Methyl rhenium pentacarbonyl


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-197.7 ± 2.0kcal/molReviewMartinho Simões 
Δfsolid-197.9 ± 1.4kcal/molReviewMartinho Simões 
Δfsolid-197.8 ± 1.2kcal/molReviewMartinho SimõesSelected data. Average of the values from Brown, Connor, et al., 1974 and Al-Takhin, Connor, et al., 1983

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub16.7 ± 0.5kcal/molHAL-HFCAl-Takhin, Connor, et al., 1983Another value has been reported for the enthalpy of sublimation: 15.6 ± 0.24 kcal/mol Hieber, Braun, et al., 1960; MS
Δsub16.7 ± 0.5kcal/molCAl-Takhin, Connor, et al., 1983, 2AC
Δsub15.6 ± 0.24kcal/molN/APilcher and Skinner, 1983See also Lalage, Brown, et al., 1974.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
15.6347.5AStephenson and Malanowski, 1987Based on data from 315. to 380. K. See also Hieber, Braun, et al., 1960, 2.; AC
15.5313. to 383.N/AHieber and Wagner, 1958AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A., J. Organomet. Chem., 1983, 259, 313. [all data]

Hieber, Braun, et al., 1960
Hieber, W.; Braun, G.; Beck, W., Chem. Ber., 1960, 93, 901. [all data]

Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A., Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives, Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A., The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds, Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hieber, Braun, et al., 1960, 2
Hieber, Walter; Braun, Gerhard; Beck, Wolfgang, Über Organometallcarbonyle, II. Organorheniumpentacarbonyle, Chem. Ber., 1960, 93, 4, 901-908, https://doi.org/10.1002/cber.19600930422 . [all data]

Hieber and Wagner, 1958
Hieber, Walter; Wagner, Gerhard, Über Organomanganpentacarbonyle, I, Justus Liebigs Ann. Chem., 1958, 618, 1, 24-30, https://doi.org/10.1002/jlac.19586180104 . [all data]


Notes

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