NO2+
- Formula: NO2+
- Molecular weight: 46.0050
- CAS Registry Number: 14522-82-8
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Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: NO2+ + H2O = (NO2+ • H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.4 (+9.6,-0.) | PD/KERD | Graul, Kim, et al., 1992 | gas phase |
By formula: NO2+ + N2O = (NO2+ • N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.0 | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 72.8 | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrH° | 55. ± 3. | kJ/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
ΔrH° | 54.8 | kJ/mol | PI | Linn and Ng, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrS° | 51.9 | J/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 24. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 75. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 23. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 88. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | N/A | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: NO2+ + N2 = (NO2+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 87.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 108. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 86.2 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.0 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T.,
The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion,
Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D
. [all data]
Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W.,
Appearence Energies of Small Cluster Ions and their Fragments,
J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S.,
Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O,
J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524
. [all data]
Illies, 1988
Illies, A.J.,
Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures,
J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037
. [all data]
Linn and Ng, 1981
Linn, S.H.; Ng, C.Y.,
Photoionization Study of CO2, N2O Dimers and Clusters,
J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931
. [all data]
Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S.,
How are Nitrogen Molecules Bound to NO2+ and NO+?,
J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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