NO2+


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°59.0kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
ΔrH°55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol
ΔrH°54.8kJ/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
ΔrS°51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°59.0kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
ΔrH°55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol
ΔrH°54.8kJ/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
ΔrS°51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molEICameron, Aitken, et al., 1994gas phase
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T., The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References


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