Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')-
- Formula: C15H12AlF9O6
- Molecular weight: 486.2193
- IUPAC Standard InChI: InChI=1S/3C5H5F3O2.Al/c3*1-3(9)2-4(10)5(6,7)8;/h3*2,9H,1H3;/q;;;+3/p-3/b3-2+;2*3-2-;
- IUPAC Standard InChIKey: NSAWTIQLFWITEH-PJFPACTGSA-K
- CAS Registry Number: 14354-59-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Aluminum trifluoroacetylacetonate; Aluminum tris(trifluoroacetylacetonate); Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato)-; Tris(1,1,1-trifluoro-2,4-pentanedionato)aluminum
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 58.7 ± 0.7 | 380. | BG | Lazarev, Greenberg, et al., 1988 | Based on data from 349. to 411. K. |
| 69.6 ± 0.5 | 438. | N/A | Igumenov, Chumachenko, et al., 1978 | Based on data from 392. to 484. K. |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 74.0 | 373. to 403. | TGA | Fahlman and Barron, 2000 | |
| 113.4 ± 1.3 | 363. to 423. | GS | Matsubara and Kuwamoto, 1985 | |
| 102.7 ± 3.2 | 369. to 392. | N/A | Igumenov, Chumachenko, et al., 1978 | |
| 43.1 | 443. | N/A | Volkov, Mazurenko, et al., 1978 | |
| 93.7 ± 6.7 | 375. | N/A | Fontaine, Pommier, et al., 1972 | Based on data from 354. to 396. K. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A.,
DSC and vapour pressure investigation of some β-diketonates,
Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589
. [all data]
Igumenov, Chumachenko, et al., 1978
Igumenov, I.K.; Chumachenko, Yu.V.; Zemskov, S.V.,
Saturated vapor pressure of aluminum, gallium, and indium tris(trifluoroacetylacetonates),
Zh. Fiz. Khim., 1978, 52, 10, 2664. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru,
Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor,
Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022
. [all data]
Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N.,
Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]
Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G.,
Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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