HS2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

S2- + Hydrogen cation = HS2

By formula: S2- + H+ = HS2

Quantity Value Units Method Reference Comment
Δr329.9 ± 3.7kcal/molD-EAMoran and Ellison, 1988gas phase
Quantity Value Units Method Reference Comment
Δr>344.60kcal/molIMRBGoodings, Bohme, et al., 1986gas phase; S- deprotonates H2S, Sn- for n≥2, does not.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

S2- + Hydrogen cation = HS2

By formula: S2- + H+ = HS2

Quantity Value Units Method Reference Comment
Δr329.9 ± 3.7kcal/molD-EAMoran and Ellison, 1988gas phase
Quantity Value Units Method Reference Comment
Δr>344.60kcal/molIMRBGoodings, Bohme, et al., 1986gas phase; S- deprotonates H2S, Sn- for n≥2, does not.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Moran and Ellison, 1988
Moran, S.; Ellison, G.B., Photoelectron Spectroscopy of Sulfur Ions, J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021 . [all data]

Goodings, Bohme, et al., 1986
Goodings, J.M.; Bohme, D.K.; Elguindi, K.; Fox, A., Sulphur Anion Chemistry in Hydrocarbon Flames with H2S, OCS, and SO2 Additives, Can. J. Chem., 1986, 64, 4, 689, https://doi.org/10.1139/v86-110 . [all data]


Notes

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