Octaethylcyclotetrasiloxane
- Formula: C16H40O4Si4
- Molecular weight: 408.8284
- IUPAC Standard InChIKey: XOCOMEGNVMCRMP-UHFFFAOYSA-N
- CAS Registry Number: 1451-99-6
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°liquid | 909.3 | J/mol*K | N/A | Dzhafarov and Kuliev, 1987 |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
746.8 | 298.15 | Dzhafarov and Kuliev, 1987 | T = 5 to 300 K. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 213.35 | K | N/A | Dzhafarov and Kuliev, 1987, 2 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
69.2 | 435. | A | Stephenson and Malanowski, 1987 | Based on data from 420. to 574. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
13.71 | 213.4 | Domalski and Hearing, 1990 | AC |
Temperature of phase transition
Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|
134. | crystaline, III | crystaline, II | Dzhafarov and Kuliev, 1987 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
12.219 | 208.16 | crystaline, II | crystaline, I | Dzhafarov and Kuliev, 1987 | DH |
13.705 | 213.35 | crystaline, I | liquid | Dzhafarov and Kuliev, 1987 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
58.69 | 208.16 | crystaline, II | crystaline, I | Dzhafarov and Kuliev, 1987 | DH |
64.38 | 213.35 | crystaline, I | liquid | Dzhafarov and Kuliev, 1987 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dzhafarov and Kuliev, 1987
Dzhafarov, O.I.; Kuliev, A.M.,
Heat capacity, phase transitions, and thermodynamic parameters of octaethylcyclotetrasiloxane,
Zhur Fiz. Khim., 1987, 61(3), 602-605. [all data]
Dzhafarov and Kuliev, 1987, 2
Dzhafarov, O.I.; Kuliev, A.M.,
Heat capacity, phase transitions, and thermodynamic parameters of octaethylcyclotetrasiloxane,
Zh. Fiz. Khim., 1987, 61, 602-5. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Domalski and Hearing, 1990
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Volume II,
J. Phys. Chem. Ref. Data, 1990, 19, 4, 881, https://doi.org/10.1063/1.555876
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions Ttriple Triple point temperature Ttrs Temperature of phase transition ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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