Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')-
- Formula: C15H12AlF9O6
- Molecular weight: 486.2193
- IUPAC Standard InChI: InChI=1S/3C5H5F3O2.Al/c3*1-3(9)2-4(10)5(6,7)8;/h3*2,9H,1H3;/q;;;+3/p-3/b3-2+;2*3-2-;
- IUPAC Standard InChIKey: NSAWTIQLFWITEH-PJFPACTGSA-K
- CAS Registry Number: 14354-59-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Aluminum trifluoroacetylacetonate; Aluminum tris(trifluoroacetylacetonate); Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato)-; Tris(1,1,1-trifluoro-2,4-pentanedionato)aluminum
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 14.0 ± 0.2 | 380. | BG | Lazarev, Greenberg, et al., 1988 | Based on data from 349. to 411. K. |
| 16.6 ± 0.1 | 438. | N/A | Igumenov, Chumachenko, et al., 1978 | Based on data from 392. to 484. K. |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 17.7 | 373. to 403. | TGA | Fahlman and Barron, 2000 | |
| 27.10 ± 0.31 | 363. to 423. | GS | Matsubara and Kuwamoto, 1985 | |
| 24.55 ± 0.76 | 369. to 392. | N/A | Igumenov, Chumachenko, et al., 1978 | |
| 10.3 | 443. | N/A | Volkov, Mazurenko, et al., 1978 | |
| 22.4 ± 1.6 | 375. | N/A | Fontaine, Pommier, et al., 1972 | Based on data from 354. to 396. K. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A.,
DSC and vapour pressure investigation of some β-diketonates,
Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589
. [all data]
Igumenov, Chumachenko, et al., 1978
Igumenov, I.K.; Chumachenko, Yu.V.; Zemskov, S.V.,
Saturated vapor pressure of aluminum, gallium, and indium tris(trifluoroacetylacetonates),
Zh. Fiz. Khim., 1978, 52, 10, 2664. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru,
Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor,
Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022
. [all data]
Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N.,
Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]
Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G.,
Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.