Iron, tris(1,1,1-trifluoro-2,4-pentanedionato)-
- Formula: C15H12F9FeO6
- Molecular weight: 515.083
- IUPAC Standard InChI: InChI=1S/3C5H5F3O2.Fe/c3*1-3(9)2-4(10)5(6,7)8;/h3*2,9H,1H3;/q;;;+3/p-3/b3*3-2-;
- IUPAC Standard InChIKey: FGBQLUGZEFCSFD-IQMQLBNYSA-K
- CAS Registry Number: 14526-22-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Ferric trifluoroacetylacetonate
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 20.8 ± 0.29 | 410. | Chumachenko, Igumenov, et al., 1978 | Based on data from 392. to 428. K. |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference |
|---|---|---|---|
| 22.9 | 373. to 403. | TGA | Fahlman and Barron, 2000 |
| 25.0 ± 0.2 | 378. to 438. | GS | Matsubara and Kuwamoto, 1985 |
| 19.2 | 433. | N/A | Volkov, Mazurenko, et al., 1978 |
| 30.81 | 345. | N/A | Götze, Bloss, et al., 1970 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chumachenko, Igumenov, et al., 1978
Chumachenko, Y.V.; Igumenov, I.K.; Zemskov, S.V.,
Russ. J. Phys. Chem., 1978, 52, 1393. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru,
Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor,
Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022
. [all data]
Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N.,
Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]
Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H.,
Dampfdruckbestimmung von Acetylacetonaten,
Zeitschrift für Physikalische Chemie, 1970, 73, 46, 314-320, https://doi.org/10.1524/zpch.1970.73.46.314
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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