+ • C4H8O)

Quantity Value Units Method Reference Comment
Δr280. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Propanal = (Magnesium ion (1+) • Propanal)

By formula: Mg+ + C3H6O = (Mg+ • C3H6O)

Quantity Value Units Method Reference Comment
Δr270. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Butanal = (Magnesium ion (1+) • Butanal)

By formula: Mg+ + C4H8O = (Mg+ • C4H8O)

Quantity Value Units Method Reference Comment
Δr280. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethyl ether = (Magnesium ion (1+) • Ethyl ether)

By formula: Mg+ + C4H10O = (Mg+ • C4H10O)

Quantity Value Units Method Reference Comment
Δr280. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Ethanol = (Magnesium ion (1+) • Ethanol)

By formula: Mg+ + C2H6O = (Mg+ • C2H6O)

Quantity Value Units Method Reference Comment
Δr260. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Isopropyl Alcohol = (Magnesium ion (1+) • Isopropyl Alcohol)

By formula: Mg+ + C3H8O = (Mg+ • C3H8O)

Quantity Value Units Method Reference Comment
Δr270. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetone = (Magnesium ion (1+) • Acetone)

By formula: Mg+ + C3H6O = (Mg+ • C3H6O)

Quantity Value Units Method Reference Comment
Δr280. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Propanol = (Magnesium ion (1+) • 1-Propanol)

By formula: Mg+ + C3H8O = (Mg+ • C3H8O)

Quantity Value Units Method Reference Comment
Δr270. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 1-Butanol = (Magnesium ion (1+) • 1-Butanol)

By formula: Mg+ + C4H10O = (Mg+ • C4H10O)

Quantity Value Units Method Reference Comment
Δr270. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + Acetaldehyde = (Magnesium ion (1+) • Acetaldehyde)

By formula: Mg+ + C2H4O = (Mg+ • C2H4O)

Quantity Value Units Method Reference Comment
Δr260. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Magnesium ion (1+) + 2-Butanone = (Magnesium ion (1+) • 2-Butanone)

By formula: Mg+ + C4H8O = (Mg+ • C4H8O)

Quantity Value Units Method Reference Comment
Δr280.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(CH3OH); M

Magnesium ion (1+) + Benzene = (Magnesium ion (1+) • Benzene)

By formula: Mg+ + C6H6 = (Mg+ • C6H6)

Quantity Value Units Method Reference Comment
Δr134. ± 9.6kJ/molCIDTAndersen, Muntean, et al., 2000RCD
Δr155.kJ/molRAKGapeev and Dunbar, 2000RCD

(Magnesium ion (1+) • 4Ammonia) + Ammonia = (Magnesium ion (1+) • 5Ammonia)

By formula: (Mg+ • 4H3N) + H3N = (Mg+ • 5H3N)

Quantity Value Units Method Reference Comment
Δr56. ± 12.kJ/molCIDTAndersen, Muntean, et al., 20005th ligand is NH3; RCD

(Magnesium ion (1+) • 2Ammonia) + Ammonia = (Magnesium ion (1+) • 3Ammonia)

By formula: (Mg+ • 2H3N) + H3N = (Mg+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr95.4 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • 3Ammonia) + Ammonia = (Magnesium ion (1+) • 4Ammonia)

By formula: (Mg+ • 3H3N) + H3N = (Mg+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr44. ± 10.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Ammonia) + Ammonia = (Magnesium ion (1+) • 2Ammonia)

By formula: (Mg+ • H3N) + H3N = (Mg+ • 2H3N)

Quantity Value Units Method Reference Comment
Δr122. ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • 2Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) • 3Carbon dioxide)

By formula: (Mg+ • 2CO2) + CO2 = (Mg+ • 3CO2)

Quantity Value Units Method Reference Comment
Δr44.4 ± 5.9kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Carbon dioxide) + Carbon dioxide = (Magnesium ion (1+) • 2Carbon dioxide)

By formula: (Mg+ • CO2) + CO2 = (Mg+ • 2CO2)

Quantity Value Units Method Reference Comment
Δr48. ± 3.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) • 2Carbon monoxide)

By formula: (Mg+ • CO) + CO = (Mg+ • 2CO)

Quantity Value Units Method Reference Comment
Δr38. ± 3.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • 2Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) • 3Methyl Alcohol)

By formula: (Mg+ • 2CH4O) + CH4O = (Mg+ • 3CH4O)

Quantity Value Units Method Reference Comment
Δr91.6 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Magnesium ion (1+) • 2Methyl Alcohol)

By formula: (Mg+ • CH4O) + CH4O = (Mg+ • 2CH4O)

Quantity Value Units Method Reference Comment
Δr120. ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Methane) + Methane = (Magnesium ion (1+) • 2Methane)

By formula: (Mg+ • CH4) + CH4 = (Mg+ • 2CH4)

Quantity Value Units Method Reference Comment
Δr15. ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Pyridine = (Magnesium ion (1+) • Pyridine)

By formula: Mg+ + C5H5N = (Mg+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr200. ± 6.7kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Magnesium ion (1+) + Ammonia = (Magnesium ion (1+) • Ammonia)

By formula: Mg+ + H3N = (Mg+ • H3N)

Quantity Value Units Method Reference Comment
Δr154. ± 12.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + 1,3-Diazine = (Magnesium ion (1+) • 1,3-Diazine)

By formula: Mg+ + C4H4N2 = (Mg+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr174. ± 5.9kJ/molCIDTAmunugama and Rodgers, 2001RCD

Magnesium ion (1+) + Argon = (Magnesium ion (1+) • Argon)

By formula: Mg+ + Ar = (Mg+ • Ar)

Quantity Value Units Method Reference Comment
Δr9.6 ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Xenon = (Magnesium ion (1+) • Xenon)

By formula: Mg+ + Xe = (Mg+ • Xe)

Quantity Value Units Method Reference Comment
Δr31. ± 12.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon dioxide = (Magnesium ion (1+) • Carbon dioxide)

By formula: Mg+ + CO2 = (Mg+ • CO2)

Quantity Value Units Method Reference Comment
Δr57.7 ± 5.9kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) • Carbon monoxide)

By formula: Mg+ + CO = (Mg+ • CO)

Quantity Value Units Method Reference Comment
Δr41. ± 5.9kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Methane = (Magnesium ion (1+) • Methane)

By formula: Mg+ + CH4 = (Mg+ • CH4)

Quantity Value Units Method Reference Comment
Δr28. ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Magnesium ion (1+) + Pyrrole = (Magnesium ion (1+) • Pyrrole)

By formula: Mg+ + C4H5N = (Mg+ • C4H5N)

Quantity Value Units Method Reference Comment
Δr184.kJ/molRAKGapeev and Yang, 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Andersen, Muntean, et al., 2000
Andersen, A.; Muntean, F.; Walter, D.; Rue, C.; Armentrout, P.B., Collision-Induced Dissociation and Theoretical Studies of Mg+ Complexes with CO, CO2, NH3, CH4, CH3OH, and C6H6, J. Phys. Chem. A, 2000, 104, 4, 692, https://doi.org/10.1021/jp993031t . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]

Operti, Tews, et al., 1988
Operti, L.; Tews, E.C.; Freiser, B.S., Determination of Gas-Phase Ligand Binding Energies to Mg+ by FTMS Techniques, J. Am. Chem. Soc., 1988, 110, 12, 3847, https://doi.org/10.1021/ja00220a020 . [all data]

Gapeev and Dunbar, 2000
Gapeev, A.; Dunbar, R.C., Binding of Alkaline Earth Halide Ions MX+ to Benzene and Mesitylene, J. Am. Soc. Mass Spectrom., 2000, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References